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1.发明授权公开(公告)号：US07038008B2
公开(公告)日：2006-05-02
申请号：US10473583
申请日：2002-04-10
申请人： Thomas Wettling , Dirk Borchers , Heinz Auer
发明人： Thomas Wettling , Dirk Borchers , Heinz Auer
摘要： A process for working up a liquid reaction discharge of the cationic polymerization of isobutene, which substantially comprises polyisobutene, unconverted isobutene and an inert diluent, in which the reaction discharge is heated and is let down into a flash container, is described, the reaction discharge separating, as a result of the flashing, into a polyisobutene-containing liquid phase and a gas phase containing the main amount of the isobutene contained in the reaction discharge and of the diluent.
摘要翻译： 描述了用于处理异丁烯的阳离子聚合的液体反应放电的方法，其基本上包括反应放电被加热并放入闪蒸容器中的聚异丁烯，未转化的异丁烯和惰性稀释剂，反应放电 作为闪光的结果将其分离成含聚异丁烯的液相和包含反应放电中所含的主要量的异丁烯和稀释剂的气相。
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公开(公告)号：US07049383B2
公开(公告)日：2006-05-23
申请号：US10482807
申请日：2002-07-02
申请人： Heinz Auer , Dirk Borchers , Thomas Wettling
发明人： Heinz Auer , Dirk Borchers , Thomas Wettling
IPC分类号： C08F110/10
CPC分类号： C08F10/10 , C08F110/10 , C08F2/01 , C08F2/001 , C08F4/14 , C08F2500/02 , C08F2500/05
摘要： A polyisobutene composition having a global maximum of the differential molecular weight distribution curve at a molecular weight Mmax of from 3 500 to 8 000 is described, which comprises at least one local maximum at a molecular weight of from 112 to 560. The isobutene oligomers present act as flow improvers and boiling assistants. They are added to higher molecular weight isobutene polymers, preferably before or in the course of a distillation, for removing unconverted isobutene and/or an inert diluent.
摘要翻译： 描述了在分子量M max> 3 000至8 000时具有总分子量分布曲线的全局最大值的聚异丁烯组合物，其包含至少一个局部最大值，分子量为 存在的异丁烯低聚物作为流动改进剂和沸腾助剂。 将它们加入到较高分子量的异丁烯聚合物中，优选在蒸馏之前或在蒸馏过程中，用于除去未转化的异丁烯和/或惰性稀释剂。
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3.发明授权Reduction of the content of compounds containing oxygen and/or nitrogen in material flows containing isobutene 有权在含有异丁烯的物料流中减少含有氧和/或氮的化合物的含量公开(公告)号：US07399404B2
公开(公告)日：2008-07-15
申请号：US10556091
申请日：2004-05-14
申请人： Thomas Wettling , Dirk Borchers
发明人： Thomas Wettling , Dirk Borchers
IPC分类号： C07C7/12
摘要： A process for reducing the content of oxygen-containing and/or nitrogen-containing compounds in streams having an isobutene content of at least 10% by weight, which comprises passing the stream in the liquid state at a temperature T [in K] and a linear velocity v [in cm/min] over a fixed bed of an acid-free zeolite having a mean pore size of from 0.3 to 1.5 nm, where the fixed bed has a length l [in cm] in the flow direction of the stream and T, v and l obey the relationship 2(T−283 K)/10 K·l/v≦500 min, is described. The process avoids the formation of isobutene oligomers.
摘要翻译： 一种用于在异丁烯含量为至少10重量％的流中降低含氧和/或含氮化合物的含量的方法，其包括使物流以[K]的温度T和 在平均孔径为0.3至1.5nm的无酸沸石的固定床上，在流动方向上的固定床的长度l [cm]，以线速度v [cm / min] 并且T，v和l遵守关系<？in-line-formula description =“In-line Formulas”end =“lead”？> 2（T-283 K）/ 10 K / v <= 500 min，<？in-line-formula description =“In-line Formulas”end =“tail”？>。 该方法避免了异丁烯低聚物的形成。
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公开(公告)号：US06710140B2
公开(公告)日：2004-03-23
申请号：US10344414
申请日：2003-02-19
申请人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
发明人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
IPC分类号： C08F240
CPC分类号： C08F6/02 , C08F10/10 , C08F110/10 , C08L23/20 , C08F4/14 , C08F2/42 , C08F2/40 , C08F2500/03 , C08F2500/02
摘要： A process for the preparation of polyisobutylenes by cationic polymerization of isobutylene or isobutylene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride acting as catalyst, the catalytic activity of boron trifluoride being partially or completely stopped by means of a solid deactivator following a given timelapse, which deactivator is an inorganic, anhydrous or hydrous oxygen compound of aluminum which is insoluble in the reaction mixture.
