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    Dendritic macomolecule and a process for the preparation thereof
    3.
    发明授权
    Dendritic macomolecule and a process for the preparation thereof 失效
    树枝状大分子及其制备方法

    公开(公告)号：US5698662A

    公开(公告)日：1997-12-16

    申请号：US686948

    申请日：1996-07-26

    申请人： Christiaan J. C. Stoelwinder ,  Ellen M. M. de Brabander-van den Berg ,  Atze J. Nijenhuis

    发明人： Christiaan J. C. Stoelwinder ,  Ellen M. M. de Brabander-van den Berg ,  Atze J. Nijenhuis

    IPC分类号： C08G73/00 ,  C08G73/02 ,  C08G73/06 ,  C08G83/00 ,  C08L101/00 ,  C09D201/00 ,  C08G63/44

    CPC分类号： C08G83/003 ,  C08G73/0213 ,  C08G73/065 ,  C08L101/005 ,  C09D201/005

    摘要： The invention relates to a dendritic macromolecule with branches prepared from halogen cyanide units composed of a monohalogenated hydrocarbon compound comprising 3-50 carbon atoms and at least one cyanide group, the halogen and the cyanide group being separated from one another by at least 3 carbon atoms. The invention also relates to a process for the preparation of a dendritic macromolecule, comprising a core and at least one branch emanating from the core, characterized in that the process comprises the steps a) through c): a) substantially every functional group of the core molecule is reacted with monomeric halogen cyanide units b) substantially every incorporated cyanide group is reduced to an amine c) substantially every amine group is reacted with monomeric halogen cyanide units, steps b) and c) being conducted alternately.

    摘要翻译： 本发明涉及一种具有由卤素氰化物单元制备的分枝的树枝状高分子，所述卤素氰化物单元由包含3-50个碳原子和至少一个氰化物基团的单卤代烃化合物组成，所述卤素和所述氰化物基彼此分开至少3个碳原子 。 本发明还涉及一种制备树突状高分子的方法，该方法包括核心和从核心发出的至少一个分支，其特征在于该方法包括步骤a）至c）：a）基本上每个功能基团 核心分子与单体卤素氰化物单元反应b）基本上每个引入的氰基都被还原成胺c）基本上每个胺基与单体卤素氰化物单元反应，步骤b）和c）交替进行。

    CLASS E SEGMENT CABLES AND TUBES
    5.
    发明申请
    CLASS E SEGMENT CABLES AND TUBES 有权
    E类分段电缆和管

    公开(公告)号：US20110003103A1

    公开(公告)日：2011-01-06

    申请号：US12743863

    申请日：2008-11-11

    申请人： Hendricus F. Aussems ,  Atze J. Nijenhuis ,  Beert J. Keestra

    发明人： Hendricus F. Aussems ,  Atze J. Nijenhuis ,  Beert J. Keestra

    IPC分类号： B32B1/08 ,  B32B27/08 ,  C08G18/40 ,  C08L75/08 ,  H01B3/30

    CPC分类号： C08G18/44 ,  C08L67/02 ,  C08L75/04 ,  C08L75/06 ,  Y10T428/139 ,  C08L2666/18 ,  C08L67/00

    摘要： The invention relates the use of a copolyester elastomer comprising hard blocks comprising polyester segments, polymeric soft blocks and urethane linkages, in applications with a thermal overload requirement specifying a thermal overload temperature above the melting temperature of the copolyester elastomer. The invention also relates to films as well as tubes and electrical cables, such as convoluted tubes and electrical cables for use in cable harness systems. The invention more further relates to polymeric materials with high heat properties that can be used in the tubes and cables and to tubes and cables at least comprising a layer consisting of the polymeric materials.

