公开(公告)号：US5149861A

公开(公告)日：1992-09-22

申请号：US664463

申请日：1991-03-01

申请人： Franz Merger ,  Peter Hettinger ,  Leopold Hupfer ,  Juergen Paetsch ,  Heribert Deck ,  Heinz Auer ,  Erwin Brunner

发明人： Franz Merger ,  Peter Hettinger ,  Leopold Hupfer ,  Juergen Paetsch ,  Heribert Deck ,  Heinz Auer ,  Erwin Brunner

IPC分类号： C07C69/06 ,  C07C27/00 ,  C07C27/02 ,  C07C29/38 ,  C07C29/74 ,  C07C29/88 ,  C07C31/22 ,  C07C67/00 ,  C07C67/03 ,  C07C67/08 ,  C07C209/00 ,  C07C209/86 ,  C07C211/03 ,  C07C211/05

CPC分类号： C07C29/88 ,  C07C67/03

摘要： Trialkylamines and methyl formate are recovered from reaction mixtures obtained in the preparation of trimethylolalkanes by reaction of n-alkanals with from 2.2 to 4.5 moles of formaldehyde in aqueous solution in the presence of from 0.6 to 3 mole of trialkylamine, each quantity based on 1 mole of alkanal, and subsequent hydrogenation in a process wherein the crude reaction mixturea) is heated to from 100.degree. to 200.degree. C., the water present in the reaction mixture is substantially separated off by distillation, together with any excess free trialkylamine, the trialkylamine present in the form of a trialkylammonium formate is freed to form a trimethylolalkane formate, the trialkylamine is distilled off and the trimethylolalkane formate is transesterified with methanol to trimethylolalkane and methyl formate in the presence or absence of a catalytic amount of an alkali metal alkoxide or alkaline earth metal alkoxide, orb) is substantially dewatered, any excess free trialkylamine being removed at the same time, the trialkylamine present in the form of a trialkylammonium formate is separated off by admixing the remaining mixture with methanol and heating the admixture to from 100.degree. to 200.degree. C. to form methyl formate and trialkylamine.

摘要翻译： 三烷基胺和甲酸甲酯从制备三羟甲基烷烃得到的反应混合物中回收，通过在0.6至3摩尔三烷基胺存在的情况下，正链烷与2.2至4.5摩尔甲醛在水溶液中的反应，每个量基于1摩尔 然后在将粗反应混合物a）加热至100至200℃的过程中随后进行氢化，反应混合物中存在的水通过蒸馏与任何过量的游离三烷基胺基本上分离出来， 以三烷基铵甲酸盐形式存在的三烷基胺可以形成甲酸三羟甲基烷烃，在存在或不存在催化量的碱金属醇盐的条件下，将三烷基胺蒸馏除去，甲醇三甲氧基链烷烃甲酯与甲醇酯交换为三羟甲基烷烃和甲酸甲酯，或 碱土金属醇盐或b）基本脱水，任何过量游离的三烷基胺为 同时除去以三烷基甲酸铵形式存在的三烷基胺，通过将剩余的混合物与甲醇混合并将混合物加热至100至200℃以分离，形成甲酸甲酯和三烷基胺。

公开(公告)号：US5981688A

公开(公告)日：1999-11-09

申请号：US159086

申请日：1998-09-23

申请人： Heinz Auer ,  Klaus Beiser ,  Jurgen Ciprian ,  Lothar Franz ,  Wolfgang Franzischka ,  Ulrich-Dieter Pessel ,  Werner Weinle

发明人： Heinz Auer ,  Klaus Beiser ,  Jurgen Ciprian ,  Lothar Franz ,  Wolfgang Franzischka ,  Ulrich-Dieter Pessel ,  Werner Weinle

IPC分类号： B01J19/18 ,  C08G65/20 ,  C08G65/30 ,  C08G65/331 ,  C08G63/00

CPC分类号： B01J19/1862 ,  B01J19/1881 ,  C08G65/20 ,  C08G65/30 ,  C08G65/3312 ,  B01J2219/0025

摘要： A process for preparing hydroxyl-containing polymers and, in particular, a process for preparing polytetrahydrofuran with terminal hydroxyl groups from the corresponding acyloxy-containing polymers by transesterification with alcohols is carried out continuously in at least one stirred vessel, with the foam produced in the transesterification being fed tangentially to a cylindrical container, preferably a cyclone separator, at an adequate velocity to destroy the foam. The liquid phase which separates out is recycled through a line to the at least one stirred vessel.This continuous process is preferably carried out in a cascade of stirred vessels, in which each stirred vessel or a subunit of at least two stirred vessels can in each case be coupled to a cylindrical container, preferably in the form of a cyclone separator.

