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    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF
    3.
    发明申请
    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF 有权
    润滑剂和燃料分散剂及其制备方法

    公开(公告)号：US20140087983A1

    公开(公告)日：2014-03-27

    申请号：US14017721

    申请日：2013-09-04

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  Satish Bodige ,  Liehpao Oscar Farng ,  Kathryn L. Peretti

    IPC: C10M149/04

    CPC classification number: C10M149/04 ,  C08F8/08 ,  C10L1/238 ,  C10L1/2383 ,  C10M133/54 ,  C10M149/14 ,  C10M149/16 ,  C10M2205/0285 ,  C10M2215/042 ,  C10M2215/064 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/06 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10 ,  C10N2270/00 ,  C08F210/06

    Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including an amination product of an epoxidized vinyl terminated macromonomer (VTM) and an amino compound containing at least one —NH— group. The epoxidized VTM is reacted with the amino compound containing at least one —NH— group under amination conditions sufficient to give said composition. The epoxidized VTM is formed by reacting a VTM with an epoxidizing agent under epoxidation conditions sufficient to give an epoxidized VTM. An amination method for making a composition for use as an additive for fuels and lubricants. The method comprises reacting an epoxidized VTM with an amino compound containing at least one —NH— group under amination conditions sufficient to give the composition. The epoxidized VTM is formed by reacting a VTM with an epoxidizing agent under epoxidation conditions sufficient to give an epoxidized VTM.

    Abstract translation: 本公开涉及用作燃料和润滑剂的添加剂的组合物，其包括环氧乙烯基封端的大分子单体（VTM）的胺化产物和含有至少一个-NH-基团的氨基化合物。 环氧化VTM与含有至少一个-NH-基团的氨基化合物在足以产生所述组合物的胺化条件下反应。 环氧化的VTM通过使VTM与环氧化剂在足以产生环氧化VTM的环氧化条件下反应而形成。 一种制备用作燃料和润滑剂添加剂的组合物的胺化方法。 该方法包括在足以产生组合物的胺化条件下使环氧化VTM与含有至少一个-NH-基团的氨基化合物反应。 环氧化的VTM通过使VTM与环氧化剂在足以产生环氧化VTM的环氧化条件下反应而形成。

    High viscosity, functionalized metallocene polyalphaolefin base stocks and processes for preparing same
    5.
    发明授权
    High viscosity, functionalized metallocene polyalphaolefin base stocks and processes for preparing same 有权
    高粘度，官能化茂金属聚α-烯烃基础油料及其制备方法

    公开(公告)号：US09458403B2

    公开(公告)日：2016-10-04

    申请号：US14017826

    申请日：2013-09-04

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  Shuji Luo ,  Satish Bodige

    IPC: C10M133/12 ,  C10M135/22 ,  C07C381/00 ,  C07C211/00 ,  C10M107/46 ,  C10M107/42 ,  C10M177/00 ,  C10M107/40 ,  C10M107/44

    CPC classification number: C10M107/46 ,  C10M107/40 ,  C10M107/42 ,  C10M107/44 ,  C10M177/00 ,  C10M2205/0285 ,  C10M2217/065 ,  C10M2221/0405 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/10 ,  C10N2260/09 ,  C10N2260/10

    Abstract: A process for producing a high viscosity functionalized metallocene polyalphaolefin (mPAO) fluid. The process includes providing a mPAO having a terminal double bond, said mPAO produced by the metallocene-catalyzed oligomerization or polymerization of an alpha-olefin feed; providing at least one of a substituted or unsubstituted alkyl thiol, aryl thiol, diphenylamine or naphthalene; and reacting, optionally in the presence of a catalyst or initiator, the mPAO having a terminal double bond with at least one of the substituted or unsubstituted alkyl thiol, aryl thiol, diphenylamine or naphthalene, under reaction conditions sufficient to produce the functionalized high viscosity mPAO fluid. The functionalized mPAO fluid has, as synthesized, a viscosity (Kv100) from 135 to 900 cSt at 100° C.; a viscosity index (VI) greater than 150; a pour point (PP) less than −25° C.; a molecular weight distribution (Mw/Mn) less than 2.0; a residual unsaturation (Bromine Number) less than 2.0; and a glass transition temperature Tg less than −30° C.