    摘要翻译： 本发明涉及包含聚酯链段，聚合物软嵌段和氨基甲酸酯键的硬块的共聚聚酯弹性体的应用，其中热过载要求规定热过载温度高于共聚酯弹性体的熔融温度。 本发明还涉及膜以及管和电缆，例如用于电缆线束系统中的回旋管和电缆。 本发明还涉及具有高热性质的聚合材料，其可用于管和电缆以及至少包括由聚合材料组成的层的管和电缆。

    Intrinsically gel-free, randomly branched polyamide
    7.
    发明授权
    Intrinsically gel-free, randomly branched polyamide 有权
    本质上无凝胶，无规分支的聚酰胺

    公开(公告)号：US06835799B2

    公开(公告)日：2004-12-28

    申请号：US09882298

    申请日：2001-06-18

    申请人： Atze J. Nijenhuis ,  René Aberson ,  Boudewijn J. R. Scholtens

    发明人： Atze J. Nijenhuis ,  René Aberson ,  Boudewijn J. R. Scholtens

    IPC分类号： C08G6908

    CPC分类号： C08J5/18 ,  C08G69/08 ,  C08G69/16 ,  C08G69/48 ,  C08J2377/06 ,  Y10T428/29 ,  Y10T428/2967 ,  Y10T428/2969

    摘要： The invention relates to a randomly branched polyamide comprising at least units derived from: 1. AB monomers, 2. at least one compound I, being a carboxylic acid (Av) having a functionality v≧2 or an amine (Bw) having a functionality w≧2, 3. at least one compound II, being a carboxylic acid (Av) having a functionality v≧3 or an amine (Bw) having a functionality w≧3, compound II being a carboxylic acid if compound I is an amine or compound II being an amine if compound I is a carboxylic acid and the amounts of all units derived from carboxylic acids and amines in the polyamide satisfying conditions as mentioned in claim 1. The composition of the randomly branched polyamide is such that it cannot form a crosslinked polyamide (and thus no gels, either), in particular during the prepolymerization, the polymerization, the post-condensation, the processing and the storage of the randomly branched polyamide, and this at a variety of ambient factors, for instance at elevated temperature and pressure. The polyamide is eminently suitable for the production of fiber and film, in particular for flat film.

    摘要翻译： 本发明涉及至少包含衍生自以下的单元的无规分支的聚酰胺：1。 AB单体，2。 至少一种化合物I是具有官能度≥2的羧酸（Av）或官能度≥2的胺（Bw）。 至少一种化合物II是官能度≥3的羧酸（Av）或官能度≥3的胺（Bw），如果化合物I是胺或化合物II，化合物II是羧酸 胺，如果化合物I是羧酸，并且在聚酰胺中衍生自羧酸和胺的所有单元的量满足权利要求1中所述的条件。无规分支的聚酰胺的组成使得它不能形成交联的聚酰胺（和 因此，也不需要凝胶），特别是在预聚合期间，聚合，后缩合，加工和无规分支的聚酰胺的储存，以及在各种环境因素下，例如在升高的温度和压力下。 聚酰胺特别适用于生产纤维和薄膜，尤其适用于平板薄膜。

    Fibers of strongly branched polyamide
    8.
    发明授权
    Fibers of strongly branched polyamide 失效
    强支化聚酰胺纤维

    公开(公告)号：US6051312A

    公开(公告)日：2000-04-18

    申请号：US205174

    申请日：1998-12-04

    申请人： Jan E. F. Arnauts ,  Atze J. Nijenhuis ,  Ellen M. M. de Brabander-ven den Berg ,  Cornelis Versluis ,  Martien Serne

    发明人： Jan E. F. Arnauts ,  Atze J. Nijenhuis ,  Ellen M. M. de Brabander-ven den Berg ,  Cornelis Versluis ,  Martien Serne

    IPC分类号： C08G69/02 ,  C08G69/26 ,  D02G3/00

    CPC分类号： C08G69/02 ,  C08G69/26 ,  Y10T428/2913 ,  Y10T428/2969

    摘要： The invention relates to a polyamide fiber whose polyamide is heavily branched. The branched polyamide preferably has 3-20 branches which are joined to a core molecule which is smaller than the polyamide arms. The arms originate preferably from functional groups which are identical and are preferably carboxyl groups. The polyamide is chosen from the group of polyamides which are produced by polycondensation of .alpha.,.omega.-aminocarboxylic acids or by ring-opening polymerization of lactams. Preferably, the polyamide is nylon-6. The properties of the fiber according to the invention are at least at the same level as those of fibers obtained by spinning linear polyamide. The spinning process for the fiber according to the invention is less susceptible to faults. Inter alia, the viscosity of the polyamide no longer changes during the spinning process.

