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    Halogenated ethylene polymers with improved resistance to agglomeration
    1.
    发明授权
    Halogenated ethylene polymers with improved resistance to agglomeration 失效
    具有改善的附聚抗性的卤化乙烯聚合物

    公开(公告)号：US4767823A

    公开(公告)日：1988-08-30

    申请号：US894441

    申请日：1986-08-01

    申请人： Edward Jones ,  Larry A. Meiske ,  Warren L. Young

    发明人： Edward Jones ,  Larry A. Meiske ,  Warren L. Young

    IPC分类号： C08F8/20

    CPC分类号： C08F8/20

    摘要： Halogenated polyethylene resins and halogenated ethylene polymer resins having a reduced tendency to "block" are provided. The halogenated resins are prepared respectively from polyethylene and ethylene polymer starting materials which have a weight-based median particle size of from about 120 to about 600 microns and a weight-based particle size distribution such that more than 60 percent of the particles have a particle size of from about 130 to about 850 microns. The halogenated resins also have a weight-based median particle size of from about 200 to about 900 microns. The halogenated polyethylene resins have a chemically combined halogen content of from about 26 to about 42 weight percent whereas the halogenated ethylene polymer resins have a chemically combined halogen content of from about 15 to about 28 weight percent. The halogenated ethylene polymer resins are prepared from ethylene polymer starting materials which have polymerized therein up to five weight percent of 1-olefin monomer copolymerizable with ethylene.

    摘要翻译： 提供了具有降低的“堵塞”倾向的卤化聚乙烯树脂和卤化乙烯聚合物树脂。 卤化树脂分别由聚乙烯和乙烯聚合物原料制备，其重量基于中值粒度为约120至约600微米，重量为基准的粒度分布使得多于60％的颗粒具有颗粒 约130至约850微米的尺寸。 卤化树脂还具有约200至约900微米的基于重量的中值粒度。 卤化聚乙烯树脂具有约26至约42重量％的化学组合卤素含量，而卤代乙烯聚合物树脂具有约15至约28重量％的化学组合卤素含量。 卤化乙烯聚合物树脂由乙烯聚合物原料制备，其中聚合有最多5重量％的可与乙烯共聚的1-烯烃单体。

    Catalyst and process for polymerizing olefins
    6.
    发明授权
    Catalyst and process for polymerizing olefins 失效
    催化剂和烯烃聚合方法

    公开(公告)号：US5114897A

    公开(公告)日：1992-05-19

    申请号：US708416

    申请日：1991-05-31

    申请人： Joseph G. Schell, Jr. ,  Gary R. Marchand ,  Larry A. Meiske

    发明人： Joseph G. Schell, Jr. ,  Gary R. Marchand ,  Larry A. Meiske

    IPC分类号： C08F4/646 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： Olefins are polymerized under solution polymerization conditions in the presence of the solid catalytic product resulting from removing the liquid components from the product resulting from admixing in an inert diluent and in an atmosphere which excludes moisture and oxygen (A) at least one hydrocarbon soluble organomagnesium compound; (B) at least one organic hydroxyl-containing compound; (C) at least one reducing halide source; (D) at least one transition metal (Tm) alkoxide.

    摘要翻译： 烯烃在溶液聚合条件下在固体催化剂存在下进行聚合，这是由惰性稀释剂和不含水分和氧气的气氛中除去来自产物的液体组分得到的（A）至少一种可溶于烃的有机镁化合物 ; （B）至少一种含有机羟基化合物; （C）至少一种还原卤素源; （D）至少一种过渡金属（Tm）醇盐。

    Method for preparing transition metal component of Ziegler-Natta catalysts
    7.
    发明授权
    Method for preparing transition metal component of Ziegler-Natta catalysts 失效
    制备齐格勒 - 纳塔催化剂的过渡金属组分的方法

    公开(公告)号：US4661465A

    公开(公告)日：1987-04-28

    申请号：US894406

    申请日：1986-08-07

    申请人： Ricardo Fuentes, Jr. ,  Gary R. Marchand ,  Larry A. Meiske

    发明人： Ricardo Fuentes, Jr. ,  Gary R. Marchand ,  Larry A. Meiske

    IPC分类号： C08F4/62 ,  C08F10/00 ,  C08F4/64 ,  C08F4/68

    CPC分类号： C08F10/00

    摘要： A method for preparing Ziegler catalysts is disclosed wherein a mixture (A) containing the product resulting from mixing in an inert hydrocarbon diluent (1) a hydrocarbon soluble magnesium alkyl compound in said hydrocarbon solvent, (2) an aliphatic alcohol or carbon dioxide and (3) a titanium compound is reacted with (B) a reducing halide source in said hydrocarbon solvent. Components (A) and (B) are mixed at a constant initial temperature. When the magnesium concentration in component (A) and the metal concentration in component (B) are relatively low, the resultant polymer has a relatively narrow particle size distribution whereas when said concentration is relatively high, the resultant polymer has a relatively broad particle size distribution. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively low, the resultant polymer has a relatively small average particle size. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively high, the resultant polymer has a relatively large average particle size.

