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公开(公告)号：US4234452A
公开(公告)日：1980-11-18
申请号：US23559
申请日：1979-03-26
申请人： Emmett H. Burk, Jr. , Jin S. Yoo , Jui-Yuan Sun , John A. Karch
发明人： Emmett H. Burk, Jr. , Jin S. Yoo , Jui-Yuan Sun , John A. Karch
IPC分类号： B01J21/20 , B01J29/90 , C10G11/02 , C10G35/06 , C10G49/02 , B01J29/38 , C10G11/04 , C10G11/05
摘要： An improved demetallization process is disclosed comprising high pressure aqueous phase oxidation of a catalyst contaminated with a metal such as nickel, vanadium, copper and/or iron. The metal-contaminated catalyst can be oxidized in an aqueous phase at high pressure either before regeneration or subsequent to regeneration. Optionally, an oxidative and reductive wash can also be employed.
摘要翻译： 公开了一种改进的脱金属工艺，其包括被金属如镍，钒，铜和/或铁污染的催化剂的高压水相氧化。 金属污染的催化剂可以在再生之前或再生之后在高压下在水相中氧化。 任选地，还可以使用氧化还原洗涤。
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公开(公告)号：US4267032A
公开(公告)日：1981-05-12
申请号：US81724
申请日：1979-10-04
申请人： Emmett H. Burk, Jr. , Jin S. Yoo , John A. Karch , Jui-Yuan Sun
发明人： Emmett H. Burk, Jr. , Jin S. Yoo , John A. Karch , Jui-Yuan Sun
IPC分类号： B01J21/20 , B01J29/90 , C10G11/02 , C10G35/06 , C10G49/02 , C10G11/00 , B01J29/38 , C10G11/05
摘要： Disclosed is an aqueous phase oxidation for removing at least a portion of metal contaminants such as nickel, vanadium, iron or copper from a catalyst used in a hydrocarbon conversion process. The aqueous phase oxidation comprises: contacting a sulfided metals contaminated catalyst with an aqueous solution comprising soluble metal nitrate ions and a catalytically effective concentration of nitrite ions. Optionally, the sulfided catalyst which has been oxidized can be further treated with an aqueous oxidative and/or reductive wash. The oxidative wash preferably follows the reductive wash for optimal results.
摘要翻译： 公开了用于从烃转化过程中使用的催化剂除去至少一部分金属污染物如镍，钒，铁或铜的水相氧化。 水相氧化包括：使硫化金属污染的催化剂与包含可溶性金属硝酸根离子和催化有效浓度的亚硝酸根离子的水溶液接触。 任选地，已经被氧化的硫化催化剂可以用水性氧化和/或还原性洗涤液进一步处理。 氧化洗涤优选地遵循还原洗涤以获得最佳结果。
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3.发明授权Catalyst demetallization by converting the metal poisons to a sulfur containing metal compound having a defined low amount of sulfur 失效通过将金属毒物转化为具有确定的低量硫的含硫金属化合物来进行催化剂脱金属化
公开(公告)号：US4293403A
公开(公告)日：1981-10-06
申请号：US756581
申请日：1977-01-03
申请人： Emmett H. Burk, Jr. , Jin S. Yoo , John A. Karch , Jui-Yuan Sun
发明人： Emmett H. Burk, Jr. , Jin S. Yoo , John A. Karch , Jui-Yuan Sun
CPC分类号： B01J29/90 , B01J21/20 , B01J37/20 , C10G11/04 , Y10S502/521
摘要： A process for the removal of metal poisons such as nickel, iron and/or vanadium from a hydrocarbon conversion catalyst which includes the step of contacting the catalyst with a sulfur-containing compound to convert at least a portion of the metals on the catalyst to a sulfur-containing metal compound. The weight % sulfur on the thus treated catalyst is controlled to about 40-90%, preferably about 40-75%, of the weight % of the total nickel, vanadium and iron on the catalyst. Preferably, the sulfur-containing compound is hydrogen sulfide in admixture with a reducing gas such as hydrogen and/or carbon monoxide. This step facilitates metal removal in subsequent processing steps.
