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    Radiation curable coating composition and coated optical fiber
    3.
    发明授权
    Radiation curable coating composition and coated optical fiber 失效
    可辐射固化涂料组合物和涂层光纤

    公开(公告)号：US5596669A

    公开(公告)日：1997-01-21

    申请号：US426601

    申请日：1995-04-21

    申请人： Edward J. Murphy ,  Stephen C. Lapin ,  Gerry K. Noren

    发明人： Edward J. Murphy ,  Stephen C. Lapin ,  Gerry K. Noren

    IPC分类号： C03C25/10 ,  G02B6/02 ,  G02B6/22

    CPC分类号： C03C25/1065 ,  C03C25/106 ,  G02B6/02395

    摘要： Provided is a radiation curable coating composition suitable for coating optical glass fiber, having a viscosity in the range of about 10 mPas to 10,000 mPas made of about 20 to about 99.9 weight % of at least one of a thermoplastic non-crosslinking polymer and an ethylenically-unsaturated oligomeric compound; optionally, from 0 to about 60 weight % of an ethylenically-unsaturated diluent, optionally, from 0 to about 60 weight % of a multifunctional ethylenically-unsaturated compound, and optionally, from 0 to about 10 weight % of a photoinitiator, provided that if the thermoplastic non-crosslinking polymer is present and no ethylenically-unsaturated oligomeric compound is present, then the ethylenically-unsaturated diluent is present in an amount up to about 60 weight % and the multifunctional ethylenically-unsaturated compound is present in an amount up to about 60 weight %. The composition provides a tack-free handeable fiber after radiation cure and is fugitive upon thermolysis. Also provided is an optical fiber coated with the coating composition.

    摘要翻译： 本发明提供一种适用于涂覆光学玻璃纤维的可辐射固化涂料组合物，其粘度范围为约20〜99.9重量％的热塑性非交联聚合物和烯属化合物中的至少一种的约10mPas至10,000mPas 不饱和低聚化合物; 任选地，0至约60重量％的烯键式不饱和稀释剂，任选地0至约60重量％的多官能烯属不饱和化合物和任选的0至约10重量％的光引发剂，条件是如果 存在热塑性非交联聚合物并且不存在烯键式不饱和低聚化合物，则烯键式不饱和稀释剂以高达约60重量％的量存在，并且多官能烯属不饱和化合物以高达约 60重量％。 组合物在辐射固化后提供无粘性的可再生纤维，并且在热分解时是挥发性的。 还提供涂覆有涂料组合物的光纤。

    Photocurable polyamine-ene compositions having improved cure speed
    4.
    发明授权
    Photocurable polyamine-ene compositions having improved cure speed 失效
    具有改进固化速度的光固化多胺 - 烯组合物

    公开(公告)号：US4943600A

    公开(公告)日：1990-07-24

    申请号：US321148

    申请日：1989-03-10

    申请人： Gerry K. Noren ,  Edward J. Murphy

    发明人： Gerry K. Noren ,  Edward J. Murphy

    IPC分类号： C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08F299/04 ,  C08L67/06 ,  C09D5/00 ,  C09D133/04 ,  C09D133/06 ,  C09D167/06 ,  C09D179/02

    CPC分类号： C08F299/0485 ,  C08F299/0478 ,  C09D167/06

    摘要： A photocurable ethylenically unsaturated liquid coating composition consisting essentially of: 1- polyethylenically unsaturated material in which the ethylenically unsaturated groups are polymerizable groups which are not (meth)acrylate groups; 2- a polyamine resin; and 3- an hydroxyalkyl phenone photoinitiator to speed the cure. The photocure rate is also speeded by combining a tertiary amine-functional acrylic copolymer, an allyl-functional resin, and a maleate-functional resin in a weight ratio of about 15-65/5-45/30-70. In preferred practice both expedients are used to maximize the cure speed.

    摘要翻译： 一种可光固化的烯键式不饱和液体涂料组合物，主要由以下组成：1-烯键式不饱和基团，其中烯属不饱和基团是不是（甲基）丙烯酸酯基团的可聚合基团; 2-聚胺树脂; 和3-羟基烷基苯酮光引发剂以加速固化。 通过将叔胺官能丙烯酸共聚物，烯丙基官能树脂和马来酸酯官能树脂以约15-65 / 5-45 / 30-70的重量比组合，光固化速度也加速。 在优选的实践中，使用两种方法来最大化固化速度。

    Ribbon assemblies and radiation-curable ink compositions for use in forming the ribbon assemblies
    6.
    发明授权
    Ribbon assemblies and radiation-curable ink compositions for use in forming the ribbon assemblies 失效
    色带组件和可用于形成色带组件的可辐射固化油墨组合物

    公开(公告)号：US06197422B1

    公开(公告)日：2001-03-06

    申请号：US09158134

    申请日：1998-09-22

    申请人： Edward J. Murphy ,  Edward P. Zahora ,  Johannes C. van den Burg

    发明人： Edward J. Murphy ,  Edward P. Zahora ,  Johannes C. van den Burg

    IPC分类号： D02G300

    CPC分类号： C03C25/106 ,  C03C25/1065 ,  C08F290/064 ,  C08F290/067 ,  G02B6/4482 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2964

    摘要： Provided is a ribbon assembly having the functional capability of providing break-out of ink coated or colored outer primary coated optical glass fibers from the ribbon assembly. The ink coating or colored outer primary coating is formulated from a benzophenone compound and at least about 1 wt. % of a homolytic photoinitiator to provide a level of adhesion between the ink coating or colored outer primary coating and matrix material which is less than the level of adhesion between the ink coating or colored outer primary coating and an adjacent underlying coating. Also provided are ink coating and colored outer primary coating compositions adapted to form ink coatings and colored outer primary coatings suitable for use on optical glass fibers contained in a ribbon assembly.

