公开(公告)号：US11600864B2

公开(公告)日：2023-03-07

申请号：US17556152

申请日：2021-12-20

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Ken S. Matsubayashi ,  Jeremie J. Dalton ,  Jason Newton Howard ,  Robert Keith Rosen

IPC: H01M10/0585 ,  H01M50/40 ,  H01M50/531

Abstract: A secondary battery for cycling between a charged and a discharged state, wherein a 2D map of the median vertical position of the first opposing vertical end surface of the electrode active material in the X-Z plane, along the length LE of the electrode active material layer, traces a first vertical end surface plot, EVP1, a 2D map of the median vertical position of the first opposing vertical end surface of the counter-electrode active material layer in the X-Z plane, along the length LC of the counter-electrode active material layer, traces a first vertical end surface plot, CEVP1, wherein for at least 60% of the length Lc of the first counter-electrode active material layer (i) the absolute value of a separation distance, SZ1, between the plots EVP1 and CEVP1 measured in the vertical direction is 1000 μm≥|SZ1|≥5 μm.

公开(公告)号：US11081718B2

公开(公告)日：2021-08-03

申请号：US16241159

申请日：2019-01-07

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Vladimir Dioumaev

IPC: H01M10/02 ,  H01M4/02 ,  H01M10/052 ,  H01M10/054 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/44 ,  H01M10/0525

Abstract: A secondary battery is provided for cycling between a charged and a discharged state, the secondary battery including a battery enclosure, an electrode assembly, carrier ions, a non-aqueous liquid electrolyte within the battery enclosure, and a set of electrode constraints. The set of electrode constraints includes a primary constraint system having first and second primary growth constraints and at least one primary connecting member, the first and second primary growth constraints separated from each other in the longitudinal direction, wherein the primary constraint array restrains growth of the electrode assembly in the longitudinal direction such that any increase in the Feret diameter of the electrode assembly in the longitudinal direction over 20 consecutive cycles of the secondary battery is less than 20%. The set of electrode constraints further includes a secondary constraint system having first and second secondary growth constraints connected by at least one secondary connecting member, wherein the secondary constraint system at least partially restrains growth of the electrode assembly in a second direction upon cycling of the secondary battery.

公开(公告)号：US12206106B2

公开(公告)日：2025-01-21

申请号：US17674133

申请日：2022-02-17

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Ken S. Matsubayashi ,  Jeremie J. Dalton ,  Jason Newton Howard ,  Robert Keith Rosen ,  Jonathan C. Doan ,  Michael J. Armstrong ,  Anthony Calcaterra ,  Benjamin L. Cardozo ,  Joshua David Winans ,  Neelam Singh ,  Jeffrey Glenn Buck ,  Thomas John Schuerlein ,  Kim Lester Fortunati ,  Neal Sarswat

IPC: H01M4/525 ,  H01M4/02 ,  H01M4/134 ,  H01M4/38 ,  H01M4/48 ,  H01M4/66 ,  H01M10/04 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/0565 ,  H01M10/0585 ,  H01M50/103 ,  H01M50/46 ,  H01M50/54

Abstract: Embodiments of secondary batteries having electrode assemblies are provided. A secondary battery can comprise an electrode assembly having a stacked series of layers, the stacked series of layers having an offset between electrode and counter-electrode layers in a unit cell member of the stacked series. A set of constraints can be provided with a primary constraint system with first and second primary growth constraints separated from each other in a longitudinal direction, and connected by at least one primary connecting member, and a secondary constraint system comprises first and second secondary growth constraints separated in a second direction and connected by members of the stacked series of layers. The primary constraint system may at least partially restrain growth of the electrode assembly in the longitudinal direction, and the secondary constraint system may at least partially restrain growth in the second direction that is orthogonal to the longitudinal direction.

