公开(公告)号：US10000713B2

公开(公告)日：2018-06-19

申请号：US14569268

申请日：2014-12-12

申请人： Fluor Technologies Corporation

发明人： John Mak

IPC分类号： C10L3/10 ,  B01D53/14

CPC分类号： C10L3/104 ,  B01D53/1406 ,  B01D53/1425 ,  B01D53/1431 ,  B01D53/1475 ,  B01D53/1493 ,  B01D2252/20 ,  B01D2252/2025 ,  B01D2252/2026 ,  B01D2252/20468 ,  B01D2256/24 ,  B01D2257/304 ,  C10L3/103 ,  C10L2290/06 ,  C10L2290/08 ,  C10L2290/48 ,  C10L2290/541 ,  C10L2290/545 ,  Y02C10/04 ,  Y02C10/06

摘要： A plant includes a pretreatment unit for H2S removal and air dehydration, and at least two absorbers that receive a feed gas at a pressure of at least 300 psig with variable CO2 content (e.g., between 5 to 60 mol %), wherein the feed gas is scrubbed in the absorbers with an ultralean and a semi-lean physical solvent, respectively, at low temperatures to at least partially remove the CO2 from the feed gas. Such configurations produces a low CO2 dry treated gas and a H2S-free CO2 for sequestration while advantageously providing cooling by expansion of the rich solvent that cools the semi-lean solvent and the feed gas, wherein an ultralean solvent is produced by stripping using dry air.

公开(公告)号：US20170114295A1

公开(公告)日：2017-04-27

申请号：US14924311

申请日：2015-10-27

申请人： Fluor Technologies Corporation

发明人： John Mak

IPC分类号： C10L3/10 ,  C01B17/04

CPC分类号： C10L3/104 ,  B01D53/14 ,  B01D53/1406 ,  B01D53/1425 ,  B01D53/1462 ,  B01D2251/606 ,  B01D2252/2026 ,  B01D2252/20405 ,  B01D2252/20431 ,  B01D2252/20468 ,  B01D2252/20489 ,  B01D2252/50 ,  C01B17/0408 ,  C10L3/102 ,  C10L3/103 ,  C10L2290/12 ,  C10L2290/541 ,  C10L2290/542 ,  C10L2290/545

摘要： Plants, processes, and methods for reducing the H2S and CO2 contents of shale gasses from fields that produce shale gasses having varying H2S and CO2 contents are provided. Acid gas enters an absorber and is scrubbed using a lean physical solvent, producing a treated gas and a rich physical solvent. The H2S content of the treated gas is further reduced in an amine absorber, producing a pipeline gas and a semi-lean amine. The pipeline gas contains lower levels of H2S and CO2 than gas produced using a polishing bed. A physical solvent regeneration unit regenerates the lean physical solvent from the rich physical solvent for feeding into the absorption unit. An amine regeneration unit regenerates the lean amine from the semi-lean amine for feeding into the amine absorber. Contemplated plants may further comprise a Claus Unit or a Redox unit for oxidizing H2S to elemental sulfur.

公开(公告)号：US09446346B2

公开(公告)日：2016-09-20

申请号：US14937209

申请日：2015-11-10

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Shinji Murai ,  Yasuhiro Kato ,  Takehiko Muramatsu ,  Satoshi Saito

IPC分类号： C07C215/00 ,  B01D53/14

CPC分类号： B01D53/1493 ,  B01D53/1425 ,  B01D53/1468 ,  B01D53/1475 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20468 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2252/20494 ,  B01D2252/504 ,  B01D2252/602 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/124 ,  Y02C10/06

摘要： There is provided an acidic gas absorbing agent that is large in absorption amount and high in absorption rate of an acidic gas per unit volume and can prevent the diffusion of ingredients of the absorbing agent. The acidic gas absorbing agent includes an amino acid salt of formula 1 or formula 2 and an amine compound of formula 3. wherein COOMe represents a carboxylate group; Me represents an alkali metal. R1 and R2 represent an C1-4 alkylene chain; R3 represents a cycloalkyl group; R4 represents a hydrogen atom or an C1-4 alkyl group; and R5 represents a hydroxyalkyl group.

公开(公告)号：US09440182B2

公开(公告)日：2016-09-13

申请号：US13332843

申请日：2011-12-21

申请人： Michael Joseph O'Brien ,  Robert James Perry ,  Tunchiao Hubert Lam ,  Grigorii Lev Soloveichik ,  Sergei Kniajanski ,  Larry Neil Lewis ,  Malgorzata Iwona Rubinsztajn ,  Dan Hancu

发明人： Michael Joseph O'Brien ,  Robert James Perry ,  Tunchiao Hubert Lam ,  Grigorii Lev Soloveichik ,  Sergei Kniajanski ,  Larry Neil Lewis ,  Malgorzata Iwona Rubinsztajn ,  Dan Hancu

