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公开(公告)号：US20130172584A1
公开(公告)日：2013-07-04
申请号：US13729480
申请日：2012-12-28
IPC分类号： C07D307/50
CPC分类号： C07D307/50
摘要： Furfural is produced by mixing an aqueous feedstock solution containing C5 sugar and/or C6 sugar with a heated high boiling, water-miscible solvent, such as sulfolane, and a solid acid catalyst. Furfural product and water can be distilled off, leaving non-volatile solvent behind. Furfural yields of over 70% at as high as 99% conversion have been obtained with this process with sulfolane as the reaction solvent and zeolite beta as the solid acid catalyst. Also, certain by-products (e.g., humins) solubilized in the reaction solvent can be precipitated by addition of water or aqueous feedstock solution and then removed by filtration, thereby providing a convenient and effective way of removing these undesirable byproducts from the reaction mixture.
摘要翻译： 通过将含有C5糖和/或C6糖的水性原料溶液与加热的高沸点，水混溶性溶剂如环丁砜和固体酸催化剂混合来制备糠醛。 糠醛产品和水可以蒸馏出来，留下非挥发性溶剂。 用环丁砜作为反应溶剂和沸石β作为固体酸催化剂，该方法已经获得高达99％转化率的糠醛产率超过70％。 此外，溶解在反应溶剂中的某些副产物（例如，胡氏体）可以通过加入水或原料溶液沉淀，然后通过过滤除去，从而提供从反应混合物中除去这些不期望的副产物的方便有效的方法。
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公开(公告)号：US20190085163A1
公开(公告)日：2019-03-21
申请号：US16095538
申请日：2017-04-25
摘要： The disclosure relates to processes for producing lightweight polyethylene terephthalate articles such as bottles that retain good barrier properties against the permeation of oxygen, carbon dioxide and/or water vapor. The use of relatively small amounts of polytrimethylene furandicarboxylate during the formation of the PET bottles can produce a bottle having the required barrier properties and result in the use of less material.
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公开(公告)号：US10227623B2
公开(公告)日：2019-03-12
申请号：US14546225
申请日：2014-11-18
发明人： Wathudura Indika Namal De Silva , Paul Joseph Fagan , F Glenn Gallagher , Zheng-Zheng Huang , Guangliang Gary Liu , Aaron Perelman , Luis Fernando Romero Millan , Anton Shpilsky , Daniel A Slanac , Maria Walsh
IPC分类号： C12P19/14 , C08H8/00 , C12P19/02 , A61K31/717 , A61K38/47 , C08B30/02 , C08B30/12 , C12P7/14 , C12P19/20 , C13K1/02 , C12P7/10 , C13K13/00 , A23K10/30 , A23K20/189
摘要： A process for mechanical destructuring of cellulosic biomass was developed that makes use of a short application of high compression, impact, and shearing forces. The biomass may be destructured using a specific energy input that is less than 40% of the total combustible energy of the biomass. The destructured biomass, with or without saccharification and/or in-feed glycosyl hydrolase enzymes, may be used in feed applications.
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4.发明申请COMPOSITE COMPOSITIONS CONTAINING CO-PRODUCT OF A LIGNOCELLULOSIC BIOMASS PROCESS 审中-公开含有液体生物质生物过程的副产物的复合组合物公开(公告)号：US20160264775A1
公开(公告)日：2016-09-15
申请号：US15066521
申请日：2016-03-10
CPC分类号： C08L67/02 , C08L67/04 , C08L69/00 , C08L97/005 , E02D3/005
摘要： The filter cake co-product of a lignocellulosic biomass fermentation process can be combined with a polymer to make a moldable composite composition that is useful in landscape and agricultural applications. The composite composition may be formed into a composite material for use, and applied to a landscape or agricultural site. The composite composition may also contain lignocellulosic syrup.
摘要翻译： 木质纤维素生物质发酵方法的滤饼副产物可以与聚合物组合以制备可用于景观和农业应用的可成型复合组合物。 复合组合物可以形成为使用的复合材料，并应用于景观或农业场所。 复合组合物还可以含有木质纤维素糖浆。
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公开(公告)号：US09181209B2
公开(公告)日：2015-11-10
申请号：US13729375
申请日：2012-12-28
发明人： Paul Joseph Fagan , Ronnie Ozer , Eric J. Till
IPC分类号： C07D311/92 , C07D307/50
CPC分类号： C07D307/50
摘要： Furfural is produced by mixing an aqueous feedstock solution containing C5 sugar and/or C6 sugar with a heated, high boiling, water-miscible solvent, such as sulfolane, and a soluble acid catalyst. Furfural product and water are distilled off through a multistage distillation column, leaving non-volatile solvent behind. Typical furfural yields with sulfolane as the reaction solvent are about 80% at as high as 99% conversion. Also, certain by-products (e.g., humins) solubilized in the reaction solvent can be precipitated by addition of water or aqueous feedstock solution and then removed by filtration, thereby providing a convenient and effective way of removing these undesirable byproducts from the reaction mixture.
