公开(公告)号：US20090047537A1

公开(公告)日：2009-02-19

申请号：US11920591

申请日：2006-05-19

申请人： Eiichi Nanba ,  Yuji Kubo ,  Kazutoshi Takeda ,  Satoshi Arai ,  Hotaka Honma ,  Kenichi Murakami ,  Hideyuki Kobayashi

发明人： Eiichi Nanba ,  Yuji Kubo ,  Kazutoshi Takeda ,  Satoshi Arai ,  Hotaka Honma ,  Kenichi Murakami ,  Hideyuki Kobayashi

IPC分类号： B32B15/00

CPC分类号： H01F1/14775 ,  C21D1/70 ,  C21D8/12 ,  C21D8/1283 ,  C22C38/02 ,  C22C38/04 ,  C22C38/60 ,  Y10T428/12007

摘要： The present invention provides oriented magnetic steel plate with excellent coating adhesion, in particular coating edge peeling resistance, that is, oriented magnetic steel plate with excellent coating adhesion containing, by mass %, Si: 1.8 to 7% and having a primary coating having forsterite as its main ingredient on its surface, said oriented magnetic steel plate characterized in that said primary coating contains one or more of Ce, La, Pr, Nd, Sc, and Y in an areal weight per side of 0.001 to 1000 mg/m2; characterized in that said primary coating contains Ti in an areal weight per side of 1 to 800 mg/m2; and characterized in that said primary coating contains one or more of Sr, Ca, and Ba in an areal weight per side of 0.01 to 100 mg/m2.

摘要翻译： 本发明提供了具有优异的涂层附着力，特别是涂覆边缘剥离性的取向磁性钢板，即具有优异的涂层粘合性的定向磁性钢板，以质量％计含有Si：1.8〜7％，并具有含镁橄榄石的初级涂层 作为其表面的主要成分，所述取向磁钢板的特征在于，所述初级涂层含有0.001至1000mg / m 2的每面重量的Ce，La，Pr，Nd，Sc和Y中的一种或多种; 其特征在于，所述初级涂层含有每面面积重量为1至800mg / m 2的Ti; 其特征在于，所述初级涂层含有每面面积重量为0.01至100mg / m 2的Sr，Ca和Ba中的一种或多种。

公开(公告)号：US07887646B2

公开(公告)日：2011-02-15

申请号：US11920591

申请日：2006-05-19

申请人： Eiichi Nanba ,  Yuji Kubo ,  Kazutoshi Takeda ,  Satoshi Arai ,  Hotaka Honma ,  Kenichi Murakami ,  Hideyuki Kobayashi

发明人： Eiichi Nanba ,  Yuji Kubo ,  Kazutoshi Takeda ,  Satoshi Arai ,  Hotaka Honma ,  Kenichi Murakami ,  Hideyuki Kobayashi

IPC分类号： H01F1/147

CPC分类号： H01F1/14775 ,  C21D1/70 ,  C21D8/12 ,  C21D8/1283 ,  C22C38/02 ,  C22C38/04 ,  C22C38/60 ,  Y10T428/12007

摘要： The present invention provides oriented magnetic steel plate with excellent coating adhesion, in particular coating edge peeling resistance, that is, oriented magnetic steel plate with excellent coating adhesion containing, by mass %, Si: 1.8 to 7% and having a primary coating having forsterite as its main ingredient on its surface, said oriented magnetic steel plate characterized in that said primary coating contains one or more of Ce, La, Pr, Nd, Sc, and Y in an areal weight per side of 0.001 to 1000 mg/m2; characterized in that said primary coating contains Ti in an areal weight per side of 1 to 800 mg/m2; and characterized in that said primary coating contains one or more of Sr, Ca, and Ba in an areal weight per side of 0.01 to 100 mg/m2.

摘要翻译： 本发明提供了具有优异的涂层附着力，特别是涂覆边缘剥离性的取向磁性钢板，即具有优异的涂层粘合性的定向磁性钢板，以质量％计含有Si：1.8〜7％，并具有含镁橄榄石的初级涂层 作为其表面的主要成分，所述取向磁钢板的特征在于，所述初级涂层含有0.001至1000mg / m 2的每面重量的Ce，La，Pr，Nd，Sc和Y中的一种或多种; 其特征在于，所述初级涂层含有每面面积重量为1至800mg / m 2的Ti; 其特征在于，所述初级涂层含有每面面积重量为0.01至100mg / m 2的Sr，Ca和Ba中的一种或多种。