摘要翻译： 特别是制备含羟基聚合物的方法，特别是通过与醇的酯交换反应，由相应的含酰氧基的聚合物制备具有末端羟基的聚四氢呋喃的方法在至少一个搅拌容器中连续进行，其中在 酯交换反应以适当的速度切向地进料到圆柱形容器，优选旋风分离器以破坏泡沫。 分离出的液相通过管线再循环至至少一个搅拌容器。 这种连续方法优选在级联的搅拌容器中进行，其中每个搅拌容器或至少两个搅拌容器的亚单位可以在每种情况下联接到圆柱形容器，优选以旋风分离器的形式。

公开(公告)号：US07105616B2

公开(公告)日：2006-09-12

申请号：US10473595

申请日：2002-04-10

申请人： Heinz Auer

发明人： Heinz Auer

IPC分类号： C08F4/06

CPC分类号： C08F6/003 ,  C08L23/20

摘要： A process for working up a liquid reaction discharge of the cationic polymerization of isobutene, which substantially comprises polyisobutene, unconverted isobutene and, if required, an inert diluent, is described. Problems with foam formation when the unconverted isobutene is being distilled off are avoided if the heated reaction discharge is let down into a flash container and/or not more than 900 m3/h of vapor are expelled per square meter of liquid surface and/or the resulting foam is destroyed, for example in a wet cyclone.

摘要翻译： 描述了基本上包含聚异丁烯，未转化的异丁烯和如果需要的惰性稀释剂的异丁烯的阳离子聚合的液体反应排放的方法。 当蒸发掉未转化的异丁烯时，如果将加热的反应物排出物放入闪蒸容器中，并且/或不超过900m 3 / h的蒸气排出每平方 液体表面和/或所得泡沫破坏，例如在湿式旋风分离器中。

公开(公告)号：US07049383B2

公开(公告)日：2006-05-23

申请号：US10482807

申请日：2002-07-02

申请人： Heinz Auer ,  Dirk Borchers ,  Thomas Wettling

发明人： Heinz Auer ,  Dirk Borchers ,  Thomas Wettling

IPC分类号： C08F110/10

CPC分类号： C08F10/10 ,  C08F110/10 ,  C08F2/01 ,  C08F2/001 ,  C08F4/14 ,  C08F2500/02 ,  C08F2500/05

摘要： A polyisobutene composition having a global maximum of the differential molecular weight distribution curve at a molecular weight Mmax of from 3 500 to 8 000 is described, which comprises at least one local maximum at a molecular weight of from 112 to 560. The isobutene oligomers present act as flow improvers and boiling assistants. They are added to higher molecular weight isobutene polymers, preferably before or in the course of a distillation, for removing unconverted isobutene and/or an inert diluent.

摘要翻译： 描述了在分子量M max> 3 000至8 000时具有总分子量分布曲线的全局最大值的聚异丁烯组合物，其包含至少一个局部最大值，分子量为 存在的异丁烯低聚物作为流动改进剂和沸腾助剂。 将它们加入到较高分子量的异丁烯聚合物中，优选在蒸馏之前或在蒸馏过程中，用于除去未转化的异丁烯和/或惰性稀释剂。

公开(公告)号：US06921833B1

公开(公告)日：2005-07-26

申请号：US10031166

申请日：2000-07-26

申请人： Heinz Auer ,  Jürgen Dahlhaus ,  Karl Fischer ,  Hans Hammer ,  Jochen Kellenbenz ,  Michael Schulz ,  Joachim Thiel ,  Maximilian Vicari

发明人： Heinz Auer ,  Jürgen Dahlhaus ,  Karl Fischer ,  Hans Hammer ,  Jochen Kellenbenz ,  Michael Schulz ,  Joachim Thiel ,  Maximilian Vicari

IPC分类号： B01D3/00 ,  B01J3/00 ,  B01J3/02 ,  B01J19/00 ,  C07B61/00 ,  C07C29/80 ,  C07C31/04 ,  C07C67/36 ,  C07C69/06

CPC分类号： C07C67/36 ,  C07C69/06

摘要： A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity.Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.

摘要翻译： 给出了在过压甲醇钠或碱土金属甲醇盐作为催化剂存在下，在超压大气压和高温下使过量甲醇与一氧化碳反应制备甲酸甲酯的方法，其中使用 的至少两个反应器元件，优选逆流操作，约100℃，约100巴的压力与无固体脱盐反应产物的组合使得非常经济，大大无故障地生产甲酸甲酯 以任何期望的质量和非常好的生产能力。 此外，描述了无固体脱盐的方法和用于实施该方法的装置。

公开(公告)号：US4984342A

公开(公告)日：1991-01-15

申请号：US296800

申请日：1989-01-13

申请人： Heinz Auer ,  Gernot Winkler

发明人： Heinz Auer ,  Gernot Winkler

IPC分类号： H01G9/032 ,  C01G45/02 ,  H01G9/02 ,  H01G9/025

CPC分类号： H01G9/025 ,  C01G45/02 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/10 ,  C01P2006/40 ,  C01P2006/80 ,  Y10T29/417 ,  Y10T29/435

摘要： A method for manufacturing solid electrolyte capacitors is provided. Pursuant to the method, pores in formed sintered members composed of a valve metal are first nearly filled with manganese dioxide that is produced by pyrolysis of solutions that contain manganese nitrate. Following thereupon, the sintered members are immersed into a dry melt of manganese nitrate that may comprise an additive of manganese dioxide and/or silicon dioxide powder. Subsequently, the members are introduced into a furnace, and heated to approximately 100.degree. C. in dry air. Subsequently, fine drops of water are applied onto the surface of the heated sintered members and the pyrolysis is ended at temperatures of approximately 200.degree. to about 350.degree. C. in a mist of water vapor that flows by.

