摘要:
Compounds having a melting point above 40.degree. C. which compounds contain uretone imine groups and which are substantially free from volatile isocyanate blocking agents which are split off under stoving conditions are excellent crosslinking agents for pulverulent coating compositions based on hydroxyl groups-containing polymers.
摘要:
The present invention relates to mixtures which are suitable for use as lacquer powders or as binders for lacquer powders and which are solid and capable of being pulverized at temperatures below about 40.degree. C. and liquid at temperatures above about 150.degree. C., which mixtures comprise(a) an isocyanate component having masked isocyanate groups;(b) a polyhydroxyl component; and, optionally(c) the conventional auxiliary agents and additives;Characterized in that the substance used as component (a) is a polyisocyanate having isocyanurate groups and isocyanate groups which are masked with lactams. The present invention also relates to the use of these mixtures as lacquer powders or as binders for lacquer powders for coating any heat-resistant substrate by the conventional coating methods employed for lacquer powders.
摘要:
New amidine/isocyanate adducts are particularly useful as catalysts for hardening epoxy resins, in particular pulverulent coating compositions based on epoxy resins. New bicyclic amidines are excellent starting materials for manufacturing these amidine/isocyanate adducts.
摘要:
New amidine/isocyanate adducts are particularly useful as catalysts for hardening epoxy resins, in particular pulverulent coating compositions based on epoxy resins. New bicyclic amidines are excellent starting materials for manufacturing these amidine/isocyanate adducts.
摘要:
New amidine/isocyanate adducts are particularly useful as catalysts for hardening epoxy resins, in particular pulverulent coating compositions based on epoxy resins. New bicyclic amidines are excellent starting materials for manufacturing these amidine/isocyanate adducts.
摘要:
A powder lacquer binder composition which comprises a homogeneous crosslinkable mixture comprising: (A) a polymer containing more than one carboxyl group and having a melting and softening point of from 20.degree. to 150.degree. C. (as determined by differential thermoanalysis) and an acid number of from 10 to 150 mg of KOH/g; and (B) a 1,2-polyepoxide which is N,N',N"-triglycidyl triazolidine-3,5-dione having an epoxide value of from 0.6 to 1.13; the mixture containing from 0.5 to 1.5 1,2-epoxide group per carboxyl group; and a process for the preparation thereof.
摘要:
1,2,4-Triazole-blocked polyisocyanates are excellent crosslinking agents for polyhydroxyl compounds. Their comparatively high melting point makes these compositions particularly suitable for coatings which are applied by fluidisation dip coating or electrostatic powder spraying.
摘要:
The present invention relates to lacquer polyisocyanates which contain about 0 to 8% free isocyanate groups, about 10 to 28% blocked isocyanate groups and about 2 to 10% of the structural units, --NH--NH--CO--O, all percentages based on the weight of the polyisocyanates, but excluding the weight of the blocking agent. Also provided is a process for preparing these polyisocyanates which comprises reacting about 10 to 30 mol % of the isocyanate groups of an organic polyisocyanate with reaction products which have (i) alcoholic hydroxyl groups and (ii) structural units of the formula, --O--CO--NH--NH--CO--O--, and/or of the formula H.sub.2 N--NH--CO--O--, with the formation of urethane groups and optionally groups corresponding to the formula, --NH--NH--CO--O--, and reacting about 50 to 90 mol % of the isocyanate groups of the organic polyisocyanate with a blocking agent. The reaction products containing alcoholic hydroxyl groups are obtained by reacting 1 mol of hydrazine or of hydrazine hydrate with about 1 to 2 mols of a cyclic carbonate. A final object of the present invention is the use of the new lacquer polyisocyanates as the isocyanate component in thermosetting, two-component polyurethane lacquers.