公开(公告)号：US20080271819A1

公开(公告)日：2008-11-06

申请号：US12215540

申请日：2008-06-27

申请人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

发明人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

IPC分类号： C21D6/00 ,  C21D8/02

CPC分类号： C22C38/16 ,  C21D3/04 ,  C21D8/1244 ,  C21D8/1255 ,  C21D8/1266 ,  C21D8/1272 ,  C21D8/1277 ,  C21D8/1283 ,  C22C38/002 ,  C22C38/008 ,  C22C38/02 ,  C22C38/60 ,  H01F1/14775 ,  H01F1/18

摘要： The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, −10×ln(A)+1,100≦B≦10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec. or more before decarburization annealing, or immediately thereafter applying preliminary annealing for 1 to 20 sec. at 700° C. or higher; or controlling a TiO2 amount B added in relation to MgO of 100 as parts by weight and an MgO coating amount C (g/m2) so that the expression, A0.8≦B×C≦400, may be satisfied in accordance with the Bi content A (ppm).

公开(公告)号：US07981223B2

公开(公告)日：2011-07-19

申请号：US12215540

申请日：2008-06-27

申请人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

发明人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

IPC分类号： H01F1/147

CPC分类号： C22C38/16 ,  C21D3/04 ,  C21D8/1244 ,  C21D8/1255 ,  C21D8/1266 ,  C21D8/1272 ,  C21D8/1277 ,  C21D8/1283 ,  C22C38/002 ,  C22C38/008 ,  C22C38/02 ,  C22C38/60 ,  H01F1/14775 ,  H01F1/18

摘要： The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, −10×ln(A)+1,100≦B≦10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec. or more before decarburization annealing, or immediately thereafter applying preliminary annealing for 1 to 20 sec. at 700° C. or higher; or controlling a TiO2 amount B added in relation to MgO of 100 as parts by weight and an MgO coating amount C (g/m2) so that the expression, A0.8≦B×C≦400, may be satisfied in accordance with the Bi content A (ppm).

摘要翻译： 本发明是一种方向性电磁钢板，其特征在于，所述Bi在基板钢与晶粒取向电工钢板的一次膜的界面处的质量比为0.01〜小于1,000ppm。 晶粒取向电工钢板通过以下任一方法制造：在脱碳退火之前，进行1〜20秒的预退火。 在700℃以上，控制温度范围内的气氛; 控制最终冷轧前的最大达到温度B（℃），使得最大达到温度B可以满足以下表达式：-10×ln（A）+ 1,100＆nlE; B＆nlE; 10×ln（A）+1,220， 根据Bi含量A（ppm），同时在10秒内将冷轧至最终厚度的钢板加热至700℃以上。 或加热速率为100℃/秒。 或更多的脱碳退火之前，或者之后立即进行1〜20秒的预退火。 在700℃以上; 或控制相对于MgO添加的TiO 2量为100重量份，MgO涂布量C（g / m 2），使得可以根据下式求出A0.8＆nlE; B×C＆nlE; 400的表达式 Bi含量A（ppm）。

公开(公告)号：US07399369B2

公开(公告)日：2008-07-15

申请号：US10484347

申请日：2002-07-16

申请人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

发明人： Eiichi Nanba ,  Katsuyuki Yanagihara ,  Satoshi Arai ,  Shuichi Yamazaki ,  Fumikazu Ando ,  Kazutoshi Takeda ,  Yousuke Kurosaki ,  Nobuo Tachibana

IPC分类号： H01F1/147 ,  H01F1/18

CPC分类号： C22C38/16 ,  C21D3/04 ,  C21D8/1244 ,  C21D8/1255 ,  C21D8/1266 ,  C21D8/1272 ,  C21D8/1277 ,  C21D8/1283 ,  C22C38/002 ,  C22C38/008 ,  C22C38/02 ,  C22C38/60 ,  H01F1/14775 ,  H01F1/18

摘要： The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, −10×ln(A)+1,100≦B≦10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec. or more before decarburization annealing, or immediately thereafter applying preliminary annealing for 1 to 20 sec. at 700° C. or higher; or controlling a TiO2 amount B added in relation to MgO of 100 as parts by weight and an MgO coating amount C (g/m2) so that the expression, A0.8≦B×C≦400, may be satisfied in accordance with the Bi content A (ppm).

摘要翻译： 本发明是一种方向性电磁钢板，其特征在于，所述Bi在基板钢与晶粒取向电工钢板的一次膜的界面处的质量比为0.01〜小于1,000ppm。 晶粒取向电工钢板通过以下任一方法制造：在脱碳退火之前，进行1〜20秒的预退火。 在700℃以上，控制温度范围内的气氛; 控制最终冷轧前的最大达到温度B（℃），使得最大达到温度B可以满足以下表达式：-10×ln（A）+1,100 <= B <= 10×ln（A）+1,220，根据 Bi含量A（ppm），同时在10秒内将钢板冷轧至最终厚度至700℃以上。 或加热速率为100℃/秒。 或更多的脱碳退火之前，或者之后立即进行1〜20秒的预退火。 在700℃以上; 或控制相对于MgO为100重量份的TiO 2 B量和MgO涂布量C（g / m 2 O 2），使得表达式A 根据Bi含量A（ppm）可以满足0.8≤BxC≤400。