摘要翻译： 提供了制造固体电解质电容器的方法。 根据该方法，由阀金属构成的成形烧结体中的孔首先接近充满由含有硝酸锰的溶液热分解产生的二氧化锰。 随后，将烧结构件浸入可能包含二氧化锰和/或二氧化硅粉末的添加剂的硝酸锰的干燥熔体中。 随后，将构件引入炉中，并在干燥空气中加热至约100℃。 随后，将微滴水施加到加热的烧结构件的表面上，并且在大约200℃至大约350℃的温度下，在流过的水蒸汽雾中结束热解。

公开(公告)号：US06987165B2

公开(公告)日：2006-01-17

申请号：US10451743

申请日：2002-01-07

申请人： Heinz Auer ,  Ulrich Kanne ,  Andre De Vos

发明人： Heinz Auer ,  Ulrich Kanne ,  Andre De Vos

IPC分类号： C08F6/06

CPC分类号： C08F10/10 ,  C08F110/10 ,  C08F2/22 ,  C08F4/14 ,  C08F2500/08 ,  C08F2500/03

摘要： A process for the preparation of highly reactive polyisobutenes is described, in which isobutene is polymerized in the presence of a complex of boron trifluoride and at least one cocatalyst in a liquid organic phase at a reaction temperature of from −60 to −4° C. and water is added in two stages to the organic phase for catalyst deactivation and catalyst extraction.

摘要翻译： 描述了制备高反应性聚异丁烯的方法，其中异丁烯在-60至-4℃的反应温度下在液态有机相中在三氟化硼与至少一种助催化剂的配合物存在下聚合。 并将水分两步加入到有机相中用于催化剂失活和催化剂萃取。

公开(公告)号：US06841700B2

公开(公告)日：2005-01-11

申请号：US10181462

申请日：2001-01-12

申请人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Till Adrian

发明人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Till Adrian

IPC分类号： C07C51/09 ,  C07C51/44 ,  C07C51/48 ,  C07C53/02

CPC分类号： C07C51/44 ,  C07C51/09 ,  C07C51/48 ,  C07C53/02

摘要： The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that—before the hydrolysis of the methyl formate—the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.

摘要翻译： 本发明涉及获得无水或基本上无水的甲酸的方法，其中首先通过甲酸甲酯的水解产生水性甲酸，甲酸甲酯中的甲醇含量预先减少。 根据本发明的方法具有以下特征：在甲酸甲酯的水解之前，甲醇的甲酸甲酯的甲醇含量在蒸馏塔中还原，该蒸馏塔同时用于工作期间的其它分离功能， 的甲酸。

公开(公告)号：US06838579B2

公开(公告)日：2005-01-04

申请号：US10181460

申请日：2001-01-24

申请人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Gerhard Wagner ,  Till Adrian

发明人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Gerhard Wagner ,  Till Adrian

IPC分类号： C07C51/56 ,  C07C51/09 ,  C07C51/44 ,  C07C51/48 ,  C07C53/02

CPC分类号： C07C51/44 ,  C07C51/09 ,  C07C51/48 ,  C07C53/02

摘要： The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group, is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.

摘要翻译： 本发明涉及获得无水或基本上无水的甲酸的方法，其中在后处理过程中，将基团R 1和R 2分别为烷基，环烷基，芳基或芳烷基或R 1和R 2共同形成的通式Ⅰ化合物 与N原子一起形成杂环的5或6元环，并且只有一个基团是芳基，并且其中R 3是氢或C 1 -C 4 - 烷基，同时被用作甲酸的萃取剂 酸和消泡剂用于蒸馏过程。

公开(公告)号：US06696603B2

公开(公告)日：2004-02-24

申请号：US10181458

申请日：2002-07-18

申请人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Gerhard Wagner ,  Till Adrian

发明人： Heinz Auer ,  Bernd Bessling ,  Hans Hammer ,  Hans Hasse ,  Friedrich Sauer ,  Maximilian Vicari ,  Gerhard Wagner ,  Till Adrian

IPC分类号： C07C5302

CPC分类号： C07C51/445 ,  B01J14/00 ,  B01J2219/00006 ,  C07C51/09 ,  C07C51/44 ,  C07C51/48 ,  C07C53/02

摘要： The invention relates to a process for the preparation of anhydrous or substantially anhydrous formic acid. The process has the special feature that a liquid of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group, employed as extractant is also employed as washing liquid for the offgases produced in the process.

摘要翻译： 本发明涉及一种制备无水或基本上无水的甲酸的方法。 该方法的特征在于，其中基团R 1和R 2的通式I的液体是烷基，环烷基，芳基或芳烷基，或R 1和R 2共同连同 N原子，形成杂环的5或6元环，并且仅一个基团是芳基，并且其中R 3是氢或作为萃取剂的C 1 -C 4 - 烷基也用作洗涤剂 在该过程中产生的废气的液体。