    摘要翻译： 提供了一种带状组件，其具有从带状组件提供油墨涂覆或着色的外部初级涂覆光学玻璃纤维的功能性能。 油墨涂料或着色的外部初级涂料由二苯甲酮化合物配制，并且至少约1wt。 ％的均相光引发剂，以提供油墨涂层或着色的外部初级涂层和基质材料之间的粘附水平，其小于油墨涂层或着色外初级涂层和相邻下层涂层之间的粘合程度。 还提供了适用于形成油墨涂层和适用于包含在色带组件中的光学玻璃纤维上的着色的外部主要涂层的着色的外部初级涂料组合物的油墨涂料和着色的外部初级涂料组合物。

    Ribbon assemblies and ink coating compositions for use in forming the ribbon assemblies
    8.
    发明授权
    Ribbon assemblies and ink coating compositions for use in forming the ribbon assemblies 失效
    用于形成色带组件的色带组件和油墨涂料组合物

    公开(公告)号：US06130980A

    公开(公告)日：2000-10-10

    申请号：US72181

    申请日：1998-05-05

    申请人： Edward J. Murphy ,  Edward P. Zahora ,  David M. Szurn

    发明人： Edward J. Murphy ,  Edward P. Zahora ,  David M. Szurn

    IPC分类号： C03C25/10 ,  C08F290/06 ,  C09D4/00 ,  C09D4/06 ,  G02B6/44 ,  G02B6/04

    CPC分类号： G02B6/4482 ,  C03C25/106 ,  C03C25/1065 ,  C08F290/064 ,  C08F290/067 ,  C09D4/00 ,  C09D4/06 ,  Y10T428/2804 ,  Y10T428/2929 ,  Y10T428/2938

    摘要： Provided is a ribbon assembly having the functional capability of providing break-out of ink coated optical glass fibers from said ribbon assembly. The monomers, oligomers and photoinitiator for forming an ink coating on the optical glass fibers contained in the ribbon assembly have been selected to provide an average percentage of reacted acrylate unsaturation which provides a level of adhesion between a matrix material and an ink coating that is less than a level of adhesion between the ink coating and the coated optical glass fiber to provide break-out of the ink coated optical glass fiber from said ribbon assembly. Also provided are ink coating compositions adapted to form ink coatings suitable for use on optical glass fibers contained in the ribbon assembly.

    摘要翻译： 提供了具有从所述带组件提供油墨涂覆的光学玻璃纤维的突出功能的色带组件。 已经选择了用于在带组件中包含的光学玻璃纤维上形成油墨涂层的单体，低聚物和光引发剂，以提供反应的丙烯酸酯不饱和度的平均百分比，其提供基体材料和较少的油墨涂层之间的粘合程度 比油墨涂层和涂覆的光学玻璃纤维之间的粘附程度提供了从所述带组件中分离的油墨涂覆的光学玻璃纤维。 还提供了适于形成适用于包含在色带组件中的光学玻璃纤维上的油墨涂料的油墨涂料组合物。

    Process for making transparent paper using a UV curable compositions of maleate, vinyl monomer and an allyl compound
    9.
    发明授权
    Process for making transparent paper using a UV curable compositions of maleate, vinyl monomer and an allyl compound 失效
    使用马来酸盐，乙烯基单体和烯丙基化合物的可UV固化组合物制造透明纸的方法

    公开(公告)号：US5207871A

    公开(公告)日：1993-05-04

    申请号：US714856

    申请日：1991-06-13

    申请人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

    发明人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

    IPC分类号： C08F2/50 ,  D21H17/53 ,  D21H25/06 ,  D21H27/06 ,  G03G7/00

    CPC分类号： D21H27/06 ,  D21H17/53 ,  D21H25/06 ,  G03G7/004 ,  Y10T428/2933 ,  Y10T428/3179 ,  Y10T428/31794

    摘要： A composition which is cured upon exposure to ultraviolet light in the absence of solvent is disclosed. The liquid composition is prepared by combining a liquid maleate polyester and at least one of a vinyl compound and an allyl functional compound. A photoinitiator is then added to the polymerizable liquid composition. A substrate is impregnated with the polymerizable liquid composition and exposed to actinic energy of a sufficient dosage for a sufficient amount of time to polymerize the composition to a sufficient degree to impart useful properties to the substrate. The composition can be used as a binder for fiberglass insulation, in the manufacture of transparent or semi-transparent paper and to manufacture paper for use in photocopy machines.

    摘要翻译： 公开了在不存在溶剂的情况下暴露于紫外线时固化的组合物。 通过将液体马来酸酯聚酯与乙烯基化合物和烯丙基官能化合物中的至少一种组合来制备液体组合物。 然后将光引发剂加入到可聚合液体组合物中。 用可聚合液体组合物浸渍基质并暴露于足够量的光化能量足够的时间以使组合物充分聚合以赋予基底有用的性质。 该组合物可用作玻璃纤维绝缘的粘合剂，用于制造透明或半透明纸并制造用于复印机的纸。