公开(公告)号：US20120171467A1

公开(公告)日：2012-07-05

申请号：US13395993

申请日：2010-09-02

申请人： Kazutoshi Takeda ,  Kenji Kosuge ,  Satoshi Arai ,  Kiyokazu Ishizuka

发明人： Kazutoshi Takeda ,  Kenji Kosuge ,  Satoshi Arai ,  Kiyokazu Ishizuka

IPC分类号： B32B5/16 ,  B05D3/02 ,  B05D3/00 ,  B05D5/00

CPC分类号： H01F1/18 ,  B05D3/0254 ,  C09D5/084 ,  H01F1/147 ,  H01F1/14775 ,  H02K1/12 ,  Y10T428/254

摘要： An electrical steel sheet (10) is provided with a base iron (1) and an insulating film (2) formed on a surface of the base iron (1). The insulating film (2) includes 100 parts by mass of a first component containing a metal phosphate, and 5 parts by mass to 45 parts by mass of a second component composed of particles of one or more kinds selected from a group consisting of a polyolefin wax, an epoxy resin and an acrylic resin, the particles having an average particle size of 2.0 μm to 15.0 μm and a melting point of 60° C. to 140° C.

摘要翻译： 电动钢板（10）在基座铁（1）的表面形成有基础铁（1）和绝缘膜（2）。 绝缘膜（2）包括100质量份含有金属磷酸盐的第一成分和5质量份〜45质量份由选自聚烯烃中的一种以上的一种以上的粒子构成的第二成分 蜡，环氧树脂和丙烯酸树脂，所述颗粒的平均粒径为2.0μm至15.0μm，熔点为60℃至140℃。

公开(公告)号：US06461741B1

公开(公告)日：2002-10-08

申请号：US09661003

申请日：2000-09-13

申请人： Kazutoshi Takeda ,  Shuichi Yamazaki ,  Hideyuki Kobayashi ,  Hiroyasu Fujii

发明人： Kazutoshi Takeda ,  Shuichi Yamazaki ,  Hideyuki Kobayashi ,  Hiroyasu Fujii

IPC分类号： B32B1504

CPC分类号： C23C28/044 ,  C04B28/346 ,  C04B2111/00525 ,  C21D8/1283 ,  C21D8/1288 ,  C23C22/08 ,  C23C22/33 ,  C23C22/74 ,  H01F1/14783 ,  H01F1/18 ,  Y10S428/90 ,  Y10S428/928 ,  Y10T428/12993 ,  Y10T428/32 ,  C04B14/06 ,  C04B14/307 ,  C04B40/0263 ,  C04B41/5006 ,  C04B41/0072

摘要： A high permeability grain-oriented electromagnetic steel sheet with a higher tension-imparting effect and more excellent cohesion and magnetic properties compared to the prior art, which also maintains sufficient corrosion resistance to withstand practical use; the grain-oriented electromagnetic steel sheet has on its surface an insulation coating comprising a first layer composed mainly of a divalent or trivalent metal hydrogen phosphate salt and silica, and a second layer composed mainly of aluminum borate and leaving a surface roughness of 0.1 &mgr;m-0.35 &mgr;m in terms of Ra (center like average roughness).

摘要翻译： 与现有技术相比，具有更高的张力赋予效果和更优异的内聚力和磁特性的高磁导率晶粒取向电磁钢板，其也保持足够的耐腐蚀性以抵抗实际应用; 晶粒取向电磁钢板表面具有包含主要由二价或三价金属磷酸氢盐和二氧化硅组成的第一层的绝缘层，以及主要由硼酸铝组成的第二层，表面粗糙度为0.1μm- 以Ra计为0.35μm（中心像平均粗糙度）。

公开(公告)号：US09051622B2

公开(公告)日：2015-06-09

申请号：US13256166

申请日：2010-03-09

申请人： Satoshi Arai ,  Yasuhide Morimoto ,  Kiyokazu Ishizuka ,  Kazutoshi Takeda

发明人： Satoshi Arai ,  Yasuhide Morimoto ,  Kiyokazu Ishizuka ,  Kazutoshi Takeda

IPC分类号： B21B1/08 ,  C21D6/00 ,  C21D8/12 ,  C22C38/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/12 ,  H01F1/16

CPC分类号： C21D6/008 ,  B21B1/08 ,  C21D6/005 ,  C21D8/1222 ,  C21D8/1233 ,  C21D8/1272 ,  C21D8/1277 ,  C21D8/1283 ,  C21D2201/05 ,  C22C38/004 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/12 ,  C23C2/02 ,  C23C2/28 ,  C25D5/50 ,  C25D7/0614 ,  H01F1/16 ,  Y10T428/12458