    摘要翻译： 本发明涉及一种聚酰胺纤维，其聚酰胺是重枝状的。 支链聚酰胺优选具有3-20个分支，其与小于聚酰胺臂的芯分子连接。 臂优选来自相同且优选为羧基的官能团。 聚酰胺选自通过α，ω-氨基羧酸的缩聚或通过内酰胺的开环聚合制备的聚酰胺。 优选地，聚酰胺是尼龙-6。 根据本发明的纤维的性质至少与通过纺丝线性聚酰胺获得的纤维的性质相同。 根据本发明的纤维的纺丝方法不太容易发生故障。 特别地，聚酰胺的粘度在纺丝过程中不再改变。

    Automotive cable harness having class E segment cables and/or tubes
    9.
    发明授权
    Automotive cable harness having class E segment cables and/or tubes 有权
    具有E级分段电缆和/或管的汽车电缆线束

    公开(公告)号：US08287972B2

    公开(公告)日：2012-10-16

    申请号：US12743863

    申请日：2008-11-11

    申请人： Hendricus F. Aussems ,  Atze J. Nijenhuis ,  Beert J. Keestra

    发明人： Hendricus F. Aussems ,  Atze J. Nijenhuis ,  Beert J. Keestra

    IPC分类号： B29C47/00

    CPC分类号： C08G18/44 ,  C08L67/02 ,  C08L75/04 ,  C08L75/06 ,  Y10T428/139 ,  C08L2666/18 ,  C08L67/00

    摘要： The invention relates the use of a copolyester elastomer comprising hard blocks comprising polyester segments, polymeric soft blocks and urethane linkages, in applications with a thermal overload requirement specifying a thermal overload temperature above the melting temperature of the copolyester elastomer. The invention also relates to films as well as tubes and electrical cables, such as convoluted tubes and electrical cables for use in cable harness systems. The invention more further relates to polymeric materials with high heat properties that can be used in the tubes and cables and to tubes and cables at least comprising a layer consisting of the polymeric materials.

    摘要翻译： 本发明涉及包含聚酯链段，聚合物软嵌段和氨基甲酸酯键的硬块的共聚聚酯弹性体的应用，其中热过载要求规定热过载温度高于共聚酯弹性体的熔融温度。 本发明还涉及膜以及管和电缆，例如用于电缆线束系统中的回旋管和电缆。 本发明还涉及具有高热性质的聚合材料，其可用于管和电缆以及至少包括由聚合材料组成的层的管和电缆。

    Copolymer of lactone and carbonate and process for the preparation of such a copolymer
    10.
    发明授权
    Copolymer of lactone and carbonate and process for the preparation of such a copolymer 失效
    内酯和碳酸酯的共聚物和制备这种共聚物的方法

    公开(公告)号：US5492997A

    公开(公告)日：1996-02-20

    申请号：US256007

    申请日：1994-06-17

    申请人： Dirk W. Grijpma ,  Erik Kroeze ,  Atze J. Nijenhuis ,  Albertus J. Pennings

    发明人： Dirk W. Grijpma ,  Erik Kroeze ,  Atze J. Nijenhuis ,  Albertus J. Pennings

    IPC分类号： C07D319/08 ,  A61L31/06 ,  C08G63/64 ,  C08G64/00

    CPC分类号： C08G63/64 ,  A61L31/06

    摘要： A copolymer of a lactone and a polycyclic carbonate is prepared by heating a monomer of a lactone with a polycyclic carbonate having two cyclic structures including a carbonate group at elevated temperatures less than 200 degrees Centigrade in the presence of a catalyst. The described copolymers evidence excellent mechanical properties, good resorption velocity and do not disintegrate upon degradation into materials of high crystallinity.

    摘要翻译： PCT No.PCT / NL92 / 00234 Sec。 371日期：1994年6月17日 102（e）日期1994年6月17日PCT提交1992年12月21日PCT公布。 公开号WO93 / 13154 PCT。 日本7月8日，1993年。内酯和多环碳酸酯的共聚物是通过在低于200摄氏度的高温下，在具有碳酸酯基的多环碳酸酯的情况下，在具有两个碳酸酯基团的多环碳酸酯的条件下， 催化剂。 所述共聚物具有优异的机械性能，良好的吸收速度，并且在降解成高结晶度材料时不分解。