公开(公告)号：US20240170714A1

公开(公告)日：2024-05-23

申请号：US18531197

申请日：2023-12-06

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali S. Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Ken S. Matsubayashi ,  Jeremie J. Dalton

IPC: H01M10/04 ,  H01M10/0525 ,  H01M50/446 ,  H01M50/491 ,  H01M4/02 ,  H01M50/414 ,  H01M50/417 ,  H01M50/426 ,  H01M50/497 ,  H01M50/55 ,  H01M50/553

CPC classification number: H01M10/0468 ,  H01M10/0525 ,  H01M50/446 ,  H01M50/491 ,  H01M2004/021 ,  H01M50/414 ,  H01M50/417 ,  H01M50/426 ,  H01M50/497 ,  H01M50/55 ,  H01M50/553

Abstract: A energy storage device for cycling between a charged state and a discharged state, the energy storage device including an enclosure, an electrode assembly and a non-aqueous liquid electrolyte within the enclosure, and a constraint that maintains a pressure on the electrode assembly as the energy storage device is cycled between the charged and the discharged states.

公开(公告)号：US11444310B2

公开(公告)日：2022-09-13

申请号：US17335725

申请日：2021-06-01

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Vladimir Dioumaev

IPC: H01M10/02 ,  H01M4/02 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/44

Abstract: A secondary battery is provided for cycling between a charged and a discharged state, the secondary battery including a battery enclosure, an electrode assembly, carrier ions, a non-aqueous liquid electrolyte within the battery enclosure, and a set of electrode constraints. The set of electrode constraints includes a primary constraint system having first and second primary growth constraints and at least one primary connecting member, the first and second primary growth constraints separated from each other in the longitudinal direction, wherein the primary constraint array restrains growth of the electrode assembly in the longitudinal direction such that any increase in the Feret diameter of the electrode assembly in the longitudinal direction over 20 consecutive cycles of the secondary battery is less than 20%. The set of electrode constraints further includes a secondary constraint system having first and second secondary growth constraints connected by at least one secondary connecting member, wherein the secondary constraint system at least partially restrains growth of the electrode assembly in a second direction upon cycling of the secondary battery.

公开(公告)号：US20240356093A1

公开(公告)日：2024-10-24

申请号：US18653761

申请日：2024-05-02

Applicant: Enovix Corporation

Inventor： Christopher G. Castledine ,  David T. Fouchard ,  Jonathan C. Doan ,  Christopher J. Spindt ,  Robert M. Spotnitz ,  James D. Wilcox ,  Ashok Lahiri ,  Murali Ramasubramanian

IPC: H01M10/44 ,  H01M4/38 ,  H01M10/0525 ,  H01M10/48

CPC classification number: H01M10/448 ,  H01M4/386 ,  H01M10/0525 ,  H01M10/446 ,  H01M10/48

Abstract: A method is provided for activating a secondary battery having a negative electrode, a positive electrode, and a microporous separator between the negative and positive electrodes permeated with carrier-ion containing electrolyte, the negative electrode having anodically active silicon or an alloy thereof. The method includes transferring carrier ions from the positive electrode to the negative electrode to at least partially charge the secondary battery, and transferring carrier ions from an auxiliary electrode to the positive electrode, to provide the secondary battery with a positive electrode end of discharge voltage Vpos,eod and a negative electrode end of discharge voltage Vneg,eod when the cell is at a predefined Vcell,eod value, the value of Vpos,eod corresponding to a voltage at which the state of charge of the positive electrode is at least 95% of its coulombic capacity and Vneg,eod is at least 0.4 V (vs Li) but less than 0.9 V (vs Li).

公开(公告)号：US20240213541A1

公开(公告)日：2024-06-27

申请号：US18399062

申请日：2023-12-28

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Murali S. Ramasubramanian ,  Bruno A. Valdes ,  James D. Wilcox ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  John F. Varni ,  Kim Han Lee ,  Richard J. Contreras ,  Thomas John Schuerlein ,  Ashok Lahiri

IPC: H01M10/058 ,  H01M10/04 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/42 ,  H01M50/489 ,  H01M50/491

CPC classification number: H01M10/058 ,  H01M10/049 ,  H01M10/0525 ,  H01M10/054 ,  H01M50/489 ,  H01M50/491 ,  H01M2010/4292

Abstract: A secondary battery for cycling between a charged and a discharged state is provided. The secondary battery has an electrode assembly having a population of anode structures, a population of cathode structures, and an electrically insulating microporous separator material. The electrode assembly also has a set of electrode constraints that at least partially restrains growth of the electrode assembly. Members of the anode structure population have a first cross-sectional area, A1 when the secondary battery is in the charged state and a second cross-sectional area, A2, when the secondary battery is in the discharged state, and members of the cathode structure population have a first cross-sectional area, C1 when the secondary battery is in the charged state and a second cross-sectional area, C2, when the secondary battery is in the discharged state, where A1 is greater than A2, and C1 is less than C2.