摘要： A non-oriented magnetic steel sheet contains, by mass %, C: 0.005% or less; Si: 2% to 4%; Mn and V: totally 11% or less; and Al: 3% or less, with the balance being Fe and inevitable impurities, wherein a Mn concentration (mass %) and a V concentration (mass %) in a thickness direction satisfy the following formula. 0.1

摘要翻译： 无取向电磁钢板以质量％计含有C：0.005％以下; Si：2％〜4％; Mn和V：总共为11％以下; 和Al：3％以下，余量为Fe和不可避免的杂质，其中厚度方向的Mn浓度（质量％）和V浓度（质量％）满足下式。 0.1 <（XsMn，V-XcMn，V）/ tMn，V <100，其中XsMn，V：钢板表面的Mn浓度（质量％）和V浓度（质量％）之和，XcMn ，V：钢板中心处的Mn浓度（质量％）和V浓度（质量％）之和，tMn，V：来自钢板表面的深度（mm）， Mn浓度（质量％）和V浓度（质量％）之和等于XcMn，V的位置。

公开(公告)号：US20120009436A1

公开(公告)日：2012-01-12

申请号：US13256166

申请日：2010-03-09

申请人： Satoshi Arai ,  Yasuhide Morimoto ,  Kiyokazu Ishizuka ,  Kazutoshi Takeda

发明人： Satoshi Arai ,  Yasuhide Morimoto ,  Kiyokazu Ishizuka ,  Kazutoshi Takeda

IPC分类号： B32B5/14 ,  B21B1/08

CPC分类号： C21D6/008 ,  B21B1/08 ,  C21D6/005 ,  C21D8/1222 ,  C21D8/1233 ,  C21D8/1272 ,  C21D8/1277 ,  C21D8/1283 ,  C21D2201/05 ,  C22C38/004 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/12 ,  C23C2/02 ,  C23C2/28 ,  C25D5/50 ,  C25D7/0614 ,  H01F1/16 ,  Y10T428/12458

摘要： A non-oriented magnetic steel sheet contains, by mass %, C: 0.005% or less; Si: 2% to 4%; Mn and V: totally 11% or less; and Al: 3% or less, with the balance being Fe and inevitable impurities, wherein a Mn concentration (mass %) and a V concentration (mass %) in a thickness direction satisfy the following formula. 0.1

摘要翻译： 无取向电磁钢板以质量％计含有C：0.005％以下; Si：2％〜4％; Mn和V：总共为11％以下; 和Al：3％以下，余量为Fe和不可避免的杂质，其中厚度方向的Mn浓度（质量％）和V浓度（质量％）满足下式。 0.1 <（XsMn，V-XcMn，V）/ tMn，V <100，其中XsMn，V：钢板表面的Mn浓度（质量％）和V浓度（质量％）之和，XcMn ，V：钢板中心处的Mn浓度（质量％）和V浓度（质量％）之和，tMn，V：来自钢板表面的深度（mm）， Mn浓度（质量％）和V浓度（质量％）之和等于XcMn，V的位置。

公开(公告)号：US11377569B2

公开(公告)日：2022-07-05

申请号：US13809279

申请日：2011-07-15

申请人： Kazutoshi Takeda ,  Kenji Kosuge ,  Tatsuya Takase ,  Kohji Muneda

发明人： Kazutoshi Takeda ,  Kenji Kosuge ,  Tatsuya Takase ,  Kohji Muneda

IPC分类号： C09D7/61 ,  C21D8/12 ,  C21D9/46 ,  H01F1/18 ,  C09D5/08 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  B05D7/14 ,  C23C22/74 ,  C09D7/65 ,  C09D7/40 ,  H01B7/02 ,  C09D1/00 ,  C09D127/18 ,  C09D167/00 ,  C09D127/12 ,  C09D133/00 ,  C09D163/00 ,  C09D127/04 ,  C08K3/22 ,  C08K3/02 ,  B05D3/02

摘要： An electrical steel sheet (10) is provided with a base iron (1) and an insulating film (2) formed on a surface of the base iron (1). The insulating film (2) contains: a first component: 100 parts by mass, the first component containing: a metal phosphate: 100 parts by mass; and one kind selected from a group consisting of an acrylic resin, an epoxy resin and a polyester resin which have an average particle size of 0.05 μm to 0.50 μm, or a mixture or copolymer of two or three kinds selected from the group: 1 part by mass to 50 parts by mass; and a second component composed of dispersion or powder of a fluorine resin having an average particle size of 0.05 μm to 0.35 μm: 0.5 parts by mass to 10 parts by mass.