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    Polymers as additives for fuels
    1.
    发明授权
    Polymers as additives for fuels 有权

    公开(公告)号：US11566196B2

    公开(公告)日：2023-01-31

    申请号：US17171456

    申请日：2021-02-09

    Applicant: BASF SE

    Inventor： Maxim Peretolchin ,  Ivette Garcia Castro ,  Aaron Flores-Figueroa

    IPC: C10L10/04 ,  C10L1/2383 ,  C10M149/04 ,  C10L10/06 ,  C10M149/06 ,  C10L10/08 ,  C10L1/196 ,  C10L1/198 ,  C10L1/236

    Abstract: A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.

    Lubricant additive compositions having improved viscosity index increase properties
    3.
    发明授权
    Lubricant additive compositions having improved viscosity index increase properties 有权
    具有改善粘度指数的润滑添加剂组合物增加性能

    公开(公告)号：US08778857B2

    公开(公告)日：2014-07-15

    申请号：US12537029

    申请日：2009-08-06

    Applicant: Peter Growcott

    Inventor： Peter Growcott

    IPC: C10M149/14 ,  C10M149/04 ,  C10M149/00

    CPC classification number: C10M157/00 ,  C10M2205/022 ,  C10M2205/026 ,  C10M2205/04 ,  C10M2205/08 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2220/033 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2230/74 ,  C10N2240/10 ,  C10N2270/02 ,  C10M2205/024 ,  C10M2205/06

    Abstract: A lubricant composition, additive concentrate, and method for lubricating an engine. The crankcase lubricant has less than 30 weight percent of a relatively low Noack volatility base oil and a viscosity additive. The viscosity additive has a minor effective amount of sacrificial polymeric viscosity index improver having a shear stability index (SSI) of greater than about 45 and a major amount of a viscosity index improver having an SSI of less than about 26. The minor amount of sacrificial viscosity index improver additive is effective to provide a lubricant composition having a ratio of absolute viscosity increase at 40° C. to an absolute viscosity increase at 40° C. of an RL 216 reference oil of less than about 0.8.

    Abstract translation: 润滑剂组合物，添加剂浓缩物和用于润滑发动机的方法。 曲轴箱润滑剂具有小于30重量％的相对较低的Noack挥发性基础油和粘度添加剂。 粘度添加剂具有少量有效量的牺牲聚合物粘度指数改进剂，其剪切稳定性指数（SSI）大于约45，而主要量的SSI小于约26的粘度指数改进剂。少量的牺牲 粘度指数改进剂添加剂有效地提供一种润滑剂组合物，该润滑剂组合物在40℃下的绝对粘度增加的比率与小于约0.8的RL 216参比油在40℃下的绝对粘度增加有关。

    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF
    4.
    发明申请
    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF 有权
    润滑剂和燃料分散剂及其制备方法

    公开(公告)号：US20140087985A1

    公开(公告)日：2014-03-27

    申请号：US14017651

    申请日：2013-09-04

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  John W. Chu ,  Satish Bodige ,  Liehpao Oscar Farng ,  Donna Jean Crowther ,  Man Kit Ng ,  Patrick Brant ,  Kathryn L. Peretti

    IPC: C10M149/04 ,  C10L1/185 ,  C10L1/228 ,  C10M145/04

    CPC classification number: C10M149/04 ,  C10L1/1857 ,  C10L1/2283 ,  C10M133/54 ,  C10M145/04 ,  C10M159/12 ,  C10M2205/0285 ,  C10M2215/26 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10

    Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

    Abstract translation: 本公开涉及用作燃料和润滑剂的添加剂的组合物，其包括基于乙烯基封端的大分子单体（VTM）的醛的还原胺化产物。 任选地，醛与氨基化合物在足以产生亚胺中间体的缩合条件下反应，并且亚胺中间体在足以产生组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。 一种制备用作燃料和润滑剂添加剂的组合物的还原胺化方法。 该方法包括使VTM基醛与含有至少一个-NH-基团的氨基化合物在足以产生亚胺中间体的缩合条件下反应，并使亚胺中间体在足以产生所述组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。

