公开(公告)号：US5521243A

公开(公告)日：1996-05-28

申请号：US392650

申请日：1995-02-23

申请人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

发明人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

IPC分类号： C08J5/18 ,  C04B26/06 ,  C08F2/38 ,  C08F265/06 ,  C08K3/22 ,  C08L33/12 ,  C08L51/00 ,  C08L31/02

CPC分类号： C08L51/003 ,  C04B26/06 ,  C08F265/06 ,  C08K3/22 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/268 ,  Y10T428/269

摘要： Ranges of chain-transfer agents, thixotropic agents, and alumina trihydrate content are balanced to minimize migration or maldistribution of coloring matter and alumina trihydrate during curing of methyl methacrylate in a syrup including polymethylmethacrylate and also during subsequent heating and deformation in thermoforming, to achieve constancy of impact resistance and improve stability of patterns even in deformed portions of formed sheets.

摘要翻译： 平衡链转移剂，触变剂和三水合氧化铝含量的范围，以使包含聚甲基丙烯酸甲酯在内的甲基丙烯酸甲酯固化过程中以及随后的热成型加热和变形期间色素和三水合氧化铝的迁移或分布不均最小化以达到恒定 的耐冲击性，并且即使在成形片的变形部分中也提高图案的稳定性。

公开(公告)号：US5705552A

公开(公告)日：1998-01-06

申请号：US720164

申请日：1996-09-25

申请人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

发明人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

IPC分类号： C08K3/20 ,  C04B26/06 ,  C08F2/44 ,  C08F265/06 ,  C08K3/22 ,  C08L33/12 ,  C08L51/00 ,  C08L51/06 ,  C08L31/02

CPC分类号： C08L51/003 ,  C04B26/06 ,  C08F265/06 ,  C08K3/22

摘要： A composition suitable for making thermoformable sheets and the like. The composition comprises a crosslinked poly (methyl methacrylate) typically having uncrosslinked poly (methyl methacrylate) dispersed therein. The composition a comprises 0.5 to about 1.0 pph of at least one crosslinking agent x, and up to about 0.58x-0.28 pph of a at least one chain terminator. The composition also comprises about 0.1 to 8 pph poly (methyl methacrylate) compatible plasticizer, and has about 20 to 60 wt % solid particle dispersed therein.

摘要翻译： 适于制造可热成形片材的组合物等。 组合物包含通常具有分散在其中的未交联聚（甲基丙烯酸甲酯）的交联聚（甲基丙烯酸甲酯）。 组合物a包含0.5至约1.0pph的至少一种交联剂x和至多约0.58x-0.28pph的至少一种链终止剂。 该组合物还包含约0.1至8pph的聚甲基丙烯酸甲酯相容的增塑剂，并且其中分散有约20至60重量％的固体颗粒。

公开(公告)号：US5567745A

公开(公告)日：1996-10-22

申请号：US620510

申请日：1996-03-22

申请人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

发明人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

IPC分类号： C08J5/18 ,  C04B26/06 ,  C08F2/38 ,  C08F265/06 ,  C08K3/22 ,  C08L33/12 ,  C08L51/00

CPC分类号： C08L51/003 ,  C04B26/06 ,  C08F265/06 ,  C08K3/22 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/268 ,  Y10T428/269

摘要： Ranges of chain-transfer agents, thixotropic agents, and alumina trihydrate content are balanced to minimize migration or maldistribution of coloring matter and alumina trihydrate during curing of methyl methacrylate in a syrup including polymethylmethacrylate and also during subsequent heating and deformation in thermoforming, to achieve constancy of impact resistance and improve stability of patterns even in deformed portions of formed sheets.

公开(公告)号：US5747154A

公开(公告)日：1998-05-05

申请号：US620511

申请日：1996-03-22

申请人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

发明人： Ettore Minghetti ,  John E. Eitel ,  Carol A. Wetter

IPC分类号： C08J5/18 ,  C04B26/06 ,  C08F2/38 ,  C08F265/06 ,  C08K3/22 ,  C08L33/12 ,  C08L51/00 ,  B32B5/16

CPC分类号： C08L51/003 ,  C04B26/06 ,  C08F265/06 ,  C08K3/22 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/268 ,  Y10T428/269

摘要： Ranges of chain-transfer agents, thixotropic agents, and alumina trihydrate content are balanced to minimize migration or maldistribution of coloring matter and alumina trihydrate during curing of methyl methacrylate in a syrup including polymethylmethacrylate and also during subsequent heating and deformation in thermoforming, to achieve constancy of impact resistance and improve stability of patterns even in deformed portions of formed sheets.