    Abstract translation: 一种生产高粘度官能化茂金属聚α-烯烃（mPAO）流体的方法。 该方法包括提供具有末端双键的mPAO，所述mPAO通过茂金属催化的α-烯烃进料的低聚或聚合产生; 提供取代或未取代的烷基硫醇，芳基硫醇，二苯胺或萘中的至少一种; 并且任选地在催化剂或引发剂存在下，在足以产生官能化的高粘度mPAO的反应条件下使具有末端双键的mPAO与至少一个取代或未取代的烷基硫醇，芳基硫醇，二苯胺或萘反应 流体。 官能化的mPAO流体在100℃下具有135至900cSt的粘度（Kv100）。 粘度指数（VI）大于150; 倾点（PP）小于-25°C; 分子量分布（Mw / Mn）小于2.0; 残余不饱和度（溴数）小于2.0; 玻璃化转变温度Tg小于-30℃。

    LOW VISCOSITY LUBRICATING OIL BASE STOCKS AND PROCESSES FOR PREPARING SAME
    6.
    发明申请
    LOW VISCOSITY LUBRICATING OIL BASE STOCKS AND PROCESSES FOR PREPARING SAME 有权
    低粘度润滑油基料及其制备方法

    公开(公告)号：US20140121143A1

    公开(公告)日：2014-05-01

    申请号：US13660152

    申请日：2012-10-25

    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

    Inventor： Abhimanyu Onkar Patil ,  Satish Bodige ,  Shuji Luo

    IPC: C10M105/72 ,  C07C323/22 ,  C07C321/04

    CPC classification number: C10M105/72 ,  C07C321/14 ,  C07C323/52 ,  C10M135/26 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2219/081 ,  C10M2219/085 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/74 ,  C10N2270/00

    Abstract: A composition that includes one or more compounds represented by the formula (R1)a(X)(R2)b wherein R1 and R2 are the same or different and are the residue of an alkyl group having from 4 to 40 carbon atoms, X is the residue of an aliphatic polythiol, aromatic polythiol, cycloaliphatic polythiol, ester or acid containing thiol, or ester or acid containing polythiol, a is a value from 1 to 6, and b is a value from 0 to 6. The composition has a viscosity (Kv100) from 2 to 30 at 100° C., a viscosity index (VI) from 100 to 200, and a Noack volatility of no greater than 20 percent. The disclosure also relates to a process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method thr improving one or more of solubility and dispersancy of polar additives in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.

    Abstract translation: 一种组合物，其包含一种或多种由式（R 1）a（X）（R 2）b表示的化合物，其中R 1和R 2相同或不同，为具有4至40个碳原子的烷基的残基，X为 脂族多硫醇，芳族多硫醇，脂环族多硫醇，含有酯或酸的硫醇或含有多硫醇的酯或酸的残基a为1至6，b为0至6的值。该组合物的粘度 （Kv100）在100℃下为2至30，粘度指数（VI）为100至200，Noack挥发度不大于20％。 本公开还涉及组合物的制造方法，含有该组合物的润滑油基础油和润滑油，以及通过使用润滑油a改善极性添加剂在润滑油中的溶解度和分散性中的一种或多种的方法 含有组合物的配方油。

    HIGH VISCOSITY, FUNCTIONALIZED METALLOCENE POLYALPHAOLEFIN BASE STOCKS AND PROCESSES FOR PREPARING SAME
    7.
    发明申请
    HIGH VISCOSITY, FUNCTIONALIZED METALLOCENE POLYALPHAOLEFIN BASE STOCKS AND PROCESSES FOR PREPARING SAME 有权
    高粘度，功能金属多金属基底料及其制备方法

    公开(公告)号：US20140087986A1

    公开(公告)日：2014-03-27

    申请号：US14017826

    申请日：2013-09-04

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  Shuji Luo ,  Satish Bodige

    IPC: C10M107/46 ,  C10M107/42

    CPC classification number: C10M107/46 ,  C10M107/40 ,  C10M107/42 ,  C10M107/44 ,  C10M177/00 ,  C10M2205/0285 ,  C10M2217/065 ,  C10M2221/0405 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/10 ,  C10N2260/09 ,  C10N2260/10

    Abstract: A process for producing a high viscosity functionalized metallocene polyalphaolefin (mPAO) fluid. The process includes providing a mPAO having a terminal double bond, said mPAO produced by the metallocene-catalyzed oligomerization or polymerization of an alpha-olefin feed; providing at least one of a substituted or unsubstituted alkyl thiol, aryl thiol, diphenylamine or naphthalene; and reacting, optionally in the presence of a catalyst or initiator, the mPAO having a terminal double bond with at least one of the substituted or unsubstituted alkyl thiol, aryl thiol, diphenylamine or naphthalene, under reaction conditions sufficient to produce the functionalized high viscosity mPAO fluid. The functionalized mPAO fluid has, as synthesized, a viscosity (Kv100) from 135 to 900 cSt at 100° C.; a viscosity index (VI) greater than 150; a pour point (PP) less than −25° C.; a molecular weight distribution (Mw/Mn) less than 2.0; a residual unsaturation (Bromine Number) less than 2.0; and a glass transition temperature Tg less than −30° C.

