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    Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature
    3.
    发明申请
    Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature 有权
    使用熔融起始温度抑制模型在线测定树脂粘性度的方法

    公开(公告)号：US20080065360A1

    公开(公告)日：2008-03-13

    申请号：US11827684

    申请日：2007-07-13

    申请人： Richard B. Pannell ,  Robert O. Hagerty ,  Eric J. Markel

    发明人： Richard B. Pannell ,  Robert O. Hagerty ,  Eric J. Markel

    IPC分类号： G06F17/10 ,  C08F2/38

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F2400/02 ,  C08F2/00 ,  C08F2/34 ,  C08F210/08 ,  C08F210/14

    摘要： In some embodiments, a method including the steps of: during a polymerization reaction producing a polymer resin in a fluid bed reactor, measuring reaction parameters including at least reactor temperature, at least one property of the resin, and amount of at least one condensable diluent gas in the reactor; determining from at least one measured resin property using a predetermined correlation, a dry melt initiation temperature value for a dry version of the polymer resin; and during the reaction, using a melt initiation temperature depression model to determine in on-line fashion a reduced melt initiation temperature for the resin (e.g., a temperature at which the resin is expected to begin to melt) in the presence of the at least one condensable diluent gas in the reactor.

    摘要翻译： 在一些实施方案中，一种方法包括以下步骤：在聚合反应期间在流化床反应器中制备聚合物树脂，测量反应参数至少包括反应器温度，树脂的至少一种性质和至少一种可冷凝稀释剂 反应堆中的气体; 使用预定的相关性从至少一种测量的树脂性质确定干燥型聚合物树脂的干熔体起始温度值; 并且在反应期间，使用熔体起始温度下降模型以在线方式确定在至少存在下存在的树脂的降低的熔融起始温度（例如，树脂预期开始熔化的温度） 一个可冷凝的稀释气体在反应器中。

    Methods for operating a polymerization reactor
    4.
    发明授权
    Methods for operating a polymerization reactor 有权
    操作聚合反应器的方法

    公开(公告)号：US08598283B2

    公开(公告)日：2013-12-03

    申请号：US13575872

    申请日：2011-02-17

    申请人： Eric J. Markel ,  Robert O. Hagerty ,  Richard B. Pannell ,  Michael E. Sieloff ,  Jerome Holveck

    发明人： Eric J. Markel ,  Robert O. Hagerty ,  Richard B. Pannell ,  Michael E. Sieloff ,  Jerome Holveck

    IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F4/00 ,  C08F210/00

    CPC分类号： C08F10/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F2/34 ,  C08F2/42 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

    摘要： Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.

    摘要翻译： 提供了在气相聚合反应器中关闭和重新开始聚合的方法。 该方法可以包括以足以阻止其中聚合的量向反应器中引入聚合中和剂。 该方法还可以包括停止从反应器中回收聚合物产物，并停止将催化剂进料和反应器进料引入反应器。 该方法还可以包括将反应器内的压力从操作压力调节到空载压力。 该方法还可以包括调节通过反应器的循环流体的表观速度从操作的表观速度到空转的表观速度。 该方法还可以包括将反应器维持在空闲状态一段时间。

    Method for on-line monitoring and control of polymerization processes and reactors to prevent discontinuity events
    5.
    发明授权
    Method for on-line monitoring and control of polymerization processes and reactors to prevent discontinuity events 失效
    用于在线监测和控制聚合过程和反应器以防止不连续事件的方法

    公开(公告)号：US08433443B2

    公开(公告)日：2013-04-30

    申请号：US12214469

    申请日：2008-06-19

    申请人： Robert O. Hagerty ,  Ian D. Burdett ,  Marc L. DeChellis ,  F. David Hussein ,  Eric J. Markel ,  Michael E. Muhle ,  Richard B. Pannell ,  Daniel P. Zilker

