Perfluoroalkyl esters, a process for their preparation and their use as
a soil-repellant agent
    1.
    发明授权
    Perfluoroalkyl esters, a process for their preparation and their use as a soil-repellant agent 失效
    全氟烷基酯,它们的制备方法及其作为防污剂的用途

    公开(公告)号:US4473371A

    公开(公告)日:1984-09-25

    申请号:US412127

    申请日:1982-08-27

    CPC分类号: D06M15/277 D06M13/213

    摘要: Perfluoroalkyl esters of the formula ##STR1## wherein R.sub.1 denotes C.sub.2 -C.sub.20, preferably C.sub.4 -C.sub.14 -perfluoroalkyl or perfluoroalkoxyperfluoroalkyl, R.sub.2 denotes C.sub.3 -C.sub.4 -alkylene, R.sub.3 denotes C.sub.2 -C.sub.5 -.omega.-epoxyalkyl or C.sub.1 -C.sub.18, preferably C.sub.1 -C.sub.5 -alkyl, which can be substituted by 1 or 2 halogen atoms, preferably chlorine atoms, by hydroxyl groups, by a group of the formula ##STR2## by 1 to 3 groups of the formula --OCO--CX.dbd.CY--COO--(CH.sub.2).sub.m --R.sub.1 or by, in each case, one lower alkoxy, epoxy, lower acyloxy, lower alkoxycarbonyl, lower acylamino, lower hydroxylalkylthio, lower trialkylamino, lower trialkylammonium, phenyl, phenoxy or furanyl group or R.sub.3, in the case where b=0, also denotes C.sub.3 -C.sub.18 -alkenyl, which can be subsituted by hydroxyl groups or a phenyl group; C.sub.3 -C.sub.8 -alkynyl, which can be substituted by hydroxyl groups; cyclohexyl; phenyl, which can be substituted by 1-3 C.sub.1 -C.sub.8 -alkyl groups or by phenyl, or naphthyl, R.sub.4 denotes hydrogen or methyl, R.sub.5 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl, X and Y denote hydrogen, halogen or C.sub.1 -C.sub.6 -alkyl, a denotes a number from 1 to 10, b denotes 0 or 1 and m denotes a number from 1 to 6, preferably 1 to 4, a process for their preparation and their use for providing oil and water-repellant finishing of textile material.

    摘要翻译: 其中R 1表示C 2 -C 20,优选C 4 -C 14全氟烷基或全氟烷氧基全氟烷基,R 2表示C 3 -C 4亚烷基,R 3表示C 2 -C 5 - ω-环氧烷基或C 1 -C 18,优选C 1 -C 5 - 烷基,其可以被1或2个卤素原子,优选氯原子,被羟基取代,通过下式的基团被1至3个基团-OCO-CX = CY-COO-(CH 2) )m-R 1,或者在每种情况下,其中b = 1的一个低级烷氧基,环氧基,低级酰氧基,低级烷氧基羰基,低级酰基氨基,低级羟烷基硫代,低级三烷基氨基,低级三烷基铵,苯基,苯氧基或呋喃基或R3。 0也表示可被羟基或苯基取代的C 3 -C 18 - 烯基; 可被羟基取代的C 3 -C 8 - 炔基; 环己基 苯基,其可以被1-3个C 1 -C 8 - 烷基或苯基或萘基取代,R 4表示氢或甲基,R 5表示氢或C 1 -C 4 - 烷基,X和Y表示氢,卤素或C 1 -C 6 - 烷基,a表示1至10的数,b表示0或1,m表示1至6的数,优选1至4,其制备方法及其用于提供纺织品的防油和防水整理的用途 材料。

    Naphthalimides containing sulfuric acid ester groups, a process for
their preparation and their use
    2.
    发明授权
    Naphthalimides containing sulfuric acid ester groups, a process for their preparation and their use 失效
    含硫酸酯基的萘二酰亚胺,其制备方法及其应用

    公开(公告)号:US4814453A

    公开(公告)日:1989-03-21

    申请号:US55904

    申请日:1987-05-29

    IPC分类号: C07D221/14 C11D3/42 D06L3/12

    CPC分类号: C07D221/14

    摘要: New optical brighteners of the general formula ##STR1## in which R denotes hydrogen, alkyl, alkoxyalkyl, cyclohexyl, methylcyclohexyl, benzyl, phenylethyl, phenyl, alkylphenyl or xylyl,X denotes a C.sub.2 -C.sub.7 -alkylene group or a bridge member of the formula --X.sup.1 --(OX.sup.2).sub.n -- in which X.sup.1 and X.sup.2 denote C.sub.2 H.sub.4 or C.sub.3 H.sub.7 and n denotes 1 or 2 and Me denotes a proton, an alkali metal cation or a cation NH.sub.2 R.sup.1 R.sup.2 in which R.sup.1 and R.sup.2 represent hydrogen, alkyl or hydroxyalkyl.

