公开(公告)号：US09695056B2

公开(公告)日：2017-07-04

申请号：US14744248

申请日：2015-06-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： Edward W. Corcoran, Jr. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantin Sanz ,  Miguel Palomino Roca

IPC: B01J20/18 ,  C01B39/48 ,  B01J29/70 ,  B01D71/02 ,  B01D53/04 ,  B01D53/047 ,  C01B3/50 ,  B01D53/02 ,  B01D53/22 ,  C01B17/16 ,  C01B21/04 ,  C01C1/12 ,  B01J20/30 ,  C07C1/20 ,  C07C1/32 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C01B39/06 ,  C01B39/08 ,  C01B37/00 ,  C01B37/02 ,  C01B39/12

CPC classification number: C01B39/48 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D53/229 ,  B01D71/028 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2256/26 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/50 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/702 ,  B01D2257/7022 ,  B01D2257/80 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B3/508 ,  C01B17/167 ,  C01B21/0466 ,  C01B37/002 ,  C01B37/007 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B2203/0405 ,  C01B2210/0018 ,  C01C1/12 ,  C07C1/20 ,  C07C1/322 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C07C2529/70 ,  C07C2529/76 ,  C07C2529/78 ,  Y02C10/08

Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

公开(公告)号：US09738539B2

公开(公告)日：2017-08-22

申请号：US14744485

申请日：2015-06-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： Edward W. Corcoran, Jr. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantín Sanz ,  Miguel Palomino Roca

IPC: C01B39/48 ,  B01J20/18 ,  B01J29/70 ,  B01D71/02 ,  B01D53/04 ,  B01D53/047 ,  C01B3/50 ,  B01D53/02 ,  B01D53/22 ,  C01B17/16 ,  C01B21/04 ,  C01C1/12 ,  B01J20/30 ,  C07C1/20 ,  C07C1/32 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C01B39/06 ,  C01B39/08 ,  C01B37/00 ,  C01B37/02 ,  C01B39/12

CPC classification number: C01B39/48 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D53/229 ,  B01D71/028 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2256/26 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/50 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/702 ,  B01D2257/7022 ,  B01D2257/80 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B3/508 ,  C01B17/167 ,  C01B21/0466 ,  C01B37/002 ,  C01B37/007 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B2203/0405 ,  C01B2210/0018 ,  C01C1/12 ,  C07C1/20 ,  C07C1/322 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C07C2529/70 ,  C07C2529/76 ,  C07C2529/78 ,  Y02C10/08

Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

公开(公告)号：US10703986B1

公开(公告)日：2020-07-07

申请号：US16261748

申请日：2019-01-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Pedro Serna Merino ,  Jadeene E. Gabay ,  Avelino Corma Canos ,  Manuel Moliner Marin

IPC: C10G11/05 ,  B01J29/70 ,  C01B32/40 ,  C01B32/50

Abstract: Systems and methods are provided for selective oxidation of CO and/or C3− hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C3− hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.

公开(公告)号：US20200239784A1

公开(公告)日：2020-07-30

申请号：US16261748

申请日：2019-01-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Pedro Serna Merino ,  Jadeene E. Gabay ,  Avelino Corma Canos ,  Manuel Moliner Marin

IPC: C10G11/05 ,  B01J29/70 ,  C01B32/40 ,  C01B32/50

Abstract: Systems and methods are provided for selective oxidation of CO and/or C3− hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C3− hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.

公开(公告)号：US09688542B2

公开(公告)日：2017-06-27

申请号：US14744334

申请日：2015-06-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： Edward W. Corcoran, Jr. ,  Pavel Kortunov ,  Charanjit S. Paur ,  Peter I. Ravikovitch ,  Yu Wang ,  Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia ,  Angel Cantin Sanz ,  Miguel Palomino Roca

IPC: B01D53/22 ,  B01D53/02 ,  B01J20/18 ,  C01B3/50 ,  C01B17/16 ,  C01B21/04 ,  C01B39/48 ,  C01C1/12 ,  B01J29/70 ,  B01D71/02 ,  B01D53/04 ,  B01D53/047 ,  B01J20/30 ,  C07C1/20 ,  C07C1/32 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C01B39/06 ,  C01B39/08 ,  C01B37/00 ,  C01B37/02 ,  C01B39/12

CPC classification number: C01B39/48 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0407 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D53/229 ,  B01D71/028 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2256/26 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/50 ,  B01D2257/504 ,  B01D2257/70 ,  B01D2257/702 ,  B01D2257/7022 ,  B01D2257/80 ,  B01J20/18 ,  B01J20/3078 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B3/508 ,  C01B17/167 ,  C01B21/0466 ,  C01B37/002 ,  C01B37/007 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B2203/0405 ,  C01B2210/0018 ,  C01C1/12 ,  C07C1/20 ,  C07C1/322 ,  C07C2/76 ,  C07C29/00 ,  C07C41/01 ,  C07C2529/70 ,  C07C2529/76 ,  C07C2529/78 ,  Y02C10/08

Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.