公开(公告)号：US20070149719A1

公开(公告)日：2007-06-28

申请号：US10584150

申请日：2004-12-22

申请人： Etsuo Fujimoto ,  Akiko Shinoda ,  Kohei Morikawa

发明人： Etsuo Fujimoto ,  Akiko Shinoda ,  Kohei Morikawa

IPC分类号： C08F8/32

CPC分类号： B01J20/262 ,  B01J20/223 ,  B01J20/24 ,  B01J20/265 ,  B01J20/267 ,  B01J20/28004 ,  B01J20/28059 ,  B01J20/286 ,  B01J20/3212 ,  B01J20/3217 ,  B01J20/3242 ,  B01J20/3265 ,  B01J20/3425 ,  B01J20/3475 ,  B01J2220/4825 ,  B01J2220/49 ,  B01J2220/52 ,  B01J2220/54 ,  B01J2220/58 ,  B01J2220/62 ,  B01J2220/66 ,  B01J2220/84

摘要： This invention provides a granular polysaccharide polymer having phthalocyanine bonded thereto which is a crosslinked polymer comprising a phthalocyanine skeleton covalently bonded to a crosslinked granular porous chitosan. When this crosslinked polymer is used as an adsorbent, a polycyclic organic material present as a mixture in a solution can be selectively adsorbed, desorbed, or separated. The granular polysaccharide polymer having phthalocyanine bonded thereto is excellent not only in the ability to adsorb polycyclic organic materials, but in the ability to desorb the adsorbed polycyclic organic materials. Accordingly, the crosslinked polymer is particularly useful for selective adsorption, desorption/concentration, or separation of polycyclic organic materials, e.g., mutagens, present in a very small amount, for example, in environments, foods, table luxuries, biological samples and can be widely utilized for the qualitative determination, quantitative determination, or removal of mutagens.

摘要翻译： 本发明提供了一种结合有酞菁的粒状多糖聚合物，其是包含与交联的颗粒状多孔壳聚糖共价键合的酞菁骨架的交联聚合物。 当该交联聚合物用作吸附剂时，可以选择性地吸附，解吸或分离作为溶液中的混合物存在的多环有机材料。 具有与其结合的酞菁的粒状多糖聚合物不仅具有吸附多环有机材料的能力，而且在吸附多环有机材料的解吸能力方面优异。 因此，交联聚合物特别可用于多环有机材料的选择性吸附，解吸/浓缩或分离，例如以非常少量存在的诱变剂，例如在环境，食品，餐具，生物样品中，并且可以是 广泛用于定性测定，定量测定或除去诱变剂。

公开(公告)号：US20070106033A1

公开(公告)日：2007-05-10

申请号：US10584152

申请日：2004-12-22

申请人： Etsuo Fujimoto ,  Akiko Shinoda ,  Kohei Morikawa ,  Yoshio Fujiwara

发明人： Etsuo Fujimoto ,  Akiko Shinoda ,  Kohei Morikawa ,  Yoshio Fujiwara

IPC分类号： C08F120/10 ,  C08F220/10 ,  C08C19/22 ,  C08F20/10 ,  C08F8/32

CPC分类号： B01J20/261 ,  B01J20/223 ,  B01J20/26 ,  B01J20/264 ,  B01J20/265 ,  B01J20/267 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/285 ,  B01J20/286 ,  B01J20/3007 ,  B01J20/3042 ,  B01J20/321 ,  B01J20/3217 ,  B01J20/3242 ,  B01J20/3265 ,  B01J20/3425 ,  B01J20/3475 ,  B01J2220/49 ,  B01J2220/52 ,  B01J2220/54 ,  B01J2220/58 ,  B01J2220/62 ,  B01J2220/66 ,  B01J2220/84 ,  C08F8/30 ,  C08F8/42

摘要： This invention provides a crosslinked polymer produced by polymerizing one or more crosslinking monomers and bonding, preferably covalently bonding, a phthalocyanine skeleton to the resultant polymer. The degree of crosslinking is 1% or higher. When this crosslinked polymer is used as an adsorbent, a polycyclic organic material present as a mixture in a solution can be selectively adsorbed, desorbed, or separated. The crosslinked polymer having a phthalocyanine bonded thereto is excellent not only in the ability to adsorb polycyclic organic materials, but in the ability to desorb the adsorbed polycyclic organic materials. Accordingly, the crosslinked polymer is particularly useful for selective adsorption, desorption/concentration, or separation of polycyclic organic materials, e.g., mutagens, present in a very small amount, for example, in environments, foods, table luxuries, biological samples and can be widely utilized for the qualitative determination, quantitative determination, or removal of mutagens.

摘要翻译： 本发明提供了通过聚合一种或多种交联单体并将酞菁骨架共价键合到所得聚合物而制备的交联聚合物。 交联度为1％以上。 当该交联聚合物用作吸附剂时，可以选择性地吸附，解吸或分离作为溶液中的混合物存在的多环有机材料。 具有与其结合的酞菁的交联聚合物不仅具有吸附多环有机材料的能力，而且在吸附多环有机材料的解吸能力方面优异。 因此，交联聚合物特别可用于多环有机材料的选择性吸附，解吸/浓缩或分离，例如以非常少量存在的诱变剂，例如在环境，食品，餐具，生物样品中，并且可以是 广泛用于定性测定，定量测定或除去诱变剂。

公开(公告)号：US20070196928A1

公开(公告)日：2007-08-23

申请号：US10594521

申请日：2005-03-30

申请人： Kazuki Nakanishi ,  Akiko Shinoda ,  Haruhiko Ikeda ,  Hiroshi Uchida

发明人： Kazuki Nakanishi ,  Akiko Shinoda ,  Haruhiko Ikeda ,  Hiroshi Uchida

IPC分类号： B01D15/08 ,  G01N33/00

CPC分类号： B01J20/103 ,  B01J20/28004 ,  B01J20/2803 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28083 ,  B01J20/28085 ,  B01J20/28092 ,  B01J20/3242 ,  B01J20/3244 ,  B01J2220/54 ,  B01J2220/58 ,  C01B33/154

摘要： The analytical pretreatment column of the present invention is filled with at least the inorganic type filler having a number average diameter consisting of double pore structure having both a through pore with a number average diameter of the range of 0.5 to 25 micrometers, and meso pore with number average diameter of the range of 2 to 50 nm.

摘要翻译： 本发明的分析预处理塔填充有至少具有数均直径由具有数均粒径为0.5〜25微米的通孔的双孔结构的无机型填料和具有0.5〜25微米范围的中孔 数均粒径为2〜50nm。