    摘要翻译: 新的通式的荧光增白剂,其中R表示氢,烷基,烷氧基烷基,环己基,甲基环己基,苄基,苯基乙基,苯基,烷基苯基或二甲苯基,X表示C 2 -C 7亚烷基或式 -X1-(OX2)n-,其中X1和X2表示C2H4或C3H7,n表示1或2,Me表示质子,碱金属阳离子或阳离子NH 2 R 1 R 2,其中R 1和R 2表示氢,烷基或羟烷基。

    Benzofuran derivatives
    4.
    发明授权
    Benzofuran derivatives 失效
    苯并呋喃衍生物

    公开(公告)号:US3974172A

    公开(公告)日:1976-08-10

    申请号:US440013

    申请日:1974-02-06

    摘要: Benzofuran compounds of the formula ##SPC1##Wherein E is a bivalent bridging member of the formula ##SPC2##S is hydrogen, halogen, lower alkyl, carboxy, sulfo, cyano, lower carboalkoxy, carbonamido, lower mono- or dialkyl carbonamido, sulfonic acid lower alkyl ester, sulfonamido, lower mono- or dialkyl sulfonamido or phenyl; P, Q, T and U are hydrogen or halogen, lower alkyl, lower alkoxy, phenyl, carboxy, cyano, lower carboalkoxy, lower carbo-alkoxy substituted by a member selected from the group consisting of lower alkoxy, lower dialkylamino and lower trialkyl ammonium, carbonamido, lower mono- or di-alkyl carbonamido, sulfo, sulfonic acid lower alkyl ester, sulfonamido or lower mono- or dialkyl sulfonamido or P and Q together or T and U together are lower alkylene or an annellated phenyl ring, and n is 1 to 3. These compounds can be synthetized by a condensation reaction of the corresponding carboxylic acid derivative with an ortho-aminophenol or by HORNER or similar syntheses forming said bridging member. The products are optical brighteners.

    摘要翻译: 式WHEREIN E的苯并呋喃化合物是式S的二价桥连构件是氢,卤素,低级烷基,羧基,磺基,氰基,低级烷氧羰基,碳酰氨基,低级单或二烷基碳酰氨基,磺酸低级烷基酯,亚磺酰氨基, 低级单烷基或二烷基亚磺酰氨基或苯基; P,Q,T和U是氢或卤素,低级烷基,低级烷氧基,苯基,羧基,氰基,低级烷氧羰基,低级烷氧基,被选自低级烷氧基,低级二烷基氨基和低级三烷基铵 ,碳酰氨基,低级单烷基或二烷基碳酰氨基,磺基,磺酸低级烷基酯,亚磺酰氨基或下单 - 或二烷基亚磺酰氨基或P和Q一起或T和U一起为低级亚烷基或环状苯环,n为 这些化合物可以通过相应的羧酸衍生物与邻氨基苯酚或HORNER的缩合反应或形成所述桥连构件的类似合成来合成。 产品是荧光增白剂。

    1,3,4-Oxadiazolone-(2) compounds and process for their manufacture
    6.
    发明授权
    1,3,4-Oxadiazolone-(2) compounds and process for their manufacture 失效
    1,3,4-恶二酮 - (2)化合物及其制备方法

    公开(公告)号:US4246403A

    公开(公告)日:1981-01-20

    申请号:US60823

    申请日:1979-07-25

    CPC分类号: C07D271/113 C07F9/65312

    摘要: Novel 1,3,4-oxadiazolone-(2) compounds of the formula ##STR1## wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.

    摘要翻译: 式(1)的新的1,3,4-恶二酮 - (2)化合物,其中Y表示任选官能修饰的或任选取代的苯基或任选取代并选自以下的五元杂环:呋喃 ,噻吩,恶唑,咪唑,恶二唑,恶二唑酮,三唑,苯并呋喃,噻二唑,苯并恶唑,苯并咪唑和苯并三唑,R表示氢,烷基或任选取代的苯基,n表示0和1,环A和B任选进一步携带非 - 发色取代基。 这些化合物可以用作荧光增白剂。