    Abstract translation: 一种生产高粘度官能化茂金属聚α-烯烃（mPAO）流体的方法。 该方法包括提供具有末端双键的mPAO，所述mPAO通过茂金属催化的α-烯烃进料的低聚或聚合产生; 提供取代或未取代的烷基硫醇，芳基硫醇，二苯胺或萘中的至少一种; 并且任选地在催化剂或引发剂存在下，在足以产生官能化的高粘度mPAO的反应条件下使具有末端双键的mPAO与至少一个取代或未取代的烷基硫醇，芳基硫醇，二苯胺或萘反应 流体。 官能化的mPAO流体在100℃下具有135至900cSt的粘度（Kv100）。 粘度指数（VI）大于150; 倾点（PP）小于-25°C; 分子量分布（Mw / Mn）小于2.0; 残余不饱和度（溴数）小于2.0; 玻璃化转变温度Tg小于-30℃。

    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF
    8.
    发明申请
    LUBRICANT AND FUEL DISPERSANTS AND METHODS OF PREPARATION THEREOF 有权
    润滑剂和燃料分散剂及其制备方法

    公开(公告)号：US20140087985A1

    公开(公告)日：2014-03-27

    申请号：US14017651

    申请日：2013-09-04

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  John W. Chu ,  Satish Bodige ,  Liehpao Oscar Farng ,  Donna Jean Crowther ,  Man Kit Ng ,  Patrick Brant ,  Kathryn L. Peretti

    IPC: C10M149/04 ,  C10L1/185 ,  C10L1/228 ,  C10M145/04

    CPC classification number: C10M149/04 ,  C10L1/1857 ,  C10L1/2283 ,  C10M133/54 ,  C10M145/04 ,  C10M159/12 ,  C10M2205/0285 ,  C10M2215/26 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10

    Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

    Abstract translation: 本公开涉及用作燃料和润滑剂的添加剂的组合物，其包括基于乙烯基封端的大分子单体（VTM）的醛的还原胺化产物。 任选地，醛与氨基化合物在足以产生亚胺中间体的缩合条件下反应，并且亚胺中间体在足以产生组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。 一种制备用作燃料和润滑剂添加剂的组合物的还原胺化方法。 该方法包括使VTM基醛与含有至少一个-NH-基团的氨基化合物在足以产生亚胺中间体的缩合条件下反应，并使亚胺中间体在足以产生所述组合物的氢化条件下反应。 醛通过使VTM在足以形成醛的加氢甲酰化条件下反应形成。

    Low viscosity lubricating oil base stocks and processes for preparing same
    9.
    发明授权
    Low viscosity lubricating oil base stocks and processes for preparing same 有权
    低粘度润滑油基础油料及其制备方法

    公开(公告)号：US09243201B2

    公开(公告)日：2016-01-26

    申请号：US13660122

    申请日：2012-10-25

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Abhimanyu Onkar Patil ,  Shuji Luo ,  Satish Bodige

    IPC: C10M107/46 ,  C10M105/72 ,  C10M105/18

    CPC classification number: C10M105/72 ,  C10M105/18 ,  C10M2205/0206 ,  C10M2205/173 ,  C10M2207/0406 ,  C10M2219/081 ,  C10M2219/082 ,  C10N2230/04 ,  C10N2230/54 ,  C10N2230/70 ,  C10N2230/74 ,  C10N2240/10

    Abstract: A composition that includes one or more compounds represented by the formula R1(X)R2 wherein R1 is an alkyl group having from 4 to 40 carbon atoms, R2 is an aliphatic group having from 4 to 20 carbon atoms, an aromatic group having from 6 to 20 carbon atoms, or a cycloaliphatic group having from 5 to 20 carbon atoms, and X is a heteroatom. The composition has a viscosity (Kv100) from 2 to 30 at 100° C., a viscosity index (VI) from 100 to 200, and a Noack volatility of no greater than 20 percent. The disclosure also relates to a process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of solubility and dispersancy of polar additives in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.

    Abstract translation: 一种组合物，其包含一种或多种由式R 1（X）R 2表示的化合物，其中R 1是具有4至40个碳原子的烷基，R 2是具有4至20个碳原子的脂族基团，具有6个 至20个碳原子，或具有5至20个碳原子的脂环族基团，X是杂原子。 该组合物在100℃下的粘度（Kv100）为2〜30，粘度指数（VI）为100〜200，Noack挥发度为20％以下。 本公开还涉及一种制备组合物的方法，含有该组合物的润滑油基础油和润滑油，以及通过使用润滑油将改善极性添加剂在润滑油中的溶解度和分散性中的一种或多种的方法 含有组合物的配方油。

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