    Additive composition comprising an amidized or imidized polymer
    7.
    发明授权
    Additive composition comprising an amidized or imidized polymer 有权
    包含酰胺化或酰亚胺化聚合物的添加剂组合物

    公开(公告)号：US08338343B2

    公开(公告)日：2012-12-25

    申请号：US11921858

    申请日：2006-06-08

    Applicant: Patric Meessen ,  Gerhard Van Vliet ,  Gerardus Arnoldus Rademakers ,  Johannes Hendrik Geesink ,  Zhaoyao Joe Qiu ,  Franciscus Victoire Paulus Houtvast

    Inventor： Patric Meessen ,  Gerhard Van Vliet ,  Gerardus Arnoldus Rademakers ,  Johannes Hendrik Geesink ,  Zhaoyao Joe Qiu ,  Franciscus Victoire Paulus Houtvast

    IPC: C10M149/04 ,  C08F255/00 ,  C08F255/02

    CPC classification number: C10M177/00 ,  C08F8/32 ,  C08F8/48 ,  C08F8/50 ,  C08F255/04 ,  C08F2800/20 ,  C08F2810/10 ,  C10M133/56 ,  C10M149/06 ,  C10M149/10 ,  C10M2215/28 ,  C10M2215/30 ,  C10M2217/024 ,  C10M2217/028 ,  C10M2217/06 ,  C10N2220/021 ,  C10N2230/54 ,  C10N2230/72 ,  C10N2240/10 ,  C10N2270/00 ,  C08F222/06 ,  C08F210/16 ,  C08F210/06 ,  C08F210/02

    Abstract: The invention relates to a process for an additive composition comprising an amidized or imidized polymer. The invention further relates to a highly grafted, multi-functional lubricant additive useful to improve the viscosity index and dispersancy properties of a lubricating oil composition. The present invention also relates to a method of extending lubricant drain intervals and improving fuel economy and fuel economy durability. The additive composition is prepared by: (A) reacting an olefin copolymer of ethylene and at least one C3 to C23 &agr; -olefin comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said C3 to C23 &agr; -olefin and from about 0 to 15 wt percent of a polyene, said copolymer having a number average molecular weight ranging from 1,000 to 500,000, with an olefinic carboxylic acid acylating agent, said process comprising heating said polymer to a molten condition at a temperature in the range of 60° C. to 240° C., grafting, in a first extruder or a first mixing device, said olefinic carboxylic acylating agent onto said copolymer, optionally subsequently reducing the molecular weight of said copolymer at a temperature in the range of 250° C. to 350° C., thereby producing a grafted, reduced molecular weight acylated copolymer having a number average molecular weight ranging from 1,000 to 80,000 and having at least 0.2-20 molecules of said carboxylic acid acylating agent grafted per 1000 C atoms of said olefin copolymer, and (B) reacting, in a second extruder or a second mixing device, said acylated copolymer made in (A) with a polyamine.

    Abstract translation: 本发明涉及包含酰胺化或酰亚胺化聚合物的添加剂组合物的方法。 本发明还涉及可用于改善润滑油组合物的粘度指数和分散性的高度接枝的多功能润滑剂添加剂。 本发明还涉及一种延长润滑剂排放间隔并提高燃料经济性和燃料经济性的耐久性的方法。 通过以下方法制备添加剂组合物：（A）使乙烯和至少一种C3至C23的烯烃共聚物与 α-烯烃，其包含约15至80摩尔％的乙烯，约20至85摩尔％的所述C 3至C 23亚烷基; 烯烃和约0至15重量％的多烯，所述共聚物的数均分子量为1,000至500,000，与烯属羧酸酰化剂，所述方法包括将所述聚合物加热至熔融条件，温度为 在60℃至240℃的范围内，在第一挤出机或第一混合装置中将所述烯烃羧酸酰化剂接枝到所述共聚物上，任选地随后在所述共聚物的温度范围内降低所述共聚物的分子量 250℃至350℃，从而产生数均分子量为1,000至80,000并具有至少0.2-20分子的每1000个碳原子接枝的所述羧酸酰化剂的接枝的，分子量较低的酰化共聚物 的所述烯烃共聚物，和（B）在第二挤出机或第二混合装置中使（A）制成的所述酰化共聚物与多胺反应。

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