摘要:
The invention relates to a process for isomerizing normal paraffins, particularly C.sub.5 -C.sub.6, in the presence of at least one catalyst based on an omega zeolite having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 6.5 to 80, a content by weight of sodium lower than 0.2%, crystalline parameters "a" and "c" respectively smaller than or equal to 1.814 nm and 0.760 nm, a capacity of adsorption of nitrogen, measured at 77K under a partial pressure of 0.19, higher than about 8% by weight, the catalyst also comprising at least one metal from group VIII of the periodic table of elements, preferably platinum or/and palladium.
摘要翻译:本发明涉及一种在至少一种催化剂存在下使正构烷烃特别是C5-C6异构化的方法,该催化剂基于SiO 2 / Al 2 O 3的摩尔比为6.5至80的ω-沸石,钠的重量比低于 0.2%,分别小于或等于1.814nm和0.760nm的结晶参数“a”和“c”,在77K下在0.19Kg,高于约8%重量下测量的氮吸附容量, 催化剂还包含元素周期表第Ⅷ族中的至少一种金属,优选铂或/和钯。
摘要:
The invention concerns a new mordenite adsorbing molecules of a kinetic diameter higher than about 0.66 nm, prepared from a mordenite of the so-called small pores type.Said zeolite, admixed with a matrix and at least one group VIII metal can be used in n-paraffins hydroisomerization reactions.
摘要:
The invention relates to a catalyst for isomerizing a C.sub.8 aromatic fraction containing a mordenite and at least one metal from group VIII of the periodic classification of elements (such as Pt or Pd), characterized in that the mordenite is such that its skeleton Si/Al atomic ratio is between 6 and 10.5, its sodium weight content is below 2000 ppm, its unit cell volume is between 2.73 and 2.78 nm.sup.3, its benzene adsorption capacity is between 4 and 10% based on the dry mordenite weight and its 1,3,5-trimethylbenzene adsorption capacity is between 0.5 and 2.5% by weight based on the dry mordenite weight. The invention also relates to the preparation of said mordenite.
摘要:
The invention relates to a catalyst for isomerizing C.sub.8 aromatic fractions, the catalyst containing a mordenite and at least one metal from group VIII of the periodic classification of elements (such as Pt or Pd), characterized in that the mordenite is such that its skeleton Si/Al atomic ratio is between 6 and 10.5, its sodium weight content is below 2000 ppm, its unit cell volume is between 2.73 and 2.78 nm.sup.3, its benzene adsorption capacity is between 4 and 10% based on the dry mordenite weight and its 1,3,5-trimethylbenzene adsorption capacity is between 0.5 and 2.5% by weight based on the dry mordenite weight. The invention also relates to the preparation of the mordenite.
摘要:
The present invention concerns a new decationized, dealuminated and stabilized zeolite of L type, characterized particularly by:a total SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 8,a potassium content lower than 2.9% by weight,parameters a and c of the elementary mesh respectively lower than 1.836 nm and 0.754 nm,a nitrogen adsorption capacity at 77 K, for a partial pressure P/Ps of 0.19, higher than 11% by weight,a benzene adsorption capacity at 30.degree. C., for a partial pressure P/Ps of 0.25, higher than 8.5% by weight, anda lattice of mesopores whose radii, measured by nitrogen adsorption-desorption at 77 K according to the BJH method, range from 0.8 nm to 20 nm.
摘要翻译:本发明涉及一种新型的分解,脱铝和稳定的L型沸石,其特征在于特征在于:总SiO 2 / Al 2 O 3摩尔比至少为8,钾含量低于2.9重量%,基本网格的参数a和c 分别低于1.836nm和0.754nm,对于分压P / Ps为0.19,高于11重量%,在30℃下的苯吸附容量为77K时的氮吸附容量,对于分压P / Ps为0.25,高于8.5重量%,并且根据BJH方法在77K下通过氮吸附 - 解吸测定的半径为0.8nm〜20nm的中孔的晶格。
摘要:
The invention concerns a new stabilized and dealuminated zeolite of OMEGA structure, characterized by:a total SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 10,a sodium content lower than 0.5% by weight,a and c parameters of elementary mesh respectively lower than 1.814 nm and 0.759 nm,a nitrogen adsorption capacity at 77 K higher than about 5% by weight for a partial pressure P/P.sub.o of 0.19,a lattice of mesopores whose radii range preferably from 1.5 to 14 nm.This zeolite can be used in admixture with a convenient matrix in reactions of hydrocarbon conversion.
