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公开(公告)号：US20180265789A1
公开(公告)日：2018-09-20
申请号：US15911733
申请日：2018-03-05
CPC分类号： C10G57/005 , C10G50/00 , C10G2300/1081 , C10G2400/02
摘要： Methods and systems producing gasoline boiling range hydrocarbons from light paraffins are disclosed. Such methods may include exposing a paraffin-containing stream to a catalyst in a side riser of a fluid catalytic cracking reactor under effective conditions for dehydrogenating at least a portion of paraffins in the stream into olefins and thereby producing an olefin-containing stream, wherein the paraffin-containing stream comprises greater than 50 wt % isobutane; and alkylating olefins in the olefin-containing stream to produce a product stream comprising an alkylate fraction comprising hydrocarbons boiling between 100° F. and 400° F.
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2.发明申请FCC REACTOR AND RISER DESIGN FOR SHORT CONTACT-TIME CATALYTIC CRACKING OF HYDROCARBONS 有权FCC反应器和升级器设计用于短时间联合催化裂化烃公开(公告)号：US20130084219A1
公开(公告)日：2013-04-04
申请号：US13685866
申请日：2012-11-27
发明人： Robert F. Tammera , Edward Nicholas Jones , Christopher G. Smalley , Phillip A. Deis , Alvin U. Chen , Christopher S. Gurciullo
IPC分类号： B01J8/20
摘要： The present invention is an improved design and operation of a short contact time Fluid Catalytic Cracking (FCC) Reactor wherein the upper internal riser and a lower internal riser are in fluid connection with one another and provide an improved disengaging zone for entraining the vapors from the dilute phase area of the FCC reactor. Detailed preferred embodiments include improvements over the prior art to the internal central riser, riser termination apparatus, cyclone separators, and a coke mitigation baffle system, as well as associated improved fluid catalytic cracking processes utilizing the novel reactor design.
摘要翻译： 本发明是短接触时间流体催化裂化（FCC）反应器的改进的设计和操作，其中上部内部提升管和下部内部提升管彼此流体连接并提供改进的分离区，用于将蒸气从 FCC反应器的稀相面积。 详细的优选实施例包括现有技术对内部中央提升管，提升管终止装置，旋风分离器和焦炭缓解挡板系统的改进，以及利用新型反应器设计的相关联的改进的流化催化裂化方法。
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公开(公告)号：US10323196B2
公开(公告)日：2019-06-18
申请号：US15911733
申请日：2018-03-05
摘要： Methods and systems producing gasoline boiling range hydrocarbons from light paraffins are disclosed. Such methods may include exposing a paraffin-containing stream to a catalyst in a side riser of a fluid catalytic cracking reactor under effective conditions for dehydrogenating at least a portion of paraffins in the stream into olefins and thereby producing an olefin-containing stream, wherein the paraffin-containing stream comprises greater than 50 wt % isobutane; and alkylating olefins in the olefin-containing stream to produce a product stream comprising an alkylate fraction comprising hydrocarbons boiling between 100° F. and 400° F.
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公开(公告)号：US20160362614A1
公开(公告)日：2016-12-15
申请号：US15156637
申请日：2016-05-17
CPC分类号： C10G11/18 , B01J8/24 , B01J38/14 , B01J38/36 , B01J2208/00752 , C10G11/182 , C10G2300/4093 , C10G2300/70
摘要： An FCC unit enables the normal regenerator to be eliminated by carrying out catalyst regeneration in the reactor section of the unit using air, oxygen-enriched air or even relatively pure oxygen as the stripping medium in the stripping section of the reactor while maintaining overall reducing conditions so that sulfur and nitrogen are produced in the form of hydrogen sulfide, ammonia and other reduced species. The combustion gases from the stripper are sent from the reactor with the cracking vapors to the FCC main fractionator, wet gas compressor and gas plant to process the by-products of the coke combustion along with the FCC reactor effluent. The principle is applicable to grass-roots FCC units with its potential for elimination of a major unit component but it also has potential for application to existing units to reduce the load on the regenerator or eliminate the need for the existing regenerator so that an existing regenerator may be converted to a parallel or auxiliary reactor system.