摘要翻译： 通过在三氟化硼作为催化剂存在下，在液相中通过阳离子聚合制备聚异丁烯的方法，三氟化硼的催化活性通过固体失活剂部分或完全停止 给定的时间延迟，该失活剂是不溶于反应混合物的无机，无水或含水铝化合物。
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5.发明授权Method for deactivating and recovering boron trifluoride when producing polyisobutenes 有权生产聚异丁烯时三氟化硼失活和回收方法公开(公告)号：US06939943B2
公开(公告)日：2005-09-06
申请号：US10432045
申请日：2001-11-16
申请人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
发明人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
IPC分类号： B01J27/12 , B01J27/32 , B01J38/00 , B01J38/52 , C08F4/14 , C08F6/00 , C08F6/02 , C08F10/00 , C08F6/08
摘要： The invention relates to a method for deactivating and recovering boron trifluoride when producing polyisobutenes by means of cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the liquid phase in the presence of boron trifluoride or in the form of a boron trifluoride catalyst complex. The catalyst complex is separated, essentially in the liquid phase, from the reactor discharge. The method comprises the following steps: a) removing from the polymerization reactor at −60 to 020 C., methanol, ethanol or a mixture of methanol and ethanol in such a quantity that an alcohol phase rich in boron trifluoride is formed; b) separating the alcohol phase according to (a) and, (c) optionally recycling the boron trifluoride of the alcohol phase obtained from (b) to the method in a suitable manner.
摘要翻译： 本发明涉及一种在三氟化硼存在下或以三氟化硼催化剂络合物的形式通过在液相中异丁烯或含有异丁烯的烃物流的阳离子聚合制备聚异丁烯时使三氟化硼失活和回收的方法。 催化剂复合物基本上在液相中从反应器排出分离。 该方法包括以下步骤：a）在-60至020℃下从聚合反应器中除去形成富含三氟化硼的醇相的甲醇，乙醇或甲醇和乙醇的混合物; b）根据（a）分离醇相，和（c）任选地将以（b）获得的醇相的三氟化硼以适当的方式再循环。
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公开(公告)号：US06846903B2
公开(公告)日：2005-01-25
申请号：US10312591
申请日：2001-07-13
申请人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
发明人： Thomas Wettling , Dirk Borchers , Wim Verrelst , Hans Peter Rath
摘要： Polyisobutenes are prepared by cationic polymerization of isobutene or isobutene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride as a catalyst, the catalytic activity of the boron trifluoride being partially or completely eliminated at a desired time by means of a solid deactivator, by a process in which the solid deactivator has boron trifluoride-binding primary, secondary, tertiary and/or quaternary nitrogen atoms and is insoluble in the reaction mixture.
摘要翻译： 聚异丁烯通过在三氟化硼作为催化剂的存在下在液相中的异丁烯或异丁烯烃流的阳离子聚合制备，三氟化硼的催化活性通过固体失活剂在期望的时间部分或完全消除 通过其中固体失活剂具有三氟化硼结合的伯，仲，叔和/或季氮原子并且不溶于反应混合物的方法。
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7.发明申请Reduction of the content of compounds containing oxygen and/or nitrogen in material flows containing isobutene 有权在含有异丁烯的物料流中减少含有氧和/或氮的化合物的含量公开(公告)号：US20070106107A1
公开(公告)日：2007-05-10
申请号：US10556091
申请日：2004-05-14
申请人： Thomas Wettling , Dirk Borchers
发明人： Thomas Wettling , Dirk Borchers
IPC分类号： C07C7/12
摘要： A process for reducing the content of oxygen-containing and/or nitrogen-containing compounds in streams having an isobutene content of at least 10% by weight, which comprises passing the stream in the liquid state at a temperature T [in K] and a linear velocity v [in cm/min] over a fixed bed of an acid-free zeolite having a mean pore size of from 0.3 to 1.5 nm, where the fixed bed has a length l [in cm] in the flow direction of the stream and T, v and l obey the relationship 2(T−283 K)/10 K·l/v≦500 min, is described. The process avoids the formation of isobutene oligomers.