摘要翻译： 糠醛通过将含有C5糖和/或C6糖的原料水溶液与加热的，沸点高的水混溶性溶剂如环丁砜和可溶性酸催化剂混合而制备。 通过多级蒸馏塔蒸馏出糠醛产物和水，留下非挥发性溶剂。 以环丁砜作为反应溶剂的典型糠醛产率为高达99％转化率的约80％。 此外，溶解在反应溶剂中的某些副产物（例如，胡氏体）可以通过加入水或原料溶液沉淀，然后通过过滤除去，从而提供从反应混合物中除去这些不期望的副产物的方便有效的方法。
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公开(公告)号：US20130172583A1
公开(公告)日：2013-07-04
申请号：US13729445
申请日：2012-12-28
发明人： David Richard Corbin , Paul Joseph Fagan , Stuart B. Fergusson , Keith W. Hutchenson , Michael Stephen McKinnon , Ronnie Ozer , Bhuma Rajagopalan , Sourav Kumar Sengupta , Eric J. Till
IPC分类号： C07D307/48
CPC分类号： C07D307/50 , C07D307/48 , Y02P20/127
摘要： Furfural is produced by contacting a feedstock solution containing C5 sugar and/or C6 sugar with a solid acid catalyst using reactive distillation. Both high yield and high conversion are obtained, without production of insoluble char in the reaction vessel. Degradation of furfural is minimized by its low residence time in contact with the solid acid catalyst. Higher catalyst lifetime can be achieved because the catalyst is continually washed with the refluxing aqueous solution and not sitting in high-boiling byproducts like humins, which are known to be deleterious to catalyst lifetime.
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公开(公告)号：US20130168227A1
公开(公告)日：2013-07-04
申请号：US13729526
申请日：2012-12-28
发明人： Paul Joseph Fagan , Ronnie Ozer , Eric J. Till
IPC分类号： C07D307/48
CPC分类号： C07D307/48 , C07D307/50
摘要： Furfural is produced in one step at both high yield and high conversion from a feedstock comprising solid biomass and/or insoluble polysaccharide, in a high boiling, water-miscible solvent containing a soluble acid catalyst, and water. Furfural product and water can be distilled off, leaving non-volatile solvent behind. Because furfural contact with the acidic medium is minimized, degradation is kept to a minimum. The feedstock does not have to be pretreated. Because the biomass undergoes near complete dissolution, the residual material is flowable and easier to handle than residual solids reported from other processes. Further, certain by-products (e.g., humins, lignins) solubilized in the reaction solvent can be precipitated by addition of water or aqueous solution and then removed from the reaction mixture.
摘要翻译： 在包含固体生物质和/或不溶性多糖的原料，在含有可溶性酸催化剂的高沸点，水混溶性溶剂和水中的高收率和高转化率下，一步生产糠醛。 糠醛产品和水可以蒸馏出来，留下非挥发性溶剂。 因为与酸性介质的糠醛接触最小化，所以降解保持最小。 原料不必经过预处理。 由于生物质几乎接近完全溶解，因此剩余物质可流动并易于处理，其余过程报告的残留物质。 此外，溶解在反应溶剂中的某些副产物（例如，胡椒，木质素）可以通过加入水或水溶液沉淀，然后从反应混合物中除去。
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公开(公告)号：US20190284151A1
公开(公告)日：2019-09-19
申请号：US16303005
申请日：2017-06-02
发明人： Torren Ryan Carlson , Jacob G. Dickinson , David William Drew , Paul Joseph Fagan , Francis G. Gallagher , Keith M. Hutchenson , Israbel Liberis , Kenneth Mersman , Gregg Sunshine
IPC分类号： C07D307/50
摘要： The disclosure relates to an efficient process for the production of a furan derivative from C5 and/or C6 sugars. The process utilizes a water immiscible organic solvent system comprising at least one alkyl phenol and at least one alkylated naphthalene.
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9.发明授权公开(公告)号：US09211529B2
公开(公告)日：2015-12-15
申请号：US13942759
申请日：2013-07-16
IPC分类号： C07C31/02 , C07C31/12 , C07C29/34 , B01J27/182 , B01J27/138 , B01J27/18 , B01J27/185 , B01J37/06 , B01J37/08 , B01J27/186 , B01J27/198 , B01J35/00 , B01J35/10 , B01J37/03
CPC分类号： B01J27/182 , B01J27/1806 , B01J27/1853 , B01J27/186 , B01J27/198 , B01J35/002 , B01J35/1014 , B01J37/031 , B01J37/06 , B01J37/08 , C07C29/34 , C07C31/12
摘要： Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM′xM″yM′″z)5(PO4)3(OH), wherein M is Mg; M′ is Ca; M″ is Sr; M′″ is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.
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公开(公告)号：US09012664B2
公开(公告)日：2015-04-21
申请号：US13729445
申请日：2012-12-28
发明人： David Richard Corbin , Paul Joseph Fagan , Stuart B Fergusson , Keith W Hutchenson , Pranit S Metkar , Ronnie Ozer , Carmo Joseph Pereira , Bhuma Rajagopalan , Sourav Kumar Sengupta , Eric J. Till
IPC分类号： C07D307/48 , C07D307/50
CPC分类号： C07D307/50 , C07D307/48 , Y02P20/127
摘要： Furfural is produced by contacting a feedstock solution containing C5 sugar and/or C6 sugar with a solid acid catalyst using reactive distillation. Both high yield and high conversion are obtained, without production of insoluble char in the reaction vessel. Degradation of furfural is minimized by its low residence time in contact with the solid acid catalyst. Higher catalyst lifetime can be achieved because the catalyst is continually washed with the refluxing aqueous solution and not sitting in high-boiling byproducts like humins, which are known to be deleterious to catalyst lifetime.
摘要翻译： 通过使用反应蒸馏将含有C5糖和/或C6糖的原料溶液与固体酸催化剂接触来制备糠醛。 获得高产率和高转化率，而在反应容器中不产生不溶性焦炭。 通过其与固体酸催化剂接触的低停留时间使糠醛的降解最小化。 可以实现更高的催化剂寿命，因为催化剂连续地用回流水溶液洗涤，而不是位于已知对催化剂寿命有害的高沸点副产物如胡氏。
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