    摘要翻译： 公开了一种制备齐格勒催化剂的方法，其中含有在惰性烃稀释剂（1）中混合产物的混合物（1）烃溶剂中的烃溶性烷基镁化合物，（2）脂族醇或二氧化碳和（ 3）钛化合物与（B）还原卤化物源在所述烃溶剂中反应。 组分（A）和（B）在恒定的初始温度下混合。 当组分（A）中的镁浓度和组分（B）中的金属浓度相对较低时，所得聚合物具有相对窄的粒度分布，而当所述浓度相对较高时，所得聚合物具有相对宽的粒度分布 。 当脂肪族醇的摩尔数：组分（1）中与金属原子相连的烃基的总数相对较低时，所得聚合物的平均粒径相对较小。 当脂肪族醇的摩尔数：组分（1）中与金属原子相连的烃基的总数相对较高时，所得聚合物的平均粒径相对较大。

    POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME
    8.
    发明申请
    POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 有权
    聚合物组合物，其制备方法和由其制备的制品

    公开(公告)号：US20120116021A1

    公开(公告)日：2012-05-10

    申请号：US13377916

    申请日：2010-07-14

    申请人： Wenbin Liang ,  Brian W. Walther ,  Timothy E. Clayfield ,  Arnis U. Paeglis ,  Sherrika D. Daniel ,  Larry A. Meiske

    发明人： Wenbin Liang ,  Brian W. Walther ,  Timothy E. Clayfield ,  Arnis U. Paeglis ,  Sherrika D. Daniel ,  Larry A. Meiske

    IPC分类号： C08L47/00

    CPC分类号： C08L23/16 ,  C08F297/06 ,  C08L2205/02 ,  C08L2666/08 ,  C08L2666/06

    摘要： The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (11 at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.

    摘要翻译： 本发明提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）第一共聚物，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中所述第一组合物具有大于0.429摩尔/ g的[（ML（1 + 4,125℃））/ Mw（conv）] * 1000。 本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML，1 + 4，125℃），并且具有小于或等于70的低剪切粘度（11弧度/秒） ，100,000Pa·秒。 本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML（1 + 4，125℃）），并且具有小于1.2的[Mw（abs）] / [Mw（conv）） 。

    Impact-modified thermoplastic polyolefins and articles fabricated therefrom
    9.
    发明授权
    Impact-modified thermoplastic polyolefins and articles fabricated therefrom 有权
    冲击改性的热塑性聚烯烃及其制造的制品

    公开(公告)号：US6140420A

    公开(公告)日：2000-10-31

    申请号：US204008

    申请日：1998-12-01

    申请人： Kalyan Sehanobish ,  Larry A. Meiske ,  Shaofu Wu ,  Pak-Wing Steve Chum

    发明人： Kalyan Sehanobish ,  Larry A. Meiske ,  Shaofu Wu ,  Pak-Wing Steve Chum

    IPC分类号： C08J3/20 ,  C08F10/02 ,  C08L23/00 ,  C08L23/08 ,  C08L23/12 ,  C08L23/16 ,  C08L51/00 ,  C08L101/00 ,  C08F8/30

    CPC分类号： C08L23/12 ,  C08L101/00 ,  C08L23/16 ,  C08L23/0815 ,  C08L2314/06 ,  Y10T428/1352

    摘要： Melt processible thermoplastic compositions and method for making them are described, these compositions comprising a thermoplastic polymer resin matrix selected from the group consisting of thermoplastic polyurethanes, polyvinyl chlorides, styrenics, engineering thermoplastics, and polyolefins, at least about 25 percent (by weight based on the total composition) of an elastomeric impact modifier dispersed as discrete particles in the thermoplastic matrix (a); and at least about 10 percent (by weight based on the total composition) of at least one homogeneous linear or substantially linear ethylene polymer dispersed as discrete particles in at least the impact modifier (b), the ethylene polymer having a molecular weight distribution less than 3.5 and a density of at least 0.04 g/cm.sup.3 higher than the density of the impact modifier component (b), wherein the elastic modulus of the thermoplastic component (a) is at least 200 times greater than the elastic modulus of the impact modifier component (b). These thermoplastic compositions have improved processability. Processes for fabricating articles from them are described. The articles made with these compositions have improved properties such as low temperature impact strength, improved percent elongation to break, greater stiffness, and improved weld line strength, making them useful for applications requiring both strength and flexibility in low temperature environments, such as automotive components and facia.