    发明人： Robert O. Hagerty ,  Ian D. Burdett ,  Marc L. DeChellis ,  F. David Hussein ,  Eric J. Markel ,  Michael E. Muhle ,  Richard B. Pannell ,  Daniel P. Zilker

    IPC分类号： G05B21/00

    CPC分类号： C08F10/00 ,  C08F2400/02 ,  C08F2/34 ,  C08F2/002 ,  C08F2/00

    摘要： Generally, a method of monitoring a polymerization reaction in a fluid bed reactor to generate, in on-line fashion, data indicative of the imminent occurrence of a discontinuity event (for example, sheeting) and optionally also control the reaction to prevent the occurrence of the discontinuity event is provided. Typical embodiments include the steps of generating in on-line fashion at least one of bed static data indicative of static charge in the fluidized bed and carryover static data indicative of carryover static; and generating at least one of temperature data (in on-line fashion using at least one monitored reaction parameter) indicative of a first temperature and acoustic emission data indicative of resin stickiness in the reactor, where the first temperature is indicative of at least one of degree of resin stickiness in the reactor and a characteristic of melting behavior of polymer resin in the reactor in the presence of at least one diluent.

    摘要翻译： 通常，监测流化床反应器中的聚合反应的方法，以在线方式产生指示即将发生的不连续事件（例如，片材）的数据，并且还可任选地控制反应以防止发生 提供不连续事件。 典型的实施方案包括以在线方式产生指示流化床中的静电荷的床静态数据中的至少一种并携带指示携带静电的静态数据的步骤; 并且产生指示在反应器中指示树脂粘性的第一温度和声发射数据的温度数据（以在线方式使用至少一个监测的反应参数）中的至少一个，其中第一温度表示以下中的至少一个： 在至少一种稀释剂存在下，反应器中的树脂粘性程度和聚合物树脂在反应器中的熔融行为的特征。

    Methods for Operating a Polymerization Reactor
    7.
    发明申请
    Methods for Operating a Polymerization Reactor 有权
    操作聚合反应器的方法

    公开(公告)号：US20120329962A1

    公开(公告)日：2012-12-27

    申请号：US13575872

    申请日：2011-02-17

    申请人： Eric J. Markel ,  Robert O. Hagerty ,  Richard B. Pannell ,  Michael E. Sieloff ,  Jerome Holveck

    发明人： Eric J. Markel ,  Robert O. Hagerty ,  Richard B. Pannell ,  Michael E. Sieloff ,  Jerome Holveck

    IPC分类号： C08F2/38

    CPC分类号： C08F10/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F2/34 ,  C08F2/42 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

    摘要： Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.

    摘要翻译： 提供了在气相聚合反应器中关闭和重新开始聚合的方法。 该方法可以包括以足以阻止其中聚合的量向反应器中引入聚合中和剂。 该方法还可以包括停止从反应器中回收聚合物产物，并停止将催化剂进料和反应器进料引入反应器。 该方法还可以包括将反应器内的压力从操作压力调节到空载压力。 该方法还可以包括调节通过反应器的循环流体的表观速度从操作的表观速度到空转的表观速度。 该方法还可以包括将反应器维持在空闲状态一段时间。

    Method for On-Line Determination of Degree or Onset of Resin Stickiness Using Acoustic Data
    8.
    发明申请
    Method for On-Line Determination of Degree or Onset of Resin Stickiness Using Acoustic Data 失效
    使用声学数据在线确定树脂粘性的程度或开始的方法

    公开(公告)号：US20100286346A1

    公开(公告)日：2010-11-11

    申请号：US12774084

    申请日：2010-05-05

    申请人： Michael E. Muhle ,  Richard B. Pannell ,  Eric J. Markel ,  Robert O. Hagerty

    发明人： Michael E. Muhle ,  Richard B. Pannell ,  Eric J. Markel ,  Robert O. Hagerty

    IPC分类号： C08F2/00

    CPC分类号： C08F10/02 ,  C08F210/16 ,  C08F2400/02 ,  C08F2/34 ,  C08F2/002 ,  C08F2/00 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/08