摘要翻译： 一种用于从烃转化催化剂中除去诸如镍，铁和/或钒的金属毒物的方法，该方法包括使催化剂与含硫化合物接触以将至少一部分催化剂上的金属转化为 含硫金属化合物。 这样处理的催化剂上的重量％硫被控制在催化剂上总镍，钒和铁的重量％的约40-90％，优选约40-75％。 优选地，含硫化合物是与还原气体如氢气和/或一氧化碳混合的硫化氢。 该步骤有助于后续加工步骤中的金属去除。
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公开(公告)号：US4295858A
公开(公告)日：1981-10-20
申请号：US126248
申请日：1980-03-03
摘要： A process for reducing the sulfur and ash content of coal comprising the steps of: (1) contacting coal particles containing ash and iron pyrite mineral matter with a promoting amount of at least one conditioning agent, said conditioning agent having a ferrous component maintained at a pH of from about 5.5 to 11.0 and being capable of modifying or altering the existing surface characteristics of the pyrite under conditions to effectuate alteration of modification of at least a portion of the contained pyritic sulfur; (2) agglomerating the coal particles while said pyrite surfaces are altered or modified in an aqueous medium with hydrocarbon oil to form coal-hydrocarbon oil agglomerates; (3) separating said coal-hydrocarbon oil agglomerates from pyrite mineral matter and ash to recover coal-hydrocarbon oil agglomerates wherein the coal exhibits reduced sulfur and ash content.
摘要翻译： 一种减少煤的硫和灰分含量的方法，包括以下步骤：（1）使含有灰分和铁黄铁矿矿物质的煤颗粒与促进量的至少一种调节剂接触，所述调理剂具有维持在 pH为约5.5至11.0，并且在条件下能够改变或改变黄铁矿的现有表面特性，以实现至少部分含硫黄硫的改性改性; （2）在含烃油的含水介质中改变或改性所述黄铁矿表面的同时使煤颗粒凝聚，形成煤 - 烃油附聚物; （3）将煤 - 烃油附聚物与黄铁矿矿物和灰分离，以回收煤 - 烃油附聚物，其中煤表现出降低的硫和灰分含量。
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公开(公告)号：US4255156A
公开(公告)日：1981-03-10
申请号：US32301
申请日：1979-04-23
CPC分类号： C10L9/00
摘要： A process for reducing the sulfur and ash content of coal comprising: treating coal particles in a hydrocarbon oil slurry with minor amounts of a conditioning agent and water to effect agglomeration of ash and pyritic sulfur mineral matter; separating the agglomerates from the slurried coal particles; and recovering coal particles from the hydrocarbon oil.
摘要翻译： 一种减少煤的硫和灰分含量的方法，包括：用少量的调节剂和水处理烃油浆中的煤颗粒，以实现灰分和黄铁矿硫矿物的附聚; 将凝聚物与浆状煤颗粒分离; 并从烃油中回收煤颗粒。
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公开(公告)号：US4174953A
公开(公告)日：1979-11-20
申请号：US866589
申请日：1978-01-03
CPC分类号： C10L9/02 , Y10S44/905
摘要： A process for reducing the sulfur content of coal comprising the steps of:(1) contacting coal particles with(i) a silicate selected from the group consisting of alkali metal silicates, alkaline earth metal silicates and mixtures thereof, and(ii) a promoter material capable of oxidizing or reducing equilibrium sulfur reaction products formed by the contacting to non-equilibrium reaction products in an aqueous medium to reduce the sulfur content of coal; and(2) recovering coal particles of reduced sulfur content.