公开(公告)号：US11264680B2

公开(公告)日：2022-03-01

申请号：US16763110

申请日：2018-11-15

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Ken S. Matsubayashi ,  Jeremie J. Dalton ,  Jason Newton Howard ,  Robert Keith Rosen ,  Jonathan C. Doan ,  Michael J. Armstrong ,  Anthony Calcaterra ,  Benjamin L. Cardozo ,  Joshua David Winans ,  Neelam Singh ,  Jeffrey Glenn Buck ,  Thomas John Schuerlein ,  Kim Lester Fortunati ,  Neal Sarswat

IPC: H01M50/54 ,  H01M4/134 ,  H01M4/38 ,  H01M4/48 ,  H01M4/525 ,  H01M4/66 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/04 ,  H01M10/054 ,  H01M10/0585 ,  H01M50/46 ,  H01M50/103 ,  H01M4/02

Abstract: Embodiments of secondary batteries having electrode assemblies are provided. A secondary battery can comprise an electrode assembly having a stacked series of layers, the stacked series of layers having an offset between electrode and counter-electrode layers in a unit cell member of the stacked series. A set of constraints can be provided with a primary constraint system with first and second primary growth constraints separated from each other in a longitudinal direction, and connected by at least one primary connecting member, and a secondary constraint system comprises first and second secondary growth constraints separated in a second direction and connected by members of the stacked series of layers. The primary constraint system may at least partially restrain growth of the electrode assembly in the longitudinal direction, and the secondary constraint system may at least partially restrain growth in the second direction that is orthogonal to the longitudinal direction.

公开(公告)号：US10770760B2

公开(公告)日：2020-09-08

申请号：US15572191

申请日：2016-05-06

Applicant: Enovix Corporation

Inventor： Christopher G. Castledine ,  David T. Fouchard ,  Jonathan C. Doan ,  Christopher J. Spindt ,  Robert M. Spotniz ,  James D. Wilcox ,  Ashok Lahiri ,  Murali Ramasubramanian

IPC: H01M10/44 ,  H01M4/38 ,  H01M10/0525 ,  H01M10/48

Abstract: A method is provided for activating a secondary battery having a negative electrode, a positive electrode, and a microporous separator between the negative and positive electrodes permeated with carrier-ion containing electrolyte, the negative electrode having anodically active silicon or an alloy thereof. The method includes transferring carrier ions from the positive electrode to the negative electrode to at least partially charge the secondary battery, and transferring carrier ions from an auxiliary electrode to the positive electrode, to provide the secondary battery with a positive electrode end of discharge voltage Vpos,eod and a negative electrode end of discharge voltage Vneg,eod when the cell is at a predefined Vcell,eod value, the value of Vpos,eod corresponding to a voltage at which the state of charge of the positive electrode is at least 95% of its coulombic capacity and Vneg,eod is at least 0.4 V (vs Li) but less than 0.9 V (vs Li).

公开(公告)号：US10283807B2

公开(公告)日：2019-05-07

申请号：US15572722

申请日：2016-05-13

Applicant: Enovix Corporation

Inventor： Robert S. Busacca ,  Ashok Lahiri ,  Murali Ramasubramanian ,  Bruno A. Valdes ,  Gardner Cameron Dales ,  Christopher J. Spindt ,  Geoffrey Matthew Ho ,  Harrold J. Rust, III ,  James D. Wilcox ,  John F. Varni ,  Kim Han Lee ,  Nirav S. Shah ,  Richard J. Contreras ,  Lynn Van Erden ,  Ken S. Matsubayashi ,  Jeremie J. Dalton

IPC: H01M10/04 ,  H01M2/02 ,  H01M2/16 ,  H01M10/0525 ,  H01M4/02

Abstract: A energy storage device for cycling between a charged state and a discharged state, the energy storage device including an enclosure, an electrode assembly and a non-aqueous liquid electrolyte within the enclosure, and a constraint that maintains a pressure on the electrode assembly as the energy storage device is cycled between the charged and the discharged states.