    摘要： Provided is a method for monitoring a polymerization reaction in a fluid bed reactor to determine in on-line fashion a current value, and preferably also a limiting value, of a stickiness control temperature, and optionally controlling the reaction in response thereto in an effort to prevent occurrence of a discontinuity event. The stickiness control temperature is a temperature indicative of a characteristic of melting behavior of polymer resin in the reactor, and may be indicative of occurrence of resin sheeting or another discontinuity event. Optionally, a predetermined relation between values of acoustic energy in the reactor and values of a stickiness control temperature is used to provide error checking for determination of the stickiness control temperature, or a current value of the stickiness control temperature is determined from acoustic data and a predetermined relation between values of an acoustic condition in the reactor and values of the stickiness control temperature.

    摘要翻译： 提供了一种用于监测流化床反应器中的聚合反应的方法，以在线方式确定粘性控制温度的当前值，优选地也是限制值，并且可选地控制响应于此的反应，以努力 防止发生不连续事件。 粘性控制温度是指示反应器中聚合物树脂的熔融特性的特性的温度，并且可以指示发生树脂片或另一不连续事件。 可选地，使用反应器中的声能值和粘性控制温度的值之间的预定关系来提供用于确定粘性控制温度的错误检查，或者根据声学数据确定粘性控制温度的当前值，并且 反应器中的声学条件的值和粘性控制温度的值之间的预定关系。

    Method for on-line monitoring and control of polymerization processes and reactors to prevent discontinuity events
    10.
    发明申请
    Method for on-line monitoring and control of polymerization processes and reactors to prevent discontinuity events 失效
    用于在线监测和控制聚合过程和反应器以防止不连续事件的方法

    公开(公告)号：US20080319583A1

    公开(公告)日：2008-12-25

    申请号：US12214469

    申请日：2008-06-19

    申请人： Robert O. Hagerty ,  Ian D. Burdett ,  Marc L. DeChellis ,  F. David Hussein ,  Eric J. Markel ,  Michael E. Muhle ,  Richard B. Pannell ,  Daniel P. Zilker

    发明人： Robert O. Hagerty ,  Ian D. Burdett ,  Marc L. DeChellis ,  F. David Hussein ,  Eric J. Markel ,  Michael E. Muhle ,  Richard B. Pannell ,  Daniel P. Zilker

    IPC分类号： G05B21/00

    CPC分类号： C08F10/00 ,  C08F2400/02 ,  C08F2/34 ,  C08F2/002 ,  C08F2/00

    摘要： Generally, a method of monitoring a polymerization reaction in a fluid bed reactor to generate, in on-line fashion, data indicative of the imminent occurrence of a discontinuity event (for example, sheeting) and optionally also control the reaction to prevent the occurrence of the discontinuity event is provided. Typical embodiments include the steps of generating in on-line fashion at least one of bed static data indicative of static charge in the fluidized bed and carryover static data indicative of carryover static; and generating at least one of temperature data (in on-line fashion using at least one monitored reaction parameter) indicative of a first temperature and acoustic emission data indicative of resin stickiness in the reactor, where the first temperature is indicative of at least one of degree of resin stickiness in the reactor and a characteristic of melting behavior of polymer resin in the reactor in the presence of at least one diluent.

    摘要翻译： 通常，监测流化床反应器中的聚合反应的方法，以在线方式产生指示即将发生的不连续事件（例如，片材）的数据，并且还可任选地控制反应以防止发生 提供不连续事件。 典型的实施方案包括以在线方式产生指示流化床中的静电荷的床静态数据中的至少一种并携带指示携带静电的静态数据的步骤; 并且产生指示在反应器中指示树脂粘性的第一温度和声发射数据的温度数据（以在线方式使用至少一个监测的反应参数）中的至少一个，其中第一温度表示以下中的至少一个： 在至少一种稀释剂存在下，反应器中的树脂粘性程度和聚合物树脂在反应器中的熔融行为的特征。