摘要翻译： FCC装置使得能够通过在反应器部分中进行催化剂再生来消除正常的再生器，所述反应器部分使用空气，富氧空气或甚至相对纯的氧作为反应器的汽提部分中的汽提介质，同时保持总体还原条件 使得硫和氮以硫化氢，氨等还原物质的形式产生。 来自汽提器的燃烧气体从具有裂解蒸汽的反应器送入FCC主分馏器，湿气压缩机和气体设备，以与FCC反应器流出物一起处理焦炭燃烧的副产物。 该原则适用于具有消除主要单元组件的潜力的基层FCC单元，但它也具有应用于现有单元以减少再生器负载的潜力，或者消除对现有再生器的需要，使得现有的再生器 可以转换为并联或辅助反应器系统。
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5.发明申请INTEGRATED PROCESS FOR CONVERTING LIGHT PARAFFINS TO GASOLINE AND DISTILLATE 审中-公开用于将光调节剂转化为汽油和蒸馏的集成方法公开(公告)号：US20160264492A1
公开(公告)日：2016-09-15
申请号：US15060888
申请日：2016-03-04
CPC分类号： C07C2/12 , C07C4/04 , C07C2529/40 , C10G9/36 , C10G50/00 , C10G57/02 , C10G2300/104 , C10G2300/1044 , C10G2300/1059 , C10G2300/1081 , C10G2400/02
摘要： An integrated process for converting light (C2-C5) paraffins to hydrocarbon products in the gasoline and distillate boiling range in which a light paraffin fraction is subjected to steam cracking under conditions to maximize weight of C5+ molecules plus a multiple of the weight of C4− olefins. This multiple is preferably between 0.7-1 to result in maximum volume of gasoline and distillate production in the overall conversion to products. Light (C2-C5) olefins are oligomerized in a zeolite-catalyzed fluidized bed oligomerization at elevated temperature to produce oligomerized products in the gasoline and middle distillate boiling range.
摘要翻译： 将轻质（C2-C5）链烷烃转化为汽油和馏出物沸点范围内的烃产物的综合方法，其中轻链烷烃馏分在使C5 +分子的重量加重C4重量的条件下进行蒸汽裂解， 烯烃。 该倍数优选在0.7-1之间，导致在产品的总体转化中汽油和馏出物产量的最大体积。 轻质（C 2 -C 5）烯烃在沸石催化的流化床低聚中在高温下低聚以在汽油和中间馏分沸点范围内产生低聚产物。
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公开(公告)号：US20200248079A1
公开(公告)日：2020-08-06
申请号：US16263026
申请日：2019-01-31
发明人： Arsam Behkish , Brian A. Cunningham , Anjaneya S. Kovvali , Brenda A. Raich , Christopher G. Smalley
IPC分类号： C10G63/04
摘要： Systems and methods are provided for conversion of light paraffinic gases to form liquid products in a two-stage reaction system. In a first stage, the light paraffinic gas is exposed to heat transfer particles in a side riser, where the heat transfer particles correspond to particles used in a separate process. Examples of a separate process include fluidized coking and fluid catalytic cracking. The conditions in the side riser can be selected to allow for conversion of at least a portion of the paraffins to olefins. After conversion, the converted olefin stream is passed to the second reaction stage while the heat transfer particles are returned to the separate process. The converted olefin stream is then exposed to a conversion catalyst under conditions for forming aromatics from the converted olefin stream in a second reaction stage. By performing the initial alkane conversion to olefins in the first reaction stage, the amount of coke formed during the aromatics formation process is reduced or minimized.