IPC分类号： C07F7/08 ,  C07F7/18 ,  C07C215/06 ,  B01D53/14

CPC分类号： B01D53/1475 ,  B01D53/1493 ,  B01D2252/20 ,  B01D2252/202 ,  B01D2252/2025 ,  B01D2252/2028 ,  B01D2252/20405 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20468 ,  B01D2252/205 ,  B01D2252/2056 ,  B01D2252/504 ,  B01D2258/0283 ,  F23J2215/50 ,  F23J2219/40 ,  Y02C10/04 ,  Y02C10/06

摘要： A carbon dioxide absorbent composition is described, including (i) a liquid, nonaqueous silicon-based material, functionalized with one or more groups that either reversibly react with CO2 or have a high-affinity for CO2; and (ii) a hydroxy-containing solvent that is capable of dissolving both the silicon-based material and a reaction product of the silicon-based material and CO2. The absorbent may be utilized in methods to reduce carbon dioxide in an exhaust gas, and finds particular utility in power plants.

摘要翻译： 描述了一种二氧化碳吸收剂组合物，其包括（i）液体，非水性硅基材料，其被一个或多个与CO 2可逆地反应或对CO 2具有高亲和力的基团官能化; 和（ii）能够溶解硅系材料和硅系材料与CO 2的反应产物的含羟基溶剂。 吸收剂可用于减少废气中的二氧化碳的方法，并且在发电厂中具有特殊的用途。

公开(公告)号：US20160193560A1

公开(公告)日：2016-07-07

申请号：US14905531

申请日：2014-09-11

申请人： DOW GLOBAL TECHNOLOGIES LLC

发明人： Jonathan W. Leister ,  Ross E. Dugas

IPC分类号： B01D53/14

CPC分类号： B01D53/1425 ,  B01D3/00 ,  B01D3/007 ,  B01D19/0015 ,  B01D2252/2021 ,  B01D2252/2025 ,  B01D2252/2026 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20447 ,  B01D2252/20452 ,  B01D2252/20468 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2256/245 ,  B01D2257/108 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/406 ,  B01D2257/408 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/702

摘要： Disclosed is an improved process for regenerating solvent used to remove contaminants from a fluid stream. Said process comprises a solvent regeneration system (10) comprising a rich/lean solvent stripper column (29), reboiler (50), condenser (36), and reflux receiver (38) wherein the improvement is the location 46 of the condensed stripper gas return from the reflux receiver.

摘要翻译： 公开了用于再生用于从流体流中除去污染物的溶剂的改进方法。 所述方法包括包含富/贫溶剂汽提塔（29），再沸器（50），冷凝器（36）和回流容器（38）的溶剂再生系统（10），其中改进是冷凝汽提塔气体的位置46 从回流接收器返回。

公开(公告)号：US20160023966A1

公开(公告)日：2016-01-28

申请号：US14877590

申请日：2015-10-07

申请人： Chevron Phillips Chemical Company LP

发明人： John D. HOTTOVY ,  Ai-fu CHANG

IPC分类号： C07C7/11 ,  C08F110/02 ,  B01J19/24

CPC分类号： C07C7/11 ,  B01D53/1487 ,  B01D53/1493 ,  B01D53/18 ,  B01D2252/10 ,  B01D2252/20405 ,  B01D2252/20421 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20468 ,  B01D2252/504 ,  B01D2257/7022 ,  B01J19/24 ,  B01J19/2455 ,  B01J2219/24 ,  C07C5/327 ,  C08F6/001 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04

摘要： A process for recovery of ethylene from a polymerization product stream of a polyethylene production system, comprising separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature in a range of from about 40° F. to about 110° F., wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system, and recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene.

公开(公告)号：US09216375B2

公开(公告)日：2015-12-22

申请号：US14419944

申请日：2013-08-06

申请人： LINDE AKTIENGESELLSCHAFT

发明人： Alexander Brandl ,  Anna Maria Fischer

IPC分类号： B01D53/14 ,  C10K1/00 ,  C10K1/16 ,  C10K3/04

CPC分类号： B01D53/14 ,  B01D53/1468 ,  B01D2252/2021 ,  B01D2252/2026 ,  B01D2252/20468 ,  B01D2252/20478 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2256/22 ,  B01D2257/304 ,  B01D2257/308 ,  C10K1/004 ,  C10K1/16 ,  C10K3/04

摘要： The invention relates to a method for operating a gas scrubber, in which a feed gas (1) containing hydrogen, carbon monoxide, carbon dioxide and carbonyl sulfide and/or hydrogen sulfide is scrubbed in a scrubbing apparatus (A1) using a scrubbing agent (3, 4) preladen with carbon dioxide in order largely selectively to separate the sulfur components from the feed gas and to produce a desulfurized gas stream (5, 9). The invention is distinguished in that a sulfur-free scrubbing agent (3, 4) is used which, on introduction thereof into the scrubbing apparatus (A1), has a carbon dioxide partial pressure which is greater than or equal to the carbon dioxide partial pressure in the feed gas (1) to be desulfurized.

