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    Supported catalysts for the polymerization of olefins
    1.
    发明授权
    Supported catalysts for the polymerization of olefins 失效
    用于烯烃聚合的负载催化剂

    公开(公告)号：US06774194B2

    公开(公告)日：2004-08-10

    申请号：US10184679

    申请日：2002-06-26

    申请人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    发明人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    IPC分类号： C08F402

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/602 ,  C08F4/63916 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/20 ,  C08F210/08

    摘要： Supported catalysts for the polymerization of olefins comprise the following components: (A) a porous organic support functionalised with groups having active hydrogen atoms; (B) an organo-metallic compound of aluminium containing heteroatoms selected from oxygen, nitrogen and sulphur; and (C) a compound of a transition metal selected from those of groups IVb, Vb or VIb of the Periodic Table of the Elements, containing ligands of the cyclopentadienyl type. These supported catalysts, obtainable in the form of spherical particles, can be used in the polymerization reaction of olefins either in liquid or in gas phase, thus producing polymers endowed with a controlled morphology and with a high bulk density.

    摘要翻译： 用于烯烃聚合的载体催化剂包括以下组分：（A）用具有活性氢原子的基团官能化的多孔有机载体;（B）含有选自氧，氮和硫的杂原子的铝的有机金属化合物; 和（C）选自元素周期表IVb，Vb或VIb族的过渡金属的化合物，其含有环戊二烯基型配体。可以使用可以球形颗粒形式获得的这些负载型催化剂 在烯烃在液相或气相中的聚合反应中，从而产生具有受控形态和高体积密度的聚合物。

    Supported catalysts for the polymerization of olefins
    2.
    发明授权
    Supported catalysts for the polymerization of olefins 失效
    用于烯烃聚合的负载催化剂

    公开(公告)号：US06423660B1

    公开(公告)日：2002-07-23

    申请号：US09004867

    申请日：1998-01-09

    申请人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    发明人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    IPC分类号： C08F444

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/602 ,  C08F4/63916 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/20 ,  C08F210/08

    摘要： Supported catalysts for the polymerization of olefins comprise the following components: (A) a porous organic support functionalised with groups having active hydrogen atoms; (B) an organo-metallic compound of aluminium containing heteroatoms selected from oxygen, nitrogen and sulphur; and (C) a compound of a transition metal selected from those of groups IVb, Vb or VIb of the Periodic Table of the Elements, containing ligands of the cyclopentadienyl type. These supported catalysts, obtainable in the form of spherical particles, can be used in the polymerization reaction of olefins either in liquid or in gas phase, thus producing polymers endowed with a controlled morphology and with a high bulk density.

    摘要翻译： 用于烯烃聚合的载体催化剂包括以下组分：（A）用具有活性氢原子的基团官能化的多孔有机载体;（B）含有选自氧，氮和硫的杂原子的铝的有机金属化合物; 和（C）选自元素周期表IVb，Vb或VIb族中的过渡金属的化合物，其含有环戊二烯基型配体。可以使用可以球形颗粒形式获得的这些负载型催化剂 在烯烃在液相或气相中的聚合反应中，从而产生具有受控形态和高体积密度的聚合物。

    Catalysts and processes for the polymerization of olefins
    7.
    发明授权
    Catalysts and processes for the polymerization of olefins 失效
    催化剂和烯烃聚合方法

    公开(公告)号：US5849653A

    公开(公告)日：1998-12-15

    申请号：US503948

    申请日：1995-07-19

    申请人： Tiziano Dall'Occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    发明人： Tiziano Dall'Occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    IPC分类号： C08F4/642 ,  C08F4/64 ,  C08F4/648 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65922 ,  Y10S526/943

    摘要： Catalysts for the polymerization of olefins are disclosed, which comprise the reaction product of: (A) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium or hafnium; (B) an organometallic aluminum compound of the formula (II): Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z(II) wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms which is different from a straight alkyl or alkenyl group and, optionally, R.sup.4 and R.sup.5 fused together can form a ring having from 4 to 6 carbon atoms, R.sup.6 is hydrogen or an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals containing from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, y=3-w-z; and (C) water. The molar ratio aluminum/water is comprised between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the above formula is used.

    摘要翻译： 公开了用于烯烃聚合的催化剂，其包含以下反应产物：（A）钛，锆或铪的桥连和/或取代的环戊二烯基化合物; （B）式（II）的有机金属铝化合物：Al（CH2-CR4R5R6）wR7yHz（Ⅱ）其中在相同或不同的（CH2-CR4R5R6）基团中，R4是烷基，烯基或芳基烷基 具有1至10个碳原子，R 5是具有3至50个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，其不同于直链烷基或烯基，并且任选地，R 4和R 5稠合在一起可以形成 具有4至6个碳原子的环，R 6是氢或具有1至10个碳原子的烷基，链烯基或芳基烷基，相同或不同的R 7取代基是含1个碳原子的烷基，烯基，芳基，芳烷基或烷芳基 至10个碳原子，并且任选地可以含有Si或Ge原子，w是1,2或3，z是0或1，y = 3-wz; 和（C）水。 铝/水的摩尔比为1:1至100:1。 这些催化剂相对于已知的催化剂显示出改善的活性，其中使用与上式不同的铝化合物。