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1.
公开(公告)号:US12053738B2
公开(公告)日:2024-08-06
申请号:US17537654
申请日:2021-11-30
Applicant: ExxonMobil Technology and Engineering Company , BASF
Inventor: Carla S. Pereira , Michael Siskin , Thomas Ingram , Gerald Vorberg , Martin Ernst
CPC classification number: B01D53/1493 , B01D53/1425 , B01D53/1468 , B01D53/18 , C10L3/10 , C10L3/103 , B01D2252/204 , B01D2252/20431 , B01D2252/20478 , B01D2252/20489 , B01D2257/304 , B01D2257/504 , C10L2290/542 , Y02C20/40
Abstract: A process for selectively separating H2S from a gas mixture which also comprises CO2 is disclosed. A stream of the gas mixture is contacted with an absorbent solution comprising one or more amines, alkanolamines, hindered alkanolamines, capped alkanolamines, or mixtures thereof. The H2S/CO2 selectivity of the absorbent solution is preferably greater than about 4.0 for an acid gas loading [mol(CO2+H2S)/mol(amine)] between about 0.2 and about 0.6, and is achieved by reducing pH of the absorbent solution.
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公开(公告)号:US11476486B2
公开(公告)日:2022-10-18
申请号:US16695286
申请日:2019-11-26
Inventor: Rodrigo F. Blanco Gutierrez , Eric B. Shen , Carla S. Pereira , Keith E. Davis , Hossein Ghezel-Ayagh
IPC: H01M8/14 , H01M8/249 , H01M8/04828 , H01M8/04537 , H01M8/04791 , H01M8/0637 , H01M8/04858
Abstract: Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated CO2 utilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated CO2 utilization.
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公开(公告)号:US11377605B2
公开(公告)日:2022-07-05
申请号:US16839344
申请日:2020-04-03
Inventor: Randall D. Partridge , Benjamin A. McCool , Carla S. Pereira , Dhaval A. Bhandari
Abstract: A molecular separation method can include: passing a deasphalted oil stream through a reactor containing an active substrate, wherein the catalytic active substrate adsorbs heteroatom species from the deasphalted oil stream and produces a pretreated hydrocarbon feed stream essentially free of 4+ ring aromatic molecules (ARC 4+ species), metal species, and heteroatom species; and chromatographically separating with a simulated moving bed apparatus or a true moving bed apparatus (SMB/TMB) the pretreated hydrocarbon feed stream into a saturate fraction and an aromatics fraction.
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公开(公告)号:US12095129B2
公开(公告)日:2024-09-17
申请号:US18110097
申请日:2023-02-15
Inventor: Everett J. O'Neal , Lu Han , Carla S. Pereira , Rodrigo F. Blanco Gutierrez , Timothy M. Healy , Carl A. Willman , Hossein Ghezel-Ayagh , Frank J. Dobek, Jr.
IPC: H01M8/14 , H01M4/86 , H01M8/04119 , H01M8/0438 , H01M8/0444 , H01M8/04746 , H01M8/04791 , H01M8/0612 , H01M8/0637
CPC classification number: H01M8/145 , H01M8/0618 , H01M4/861 , H01M4/8636 , H01M8/04179 , H01M8/04388 , H01M8/04395 , H01M8/04402 , H01M8/0441 , H01M8/04462 , H01M8/0447 , H01M8/04477 , H01M8/04753 , H01M8/04798 , H01M8/0625 , H01M8/0631 , H01M8/0637 , H01M8/14 , H01M2008/147 , H01M2300/0051
Abstract: A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.
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公开(公告)号:US11843150B2
公开(公告)日:2023-12-12
申请号:US17941291
申请日:2022-09-09
Inventor: Rodrigo F. Blanco Gutierrez , Eric B. Shen , Carla S. Pereira , Keith E. Davis , Hossein Ghezel-Ayagh
IPC: H01M8/14 , H01M8/249 , H01M8/04828 , H01M8/04537 , H01M8/04791 , H01M8/0637 , H01M8/04858
CPC classification number: H01M8/145 , H01M8/04589 , H01M8/04805 , H01M8/04843 , H01M8/04952 , H01M8/0637 , H01M8/249 , H01M2008/147
Abstract: Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated CO2 utilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated CO2 utilization.