摘要翻译： 本发明涉及一种操作气体洗涤器的方法，其中在洗涤装置（A1）中使用洗涤剂（A1）洗涤含有氢气，一氧化碳，二氧化碳和羰基硫化物和/或硫化氢的进料气体（1） 3，4）预先装有二氧化碳，以便大量选择性地将硫成分与进料气体分离并产生脱硫气流（5,9）。 本发明的区别在于，使用无硫洗涤剂（3,4），其在进入洗涤装置（A1）时具有二氧化碳分压大于或等于二氧化碳分压 在待脱硫的进料气体（1）中。

公开(公告)号：US08952206B2

公开(公告)日：2015-02-10

申请号：US14239636

申请日：2012-08-24

申请人： Christophe R. Laroche

发明人： Christophe R. Laroche

IPC分类号： C07C41/34 ,  B01D53/14

CPC分类号： C07C41/34 ,  B01D53/1425 ,  B01D53/1456 ,  B01D2252/2021 ,  B01D2252/2025 ,  B01D2252/2026 ,  B01D2252/20452 ,  B01D2252/20463 ,  B01D2252/20468 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/406 ,  B01D2257/408 ,  B01D2257/504 ,  B01D2258/02 ,  Y02C10/06

摘要： There is described a process for reducing the concentration of formate based heat stable salts formed in a physical solvent acid gas absorption process (12) wherein acid gas contaminants such as hydrogen sulfide and carbon dioxide are removed from gas mixtures (30) which include these contaminants. The process comprises the step of contacting the physical solvent containing formate based heat stable salts (46) with a metallic and/or organometallic catalyst (52), preferably the catalyst comprises palladium, zinc, platinum, nickel, or rhodium, and/or salts thereof and/or oxides thereof. The process is particularly suited for physical solvents such as refrigerated methanol, dialkyl ethers of polyethylene glycols, N-methyl-2-pyrrolidones, propylene carbonate, blends of N-acetylmorpholine and N-formylmorpholine, 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone, and the like and particularly gas mixtures containing ammonia as a contaminant.

摘要翻译： 描述了一种降低在物理溶剂酸性气体吸收过程（12）中形成的甲酸酯基热稳定盐的浓度的方法，其中从包括这些污染物的气体混合物（30）中除去诸如硫化氢和二氧化碳的酸性气体污染物 。 该方法包括使含有甲酸盐的热稳定盐（46）的物理溶剂与金属和/或有机金属催化剂（52）接触的步骤，优选地，催化剂包括钯，锌，铂，镍或铑，和/或 和/或其氧化物。 该方法特别适用于物理溶剂如冷冻甲醇，聚乙二醇二烷基醚，N-甲基-2-吡咯烷酮，碳酸亚丙酯，N-乙酰基吗啉和N-甲酰基吗啉的共混物，1,3-二甲基-3,4， 特别是包含氨作为污染物的气体混合物。

公开(公告)号：US20120095181A1

公开(公告)日：2012-04-19

申请号：US12905966

申请日：2010-10-15

申请人： John D. HOTTOVY ,  Ted CYMBALUK

发明人： John D. HOTTOVY ,  Ted CYMBALUK

IPC分类号： C08F2/38 ,  B01J19/00

CPC分类号： C08F6/001 ,  B01D53/1487 ,  B01D53/1493 ,  B01D2252/20405 ,  B01D2252/20421 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20468 ,  B01D2252/504 ,  B01D2257/7022 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08F2/00

摘要： A polyethylene production process, comprising contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream, separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein at least a portion of the ethylene from the light gas stream is absorbed by the absorption solvent system, removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream, and recovering ethylene from the absorption solvent system.

摘要翻译： 一种聚乙烯生产方法，包括在合适的反应条件下使乙烯和聚合催化剂接触以产生聚合产物流，从聚合产物流中分离轻质气体流，其中轻质气流包含乙烷和未反应的乙烯，使轻质气体流 其中吸收溶剂系统，其中来自轻质气体流的乙烯的至少一部分被吸收溶剂系统吸收，除去轻质气体流的未吸收气体与吸收溶剂系统接触以形成废气流，以及 从吸收溶剂体系中回收乙烯。

公开(公告)号：US20110223087A1

公开(公告)日：2011-09-15

申请号：US13045911

申请日：2011-03-11

申请人： Steven Raymond Lustig ,  Dennis A. Redder

发明人： Steven Raymond Lustig ,  Dennis A. Redder

IPC分类号： B01D53/62 ,  B01D53/50

CPC分类号： B01D53/1493 ,  B01D53/1475 ,  B01D53/1481 ,  B01D2252/2041 ,  B01D2252/20415 ,  B01D2252/20442 ,  B01D2252/20447 ,  B01D2252/20468 ,  B01D2252/20473 ,  B01D2257/302 ,  B01D2257/504 ,  Y02A50/2342 ,  Y02A50/2349 ,  Y02C10/04 ,  Y02C10/06

摘要： Described are amino compounds that are useful to methods of carbon dioxide removal.

摘要翻译： 描述了可用于二氧化碳去除方法的氨基化合物。