    摘要翻译： 描述了可熔融加工的热塑性组合物及其制备方法，这些组合物包含选自热塑性聚氨酯，聚氯乙烯，苯乙烯，工程热塑性塑料和聚烯烃的热塑性聚合物树脂基体，至少约25％（以 分散在热塑性基体（a）中的离散颗粒的弹性体抗冲改性剂的总组成）; 至少约10％（基于总组合物的重量计）至少一种均匀的直链或基本上线性的乙烯聚合物，其至少在至少抗冲改性剂（b）中分散成分散的颗粒，乙烯聚合物的分子量分布小于 3.5，并且比冲击改性剂组分（b）的密度高至少0.04g / cm 3的密度，其中热塑性组分（a）的弹性模量是冲击改性剂组分（a）的弹性模量的至少200倍 （b）。 这些热塑性组合物具有改善的加工性能。 描述从它们制造制品的方法。 用这些组合物制成的制品具有改进的性能，例如低温冲击强度，改善的断裂延伸百分比，更大的刚度和更好的焊接线强度，使得它们可用于在低温环境中要求强度和柔性的应用，例如汽车部件 和面。

    Impact-modified thermoplastic polyolefins and articles fabricated therefrom
    10.
    发明授权
    Impact-modified thermoplastic polyolefins and articles fabricated therefrom 失效
    冲击改性的热塑性聚烯烃及其制造的制品

    公开(公告)号：US5861463A

    公开(公告)日：1999-01-19

    申请号：US741648

    申请日：1996-10-31

    申请人： Kalyan Sehanobish ,  Shaofu Wu ,  Larry A. Meiske ,  Pak-Wing Steve Chum

    发明人： Kalyan Sehanobish ,  Shaofu Wu ,  Larry A. Meiske ,  Pak-Wing Steve Chum

    IPC分类号： C08J3/20 ,  C08F10/02 ,  C08L23/00 ,  C08L23/08 ,  C08L23/12 ,  C08L23/16 ,  C08L51/00 ,  C08L101/00 ,  C08F30/00

    CPC分类号： C08L23/12 ,  C08L101/00 ,  C08L23/16 ,  C08L23/0815 ,  C08L2314/06 ,  Y10T428/1352

    摘要： Melt processible thermoplastic compositions and method for making them are described, these compositions comprising a) a polypropylene matrix, b) at least about 25 percent (by weight based on the total composition) of an elastomeric impact modifier dispersed as discrete particles in the polypropylene matrix (a); and c) at least about 10 percent (by weight based on the total composition) of at least one homogeneous linear or substantially linear ethylene polymer dispersed as discrete particles in at least the impact modifier (b), the ethylene polymer having a molecular weight distribution less than 3.5 and a density of at least 0.04 g/cm.sup.3 higher than the density of the impact modifier component (b), wherein the elastic modulus of the polypropylene (a) is at least 200 times greater than the elastic modulus of the impact modifier component (b).These thermoplastic compositions have improved processability. Processes for fabricating articles from them are described. The articles made with these compositions have improved properties such as low temperature impact strength, improved percent elongation to break, greater stiffness, and improved weld line strength, making them useful for applications requiring both strength and flexibility in low temperature environments, such as automotive components and facia.

    摘要翻译： 描述了可熔融加工的热塑性组合物及其制备方法，这些组合物包含a）聚丙烯基体，b）至少约25重量％（基于总组合物的重量）作为分散颗粒分散在聚丙烯基体中的弹性体抗冲改性剂 （一个）; 和至少一种在至少一种抗冲改性剂（b）中作为离散颗粒分散的均匀线性或基本上线性的乙烯聚合物的至少约10重量％（基于总组合物计）），乙烯聚合物具有分子量分布 小于3.5，并且比冲击改性剂组分（b）的密度高至少0.04g / cm 3的密度，其中聚丙烯（a）的弹性模量比冲击改性剂的弹性模量大至少200倍 组分（b）。 这些热塑性组合物具有改善的加工性 描述从它们制造制品的方法。 用这些组合物制成的制品具有改进的性能，例如低温冲击强度，改善的断裂延伸百分比，更大的刚度和更好的焊接线强度，使得它们可用于在低温环境中要求强度和柔性的应用，例如汽车部件 和面。