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公开(公告)号:US11742508B2
公开(公告)日:2023-08-29
申请号:US16696821
申请日:2019-11-26
Inventor: Everett J. O'Neal , Lu Han , Carla S. Pereira , Rodrigo F. Blanco Gutierrez , Timothy M. Healy , Carl A. Willman , Hossein Ghezel-Ayagh , Frank J. Dobek, Jr.
IPC: H01M8/14 , H01M8/0612 , H01M8/04791 , H01M8/0637 , H01M8/0444 , H01M8/04119 , H01M4/86 , H01M8/0438 , H01M8/04746
CPC classification number: H01M8/145 , H01M8/0618 , H01M4/861 , H01M4/8636 , H01M8/0441 , H01M8/0447 , H01M8/04179 , H01M8/04388 , H01M8/04395 , H01M8/04402 , H01M8/04462 , H01M8/04477 , H01M8/04753 , H01M8/04798 , H01M8/0625 , H01M8/0631 , H01M8/0637 , H01M8/14 , H01M2008/147 , H01M2300/0051
Abstract: A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.
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7.
公开(公告)号:US20230226483A1
公开(公告)日:2023-07-20
申请号:US18002519
申请日:2021-07-06
Inventor: Carla S. Pereira , Jenny P. Seagraves , P. Scott Northrop , Michael Siskin , Thomas Ingram , Gerald Vorberg , Martin Ernst , Georg K. Sieder
CPC classification number: B01D53/1425 , B01D53/1468 , B01D53/1493 , B01D53/1475 , B01D53/52 , B01D53/62 , B01D53/78 , B01D53/96 , B01D2257/304 , B01D2257/504 , B01D2252/2041 , B01D2252/20405 , B01D2252/20426 , B01D2252/20452 , B01D2252/20468 , B01D2252/20484 , B01D2252/60
Abstract: Capture of hydrogen sulfide from a gas mixture may be accomplished using an aqueous solution comprising an amine. Certain sterically hindered amines may selectively form a reaction product with hydrogen sulfide under kinetically controlled contacting conditions and afford a light phase and a heavy phase above a critical solution temperature, wherein the hydrogen sulfide may be present in either phase. Upon separation of the light phase from the heavy phase, processing of one of the phases may take place to remove hydrogen sulfide therefrom. Recycling of the amine to an absorber tower may then take place to promote capture of additional hydrogen sulfide.
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公开(公告)号:US20230197994A1
公开(公告)日:2023-06-22
申请号:US18110097
申请日:2023-02-15
Inventor: Everett J. O'Neal , Lu Han , Carla S. Pereira , Rodrigo F. Blanco Gutierrez , Timothy M. Healy , Carl A. Willman , Hossein Ghezel-Ayagh , Frank J. Dobek, JR.
IPC: H01M8/14 , H01M8/0612
CPC classification number: H01M8/145 , H01M8/0618 , H01M2008/147 , H01M8/04798
Abstract: A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.
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公开(公告)号:US20230006236A1
公开(公告)日:2023-01-05
申请号:US17941291
申请日:2022-09-09
Inventor: Rodrigo F. Blanco Gutierrez , Eric B. Shen , Carla S. Pereira , Keith E. Davis , Hossein Ghezel-Ayagh
IPC: H01M8/14
Abstract: Systems and methods are provided for using fuel cell staging to reduce or minimize variations in current density when operating molten carbonate fuel cells with elevated CO2 utilization. The fuel cell staging can mitigate the amount of alternative ion transport that occurs when operating molten carbonate fuel cells under conditions for elevated CO2 utilization.
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