摘要翻译： 一种用于在异丁烯含量为至少10重量％的流中降低含氧和/或含氮化合物的含量的方法，其包括使物流以[K]的温度T和 在平均孔径为0.3至1.5nm的无酸沸石的固定床上，在流动方向上的固定床的长度l [cm]，以线速度v [cm / min] 并且T，v和l遵守关系<？in-line-formula description =“In-line Formulas”end =“lead”？> 2（T-283 K）/ 10 K / v <= 500 min，<？in-line-formula description =“In-line Formulas”end =“tail”？>。 该方法避免了异丁烯低聚物的形成。
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公开(公告)号：US07745554B2
公开(公告)日：2010-06-29
申请号：US12089930
申请日：2006-10-13
申请人： Hans Peter Rath , Helmut Mach , Thomas Wettling
发明人： Hans Peter Rath , Helmut Mach , Thomas Wettling
CPC分类号： C08F110/10 , C08F4/14
摘要： The invention relates to a process for preparing polyisobutene having a mean molecular weight Mn of from 400 to 50 000, in particular from 500 to 10 000, by polymerizing isobutene in the presence of a BF3-containing complex catalyst, wherein the polymerization is carried out at least temporarily in the presence of one or more cyclic ethers.
摘要翻译： 本发明涉及通过在含BF 3的络合物催化剂存在下聚合异丁烯来制备平均分子量Mn为400至50,000，特别是500至10000的聚异丁烯的方法，其中进行聚合 至少暂时存在一种或多种环醚。
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公开(公告)号：US20070094922A1
公开(公告)日：2007-05-03
申请号：US10550910
申请日：2004-03-31
申请人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
发明人： Marco Bergemann , Harald Schwahn , Dietmar Posselt , Erich Fehr , Thomas Wettling , Klaus Diehl , Helmut Schmidtke
IPC分类号： C10L1/22 , C07C211/13
CPC分类号： C10L1/238 , C08F8/32 , C08L39/00 , C09D11/03 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1691 , C10L1/2383 , C10L1/2387 , C10L10/14 , C10M133/06 , C10M133/08 , C10M133/40 , C10M133/48 , C10M133/50 , C10M133/54 , C10M141/04 , C10M2203/022 , C10M2203/106 , C10M2215/04 , C10M2215/042 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10N2220/023 , C08F10/10
摘要： The present invention relates to polyalkene amine formulations comprising at least one polyalkene amine in a solvent, having improved performance properties, especially improved low temperature properties; a process for preparing such formulations and the use of these formulations in fuel and lubricant compositions, in particular fuels, for improving the intake system-cleaning action of such fuels.
摘要翻译： 本发明涉及在溶剂中包含至少一种聚烯烃胺的聚烯烃胺配方，具有改进的性能特性，特别是改进的低温性能; 制备这种制剂的方法以及这些制剂在燃料和润滑剂组合物，特别是燃料中的用途，以改善这种燃料的进气系统清洁作用。
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公开(公告)号：US5792884A
公开(公告)日：1998-08-11
申请号：US170985
申请日：1993-12-21
申请人： Thomas Wettling
发明人： Thomas Wettling
CPC分类号： C07F9/509
摘要： Tertiary phosphines (I) are prepared by reducing the corresponding phosphine oxides (IIa) or phosphine dihalides (IIb) using silicon or a silicon alloy as reducing agent.
摘要翻译： 通过使用硅或硅合金作为还原剂还原相应的氧化膦（IIa）或二卤化膦（IIb）来制备叔膦（I）。
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