摘要翻译： 一种降低煤的硫含量的方法，包括以下步骤：（1）使煤颗粒与（i）选自碱金属硅酸盐，碱土金属硅酸盐及其混合物的硅酸盐接触，和（ii） 能够氧化或还原通过在水介质中与非平衡反应产物接触形成的平衡硫反应产物以降低煤的硫含量的材料; 和（2）回收硫含量降低的煤颗粒。
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公开(公告)号：US4249910A
公开(公告)日：1981-02-10
申请号：US944452
申请日：1978-09-21
CPC分类号： C10L9/00
摘要： A process for reducing the sulfur and ash content of coal comprising the steps of:(1) contacting coal particles containing ash and iron pyrite mineral matter with a promoting amount of at least one conditioning agent capable of modifying or altering the existing surface characteristics of the pyrite under conditions to effectuate alteration or modification of at least a portion of the contained pyritic sulfur;(2) agglomerating the coal particles while said surfaces are altered or modified in an aqueous medium with hydrocarbon oil; and(3) recovering coal hydrocarbon oil agglomerates wherein the coal exhibits reduced sulfur and ash content.
摘要翻译： 一种减少煤的硫和灰分含量的方法，包括以下步骤：（1）使含有灰分和铁黄铁矿矿物质的煤颗粒与促进量的至少一种调节剂接触，所述调节剂能够改变或改变现有的表面特性 黄铁矿在条件下进行至少部分含硫黄硫的改变或改性; （2）在具有烃油的水性介质中改变或改性所述表面时，使煤颗粒凝聚; 和（3）回收煤炭烃油附聚物，其中煤表现出降低的硫和灰分含量。
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8.发明授权Process for removing sulfur from coal employing aqueous solutions of sulfites and bisulfites 失效使用亚硫酸盐和亚硫酸氢盐的水溶液从煤中除去硫的方法
公开(公告)号：US4155717A
公开(公告)日：1979-05-22
申请号：US866592
申请日：1978-01-03
申请人： Jui-Yuan Sun , Jin S. Yoo , Emmett H. Burk, Jr.
发明人： Jui-Yuan Sun , Jin S. Yoo , Emmett H. Burk, Jr.
CPC分类号： C10L9/02
摘要： A process for reducing the sulfur content of coal comprising the steps of:(1) contacting coal particles with an aqueous solution of compositions selected from the group comprising alkali metal and alkaline earth metal sulfites and bisulfites to reduce the sulfur content of the coal; and(2) recovering coal particles of reduced sulfur content.
摘要翻译： 一种降低煤的硫含量的方法，包括以下步骤：
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公开(公告)号：US4448584A
公开(公告)日：1984-05-15
申请号：US175983
申请日：1980-08-07
摘要： A process for reducing the sulfur and ash content of coal comprising the steps of:(1) contacting coal particles containing ash and iron pyrite mineral matter with a promoting amount of at least one conditioning agent capable of modifying or altering the existing surface characteristics of the pyrite under conditions to effectuate alteration or modification of at least a portion of the contained pyritic sulfur;(2) separating the coal particles from at least a portion of the pyritic sulfur while surface characteristics are altered or modified; and(3) recovering coal particles wherein the coal exhibits reduced sulfur and ash content.
摘要翻译： 一种减少煤的硫和灰分含量的方法，包括以下步骤：（1）使含有灰分和铁黄铁矿矿物质的煤颗粒与促进量的至少一种调节剂接触，所述调节剂能够改变或改变现有的表面特性 黄铁矿在条件下进行至少部分含硫黄硫的改变或改性; （2）将煤粒子与至少一部分黄铁矿硫分离，同时改变或改变表面特性; 和（3）回收煤颗粒，其中煤表现出降低的硫和灰分含量。
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公开(公告)号：US4155716A
公开(公告)日：1979-05-22
申请号：US866590
申请日：1978-01-03
CPC分类号： C10L9/02
摘要： A process for reducing the sulfur content of coal comprising the steps of:(1) contacting coal particles with a silicate selected from the group consisting of alkali metal silicates, alkaline earth metal silicates and mixtures thereof in an aqueous medium to reduce the sulfur content of the coal; and(2) recovering coal particles of reduced sulfur content.
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