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    Substituted cyclopropanecarboxylic acid esters and pesticidal compositions containing the same as active ingredient
    1.
    发明授权
    Substituted cyclopropanecarboxylic acid esters and pesticidal compositions containing the same as active ingredient 失效
    取代的环丙烷羧酸酯和含有与活性成分相同的杀虫组合物

    公开(公告)号：US4389412A

    公开(公告)日：1983-06-21

    申请号：US134589

    申请日：1980-03-27

    申请人： Fumio Mori ,  Manzo Shiono ,  Yoshiaki Omura

    发明人： Fumio Mori ,  Manzo Shiono ,  Yoshiaki Omura

    IPC分类号： A01N53/00 ,  A01N53/08

    CPC分类号： A01N53/00

    摘要： A new pyrethroid compound which is low in toxicity to fish and a pesticidal composition containing the same as an active ingredient are provided. The above pyrethroid compound is a substituted cyclopropanecarboxylic acid ester of the general formula: ##STR1## (wherein A is a hydrogen atom or an ethynyl group) Despite its broad pesticidal spectrum and high pesticidal activity, this ester is very low in toxicity to man and domestic animals and especially low in toxicity to fish as compared with the conventional pyrethroid compounds.

    摘要翻译： 提供了一种对鱼类毒性低的新型拟除虫菊酯化合物，含有与活性成分相同的农药组合物。 上述拟除虫菊酯化合物是以下通式的取代环丙烷羧酸酯：其中A为氢原子或乙炔基。尽管其广泛的杀虫谱和高杀虫活性，但该酯对人类的毒性非常低， 与常规的拟除虫菊酯化合物相比，对鱼类的毒性特别低。

    Process for the production of substituted ketones
    6.
    发明授权
    Process for the production of substituted ketones 失效
    制备取代酮的方法

    公开(公告)号：US3984475A

    公开(公告)日：1976-10-05

    申请号：US581854

    申请日：1975-05-29

    申请人： Yoshin Tamai ,  Takashi Nishida ,  Fumio Mori ,  Yoshiaki Omura ,  Masahisa Tanomura ,  Takeo Hosogai ,  Yoichi Ninagawa ,  Kazuo Itoi

    发明人： Yoshin Tamai ,  Takashi Nishida ,  Fumio Mori ,  Yoshiaki Omura ,  Masahisa Tanomura ,  Takeo Hosogai ,  Yoichi Ninagawa ,  Kazuo Itoi

    IPC分类号： C07C49/20 ,  C07C45/00

    CPC分类号： C07C45/68

    摘要： Process for producing substituted ketones from the reaction between organic halides and ketones having replaceable active hydrogen atoms on the carbon atom(s) alpha to the carbonyl group, in the presence of an alkali metal hydroxide unitilizing phosphonium salts as the catalyst, which salts have the following formula: ##EQU1## wherein said R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are branched or straight chain alkyl of 1-30 carbon atoms, cycloalkyl of 6-10 carbon atoms, aryl of 6-10 carbon atoms aralkyl or alkaryl wherein the aryl and alkyl are as above defined and X.sup.- is an inorganic or organic anion.

    摘要翻译： 在碱金属氢氧化物的存在下，在鏻盐作为催化剂的存在下，在有机卤化物和在羰基的α原子上具有可取代的活性氢原子的酮之间的反应生成取代的酮的方法，该盐具有 其中所述R 1，R 2，R 3和R 4相同或不同，为具有1-30个碳原子的支链或直链烷基，其中R 1，R 2，R 3和R 4相同或不同， 6-10个碳原子，6-10个碳原子的芳基芳烷基或烷芳基，其中芳基和烷基如上定义，X​​ - 是无机或有机阴离子。

    Novel pesticides and pesticidal compositions cyclopropanecarboxylates and pesticidal method
    7.
    发明授权
    Novel pesticides and pesticidal compositions cyclopropanecarboxylates and pesticidal method 失效
    新型农药和杀虫剂组合物环丙烷羧酸酯和杀虫剂方法

    公开(公告)号：US4299839A

    公开(公告)日：1981-11-10

    申请号：US79180

    申请日：1979-09-26

    申请人： Yoshiaki Omura ,  Fumio Mori ,  Yoshiji Fujita ,  Takashi Nishida ,  Takeo Hosogai ,  Sukeji Aihara ,  Yoshin Tamai ,  Fumio Wada ,  Kazuo Itoi

    发明人： Yoshiaki Omura ,  Fumio Mori ,  Yoshiji Fujita ,  Takashi Nishida ,  Takeo Hosogai ,  Sukeji Aihara ,  Yoshin Tamai ,  Fumio Wada ,  Kazuo Itoi

    IPC分类号： A01N53/00 ,  C07C153/057 ,  C07D307/52

    CPC分类号： A01N53/00

    摘要： Novel pesticidal compositions are comprised of a 2,2-dimethyl-3-(substituted ethyl)cyclopropanecarboxylic acid ester as the active ingredient, said cyclopropanecarboxylate having the structural formula: ##STR1## wherein X, Y and Z are the same or different and at least two of same are chlorine or bromine, with the remaining one being hyrogen, methyl, chlorine or bromine; R is an alcohol residue represented by one of the following structural formulae (II), (III), (IV) and (V): ##STR2## where A represents hydrogen, cyano, ethynyl or thiocarbamoyl; Q is hydrogen, chlorine, bromine, fluorine, methyl or trifluoromethyl; R.sup.1 is propargyl or benzyl; R.sup.2 represents 2-halogeno-3-phenyl-1-propen-1-yl, (dihalogenovinyloxy)phenyl, benzylphenyl, phthalimido, thiophthalimido, di- or tetrahydrophthalimido or dialkylmaleido; R.sup.3 represents allyl, 2,4-pentadienyl, propargyl or benzyl.

    摘要翻译： 新型杀虫剂组合物由2,2-二甲基-3-（取代的乙基）环丙烷甲酸酯作为活性成分组成，所述环丙烷羧酸酯具有以下结构式：其中X，Y和Z相同或不同， 其中至少两个是氯或溴，剩下的一个是氢，甲基，氯或溴; R是由以下结构式（II），（III），（IV）和（V）之一表示的醇残基：其中A表示氢，氰基，乙炔基或硫代氨基甲酰基; Q是氢，氯，溴，氟，甲基或三氟甲基; R1是炔丙基或苄基; R 2表示2-卤代-3-苯基-1-丙烯-1-基，（二卤代乙烯基氧基）苯基，苄基苯基，邻苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基，二或四氢邻苯二甲酰亚氨基或二烷基马来酰亚胺; R3表示烯丙基，2,4-戊二烯基，炔丙基或苄基。