摘要翻译:本发明涉及一种OMEGA结构的新的稳定和脱铝沸石,其特征在于:SiO 2 / Al 2 O 3的总摩尔比至少为10,钠含量低于0.5重量%,基本网格的a和c参数分别低于1.814nm 和0.759nm,对于分压P / Po为0.19,77K时的氮吸附容量高于约5重量%,半径范围优选为1.5至14nm的中孔的晶格。 该沸石可以与烃转化反应中的方便的基质混合使用。
摘要:
The cracking catalyst of the invention contains:(a) 20-95% by weight of at least one matrix, selected from the group consisting of alumina, silica, magnesia, clay, titanium oxide, zirconia, combinations of at least two of these compounds and alumina-boron oxide combinations,(b) 1-60% by weight of at least one zeolite of open structure whose main dodecagonal channels have openings of at least 7 Angstroms, said zeolite of open structure being selected from the group formed of X, Y, L, omega and beta zeolites,(c) 0.5-60% by weight of at least one offretite whose main dodecagonal channels have openings smaller than 7 Angstroms and which have a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio from about 15 to about 500, the crystalline paramaters a and c of elementary mesh ranging respectively from 1.285 to 1.315 nm for a and from 0.748 to 0.757 nm for c and have a potassium content lower than 1.5% by weight.
摘要:
A new catalyst with a highly dealuminated mordenite base, useful in particular in hydrotreatment processes for improving the low temperature properties and the pour point and cloud point of oil cuts contains:(1) an acidic carrier comprising(a) at least 50% (calculated as dry base) of highly dealuminated mordenite and characterized by a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 higher than 110 and a sodium content lower than or equal to 0.5% by weight, and(b) an amorphous matrix, and(2) said acid carrier containing in association at least one oxide of a metal from group VIII and at least one oxide of a metal from group VI of the periodic classification of elements.
摘要翻译:具有高脱铝丝光沸石基质的新型催化剂,尤其用于改进油料的低温性能和倾点和浊点的加氢处理方法中包含:(1)酸性载体,其包含(a)至少50%(计算值 作为干碱),其特征在于SiO 2 / Al 2 O 3的摩尔比高于110,钠含量低于或等于0.5重量%,和(b)无定形基质,和(2)所述酸性载体含有 关于来自第VIII族的金属的至少一种氧化物和至少一种元素的周期性分类的来自第VI族的金属的氧化物。
摘要:
The cracking catalyst of the invention contains:(a) 20-95% by weight of at least one matrix, selected from the group consisting of alumina, silica, magnesia, clay, titanium oxide, zirconia, combinations of at least two of these compounds and alumina-boron oxide combinations,(b) 1-60% by weight of at least one zeolite of open structure whose main dodecagonal channels have openings of at least 7 Angstroms, said zeolite of open structure being selected from the group formed of X, Y, L, omega and beta zeolites,(c) 0.5-60% by weight of at least one offretite whose main dodecagonal channels have openings smaller than 7 Angstroms and which have a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio from about 15 to about 500, the crystalline parameters a and c of elementary mesh ranging respectively from 1.285 to 1.315 nm for a and from 0.748 to 0.757 nm for c and have a potassium content lower than 1.5% by weight.
摘要翻译:本发明的裂化催化剂包含:(a)20-95重量%的至少一种选自氧化铝,二氧化硅,氧化镁,粘土,氧化钛,氧化锆,这些化合物中的至少两种的组合的基质 和氧化铝 - 氧化硼组合,(b)1-60重量%的至少一种开口结构的沸石,其主要十二边形通道具有至少7埃的开口,所述开放结构的沸石选自由X, Y,L,ω和β沸石,(c)0.5-60%重量的至少一种其主要十二边形通道的开口小于7埃,并且具有约15至约500的SiO 2 / Al 2 O 3摩尔比, 基本网格的结晶参数a和c分别为1.85〜1.315nm,c为0.748〜0.757nm,钾含量低于1.5重量%。
摘要:
The invention concerns a stabilized and dealuminated omega zeolite, its manufacture and use in catalytic cracking.It has in particular a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio higher than 10, a sodium content lower than 0.3%, "a" and "c" crystalline parameters respectively lower than or equal to 1.814 nm and 0.760 nm, a particular capacity for nitrogen adsorption and a particular lattice of secondary pores.
摘要翻译:本发明涉及一种稳定和脱铝的ω-沸石,其制造和用于催化裂化。 特别是具有高于10,低于0.3%的钠含量,分别低于或等于1.814nm和0.760nm的“a”和“c”结晶参数的SiO 2 / Al 2 O 3摩尔比,具有特定氮吸附能力和 二次孔的特定晶格。