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公开(公告)号：US09738539B2
公开(公告)日：2017-08-22
申请号：US14744485
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantín Sanz , Miguel Palomino Roca
IPC: C01B39/48 , B01J20/18 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , C01B3/50 , B01D53/02 , B01D53/22 , C01B17/16 , C01B21/04 , C01C1/12 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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公开(公告)号：US20220280911A1
公开(公告)日：2022-09-08
申请号：US17634960
申请日：2020-07-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Yu Wang , Quanchang Li , Stephen M. Cundy , Harry W. Deckman
IPC: B01J20/18 , B01J20/32 , B01D53/047
Abstract: A method of increasing hydrothermal stability of an adsorbent comprising a small pore cationic zeolite in a swing adsorption process is disclosed. The method comprises the steps of coating the zeolite with a silylation agent to result in a silylated zeolite; and performing the swing adsorption process. The swing adsorption process comprises contacting the silylated zeolite with feed stream comprising water. The swing adsorption process may comprise removing CO2 from a feed stream comprising CO2 and water.
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公开(公告)号：US09695056B2
公开(公告)日：2017-07-04
申请号：US14744248
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Miguel Palomino Roca
IPC: B01J20/18 , C01B39/48 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , C01B3/50 , B01D53/02 , B01D53/22 , C01B17/16 , C01B21/04 , C01C1/12 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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公开(公告)号：US09688542B2
公开(公告)日：2017-06-27
申请号：US14744334
申请日：2015-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Edward W. Corcoran, Jr. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Miguel Palomino Roca
IPC: B01D53/22 , B01D53/02 , B01J20/18 , C01B3/50 , C01B17/16 , C01B21/04 , C01B39/48 , C01C1/12 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B37/02 , C01B39/12
CPC classification number: C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
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