公开(公告)号：US20140087985A1

公开(公告)日：2014-03-27

申请号：US14017651

申请日：2013-09-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu Onkar Patil ,  John W. Chu ,  Satish Bodige ,  Liehpao Oscar Farng ,  Donna Jean Crowther ,  Man Kit Ng ,  Patrick Brant ,  Kathryn L. Peretti

IPC: C10M149/04 ,  C10L1/185 ,  C10L1/228 ,  C10M145/04

CPC classification number: C10M149/04 ,  C10L1/1857 ,  C10L1/2283 ,  C10M133/54 ,  C10M145/04 ,  C10M159/12 ,  C10M2205/0285 ,  C10M2215/26 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10

Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

Abstract translation: 本公开涉及用作燃料和润滑剂的添加剂的组合物，其包括基于乙烯基封端的大分子单体（VTM）的醛的还原胺化产物。 任选地，醛与氨基化合物在足以产生亚胺中间体的缩合条件下反应，并且亚胺中间体在足以产生组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。 一种制备用作燃料和润滑剂添加剂的组合物的还原胺化方法。 该方法包括使VTM基醛与含有至少一个-NH-基团的氨基化合物在足以产生亚胺中间体的缩合条件下反应，并使亚胺中间体在足以产生所述组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。

公开(公告)号：US20140087983A1

公开(公告)日：2014-03-27

申请号：US14017721

申请日：2013-09-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu Onkar Patil ,  Satish Bodige ,  Liehpao Oscar Farng ,  Kathryn L. Peretti

IPC: C10M149/04

CPC classification number: C10M149/04 ,  C08F8/08 ,  C10L1/238 ,  C10L1/2383 ,  C10M133/54 ,  C10M149/14 ,  C10M149/16 ,  C10M2205/0285 ,  C10M2215/042 ,  C10M2215/064 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/06 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10 ,  C10N2270/00 ,  C08F210/06

Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including an amination product of an epoxidized vinyl terminated macromonomer (VTM) and an amino compound containing at least one —NH— group. The epoxidized VTM is reacted with the amino compound containing at least one —NH— group under amination conditions sufficient to give said composition. The epoxidized VTM is formed by reacting a VTM with an epoxidizing agent under epoxidation conditions sufficient to give an epoxidized VTM. An amination method for making a composition for use as an additive for fuels and lubricants. The method comprises reacting an epoxidized VTM with an amino compound containing at least one —NH— group under amination conditions sufficient to give the composition. The epoxidized VTM is formed by reacting a VTM with an epoxidizing agent under epoxidation conditions sufficient to give an epoxidized VTM.

Abstract translation: 本公开涉及用作燃料和润滑剂的添加剂的组合物，其包括环氧乙烯基封端的大分子单体（VTM）的胺化产物和含有至少一个-NH-基团的氨基化合物。 环氧化VTM与含有至少一个-NH-基团的氨基化合物在足以产生所述组合物的胺化条件下反应。 环氧化的VTM通过使VTM与环氧化剂在足以产生环氧化VTM的环氧化条件下反应而形成。 一种制备用作燃料和润滑剂添加剂的组合物的胺化方法。 该方法包括在足以产生组合物的胺化条件下使环氧化VTM与含有至少一个-NH-基团的氨基化合物反应。 环氧化的VTM通过使VTM与环氧化剂在足以产生环氧化VTM的环氧化条件下反应而形成。