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7.发明授权公开(公告)号：US09394488B2
公开(公告)日：2016-07-19
申请号：US13860798
申请日：2013-04-11
CPC分类号： C10G11/187 , B01J8/085 , B01J8/1809 , B01J2208/00902 , C10G2300/4006
摘要： A method of improving the uniformity of the contacting of a heavy oil feed with FCC cracking catalyst in the feed zone of an FCC cracking riser in which the heavy oil feed is injected into the catalyst in the riser by means of feed injectors located around the riser, the method comprising minimizing the differences in the temperature profile in the oil/catalyst mixture across the feed zone by varying the oil feed rate to the injectors.
摘要翻译： 一种改进FCC裂化提升管进料区中重油进料与FCC裂化催化剂接触的均匀性的方法，其中重油进料通过位于提升管周围的进料喷射器注入到提升管中的催化剂中 该方法包括通过改变向喷射器的供油速率来最小化在进料区中的油/催化剂混合物中的温度分布的差异。
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公开(公告)号：US09358516B2
公开(公告)日：2016-06-07
申请号：US13685866
申请日：2012-11-27
发明人： Robert F. Tammera , Edward Nicholas Jones , Christopher G. Smalley , Phillip A. Deis , Alvin U. Chen , Christopher S. Gurciullo
摘要： The present invention is an improved design and operation of a short contact time Fluid Catalytic Cracking (FCC) Reactor wherein the upper internal riser and a lower internal riser are in fluid connection with one another and provide an improved disengaging zone for entraining the vapors from the dilute phase area of the FCC reactor. Detailed preferred embodiments include improvements over the prior art to the internal central riser, riser termination apparatus, cyclone separators, and a coke mitigation baffle system, as well as associated improved fluid catalytic cracking processes utilizing the novel reactor design.
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9.发明申请公开(公告)号：US20180169602A1
公开(公告)日：2018-06-21
申请号：US15825174
申请日：2017-11-29
发明人： Mohsen N. Harandi , Alvin U. Chen , Charles R. Bolz , Christopher G. Smalley , Masaaki Sugita , Suriyanarayanan Rajagopalan , Bing Du
CPC分类号： B01J8/26 , B01J8/1863 , B01J8/1872 , B01J8/30 , B01J8/388 , B01J29/40 , B01J29/90 , B01J38/14 , C07C2/12 , C10G11/182 , C10G2300/1092 , C10G2300/708 , C10G2400/02
摘要： A method is provided for upgrading a hydrocarbon feed. The method may include contacting a hydrocarbon feed with a catalyst in a fluidized bed reactor; directing a portion of the catalyst from the fluidized bed reactor to a regeneration zone, such that the portion of the catalyst flows in a first direction through the regeneration zone; directing combustion air into the regeneration zone in a counter-flow direction to the first direction, wherein the combustion air is provided at a rate of about 100.05% or less of the stoichiometric air requirement for combusting coke present on the portion of catalyst; regenerating the portion of the catalyst in the regeneration zone to produce regenerated catalyst; and directing a portion of the hydrocarbon feed to combine with the regenerated catalyst downstream of the regeneration zone and lift the regenerated catalyst back to the fluidized bed reactor.
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公开(公告)号：US09890334B2
公开(公告)日：2018-02-13
申请号：US15156637
申请日：2016-05-17
CPC分类号： C10G11/18 , B01J8/24 , B01J38/14 , B01J38/36 , B01J2208/00752 , C10G11/182 , C10G2300/4093 , C10G2300/70
摘要： An FCC unit enables the normal regenerator to be eliminated by carrying out catalyst regeneration in the reactor section of the unit using air, oxygen-enriched air or even relatively pure oxygen as the stripping medium in the stripping section of the reactor while maintaining overall reducing conditions so that sulfur and nitrogen are produced in the form of hydrogen sulfide, ammonia and other reduced species. The combustion gases from the stripper are sent from the reactor with the cracking vapors to the FCC main fractionator, wet gas compressor and gas plant to process the by-products of the coke combustion along with the FCC reactor effluent. The principle is applicable to grass-roots FCC units with its potential for elimination of a major unit component but it also has potential for application to existing units to reduce the load on the regenerator or eliminate the need for the existing regenerator so that an existing regenerator may be converted to a parallel or auxiliary reactor system.
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