公开(公告)号：US5415931A

公开(公告)日：1995-05-16

申请号：US98564

申请日：1993-07-26

申请人： Ettore Minghetti ,  John E. Eitel

发明人： Ettore Minghetti ,  John E. Eitel

IPC分类号： B29C39/02 ,  B29C51/00 ,  C08F20/18 ,  C08F220/10 ,  C08F265/06 ,  C08J5/18 ,  C08K3/00 ,  C08L33/04 ,  C08L33/12 ,  B32B5/16 ,  C08L35/02

CPC分类号： B29C51/002 ,  B29C39/026 ,  C08F265/06 ,  B29K2033/12 ,  B29K2433/12 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/31928 ,  Y10T428/31935

摘要： A monomer-rich acrylic syrup is cast including about 10% to about 20% ground acrylic particles. During curing, the particles absorb over half their weight in monomer, and a cured sheet is formed in which the matrix monomer and uncrosslinked polymer form a phase which extends through the particles, while the particles appear to be fused together. Including a crosslinker in the syrup further insures the interpenetration of the matrix phase into the swollen particles. A textured surface is formed, which is useful as an anti-slip surface in bathtubs and shower stalls, after thermoforming.

摘要翻译： 含有富含单体的丙烯酸浆料包括约10％至约20％的研磨丙烯酸颗粒。 在固化期间，颗粒在单体中吸收超过其重量的一半，并且形成固化片，其中基质单体和未交联的聚合物形成延伸穿过颗粒的相，同时颗粒看起来融合在一起。 在糖浆中包括交联剂进一步确保了基质相相互渗透成溶胀的颗粒。 形成纹理表面，其在热成型后可用作浴缸和淋浴间中的防滑表面。

公开(公告)号：US5530041A

公开(公告)日：1996-06-25

申请号：US373686

申请日：1995-01-17

申请人： Ettore Minghetti ,  John E. Eitel

发明人： Ettore Minghetti ,  John E. Eitel

IPC分类号： B29C39/02 ,  B29C51/00 ,  C08F20/18 ,  C08F220/10 ,  C08F265/06 ,  C08J5/18 ,  C08K3/00 ,  C08L33/04 ,  C08L33/12 ,  C08K5/00 ,  B32B5/12

CPC分类号： B29C51/002 ,  B29C39/026 ,  C08F265/06 ,  B29K2033/12 ,  B29K2433/12 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/31928 ,  Y10T428/31935

摘要： A monomer-rich acrylic syrup is cast including about 10% to about 20% ground acrylic particles. During curing, the particles absorb over half their weight in monomer, and a cured sheet is formed in which the matrix monomer and uncrosslinked polymer form a phase which extends through the particles, while the particles appear to be fused together. Including a crosslinker in the syrup further insures the interpenetration of the matrix phase into the swollen particles. A textured surface is formed, which is useful as an anti-slip surface in bathtubs and shower stalls, after thermoforming.

摘要翻译： 含有富含单体的丙烯酸浆料包括约10％至约20％的研磨丙烯酸颗粒。 在固化期间，颗粒在单体中吸收超过其重量的一半，并且形成固化片，其中基质单体和未交联的聚合物形成延伸穿过颗粒的相，同时颗粒看起来融合在一起。 在糖浆中包括交联剂进一步确保了基质相相互渗透成溶胀的颗粒。 形成纹理表面，其在热成型后可用作浴缸和淋浴间的防滑表面。

公开(公告)号：US5242968A

公开(公告)日：1993-09-07

申请号：US572831

申请日：1990-08-27

申请人： Ettore Minghetti ,  John E. Eitel

发明人： Ettore Minghetti ,  John E. Eitel

IPC分类号： B29C39/02 ,  B29C51/00 ,  C08F20/18 ,  C08F220/10 ,  C08F265/06 ,  C08J5/18 ,  C08K3/00 ,  C08L33/04 ,  C08L33/12

CPC分类号： B29C51/002 ,  B29C39/026 ,  C08F265/06 ,  B29K2033/12 ,  B29K2433/12 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/31928 ,  Y10T428/31935

摘要： A monomer-rich acrylic syrup is cast including about 10% to about 20% ground acrylic particles. During curing, the particles absorb over half their weight in monomer, and a cured sheet is formed in which the matrix monomer and uncrosslinked polymer form a phase which extends through the particles, while the particles appear to be fused together. Including a crosslinker in the syrup further insures the interpenetration of the matrix phase into the swollen particles. A textured surface is formed, which is useful as an anti-slip surface in bathtubs and shower stalls, after thermoforming.

摘要翻译： 含有富含单体的丙烯酸浆料包括约10％至约20％的研磨丙烯酸颗粒。 在固化期间，颗粒在单体中吸收超过其重量的一半，并且形成固化片，其中基质单体和未交联的聚合物形成延伸穿过颗粒的相，同时颗粒看起来融合在一起。 在糖浆中包括交联剂进一步确保了基质相相互渗透成溶胀的颗粒。 形成纹理表面，其在热成型后可用作浴缸和淋浴间中的防滑表面。