摘要:
The present invention provides a polyester resin having in the molecule at least one quaternary ammonium base represented by the formula (wherein X is halogen and R is alkyl), and a process for its production. The present invention further provides a pigment dispersion containing a pigment and the above polyester resin as resin for dispersion of the pigment, and also provides a coating composition containing the above pigment dispersion.
摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20° C. of 15 or more and the minimum value of dynamic modulus E′ at a frequency of 110 Hz in the temperature range of 150-200° C., of 1×109 dyn/cm or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherabiIity, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20° C. of 15 or more and the minimum value of dynamic modulus E′ at a frequency of 110 Hz in the temperature range of 150-200° C., of 1×109 dyn/cm2 or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherability, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要翻译:本发明提供一种热固性有机溶剂型涂料,其能够在20℃下形成具有15℃以上的TUKON硬度的固化涂膜,在110Hz的温度范围内形成频率为110Hz的动态模量E'的最小值 150-200℃,1×10 9 dyn / cm 2以上。 与由用作汽车面漆的常规有机溶剂型涂料形成的固化膜(例如含有含羟基的丙烯酸树脂的主要成分的有机溶剂型涂料)相比,由涂层形成的固化膜 三聚氰胺树脂或羧基环氧型涂料)在耐候性,外观,耐酸性等方面至少相当,并且耐污染性优异。
摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20.degree. C. of 15 or more and the minimum value of dynamic modulus E' at a frequency of 110 Hz in the temperature range of 150-200.degree. C., of 1.times.1O.sup.9 dyn/cm.sup.2 or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherability, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要翻译:本发明提供一种热固性有机溶剂型涂料,其能够在20℃下的TUKON硬度形成15或更高的固化涂膜,并且在110℃的频率下在110Hz的频率下形成动态模量E'的最小值 150-200℃,为1×10 9 dyn / cm 2以上。 与由用作汽车面漆的常规有机溶剂型涂料形成的固化膜(例如含有含羟基的丙烯酸树脂的主要成分的有机溶剂型涂料)相比,由涂层形成的固化膜 三聚氰胺树脂或羧基环氧型涂料)在耐候性,外观,耐酸性等方面至少相当,并且耐污染性优异。
摘要:
This invention provides a copolymer having a number-average molecular weight within a range of 2,000-100,000 and a resin acid value within a range of 10-200 mgKOH/g, which is obtained by copolymerizing (a) 5-50 parts by weight of carboxyl-containing, polymerizable unsaturated macromonomer, (b) 30-70 parts by weight of at least one polymerizable unsaturated macromonomer selected from polyalkyl (meth)acrylate macromonomers and polystyrene macromonomers, and (c) 5-65 parts by weight of at least one other polymerizable unsaturated monomer which is copolymerizable with said (a) and/or (b) component; a pigment dispersion using this copolymer; and a pigment composition using this pigment dispersion.
摘要:
An aqueous amino resin dispersion excelling in storage stability and mechanical stability which is formed by dispersing hydrophobic amino resin in aqueous medium, using a polyester resin having specific hydroxyl value, acid value and number-average molecular weight as a dispersion stabilizer, said polyester resin being prepared by reacting polyhydric alcohol, polycarboxylic acid and/or polycarboxylic anhydride and monoepoxide compound having a long chain hydrocarbon group; thermosetting, water-based paint compositions comprising the aqueous amino resin dispersion; and multi-layered coating film-forming methods using the water-based paint compositions are provided.
摘要:
This invention provides water-based paint compositions containing water-dispersible acrylic polymer particles, hydroxyl-containing resin and curing agent, the water-dispersible acrylic polymer particles having a weight-average molecular weight of at least 1,100,000 and an absorbance value not higher than 0.2 at a wavelength of 330 nm, as measured with spectrophotometer in the state of liquid dispersion at a mass concentration of 1.35% in 1,4-dioxane solvent; and the compositions excelling in finished appearance such as coated surface smoothness and coating film performance such as chipping resistance and water resistance.
摘要:
This invention provides a water-based paint composition comprising an emulsion resin (A), melamine resin (B) and hydrophobic solvent (C), the emulsion resin (A) being fine resin particles having core/shell type multilayered structure composed of the core made of a copolymer (I) obtained by copolymerization of 0.1-30 mass % of polymerizable unsaturated monomer (a) having at least two polymerizable unsaturated groups per molecule and 70-99.9 mass % of other polymerizable unsaturated monomer (b), and the shell made of a copolymer (II) obtained by copolymerization of 5-50 mass % of vinyl aromatic compound (c) and 50-95 mass % of other polymerizable unsaturated monomer (d), the solid mass ratio of the copolymer (I)/copolymer (II) being within a range of 10/90-90/10; the melamine resin (B) having a weight-average molecular weight within a range of 1,000-5,000; and containing, per 100 mass parts of solid resin content in the water-based paint composition, the emulsion resin (A) within a range of 10-80 mass parts, the melamine resin (B), within a range of 5-50 mass parts, and the hydrophobic solvent (C), within a range of 10-100 mass parts. Use of the water-based paint composition allows formation of coating film free of metallic mottling and excelling in flip-flop property, smoothness, luster and water resistance.
摘要:
This invention provides both a pigment dispersing resin which is a copolymer of: (A) polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of tertiary amino group, quaternary ammonium salt and sulfonic acid group; (B) nonionic polymerizable unsaturated monomer having polyoxyalkylene chain; (C) ultraviolet-absorbing polymerizable unsaturated monomer and/or an ultraviolet-stabilizing polymerizable unsaturated monomer; and (D) other ethylenically unsaturated monomer, and water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, dispersing agent as well.
摘要:
This invention relates to a phosphoric acid group-containing non-aqueous dispersion wherein polymer particles are dispersed in a solution of a macromolecular dispersion stabilizer dissolved in an organic solvent, said polymer particle being a particle of polymer comprising a phosphoric acid group-containing polymerizable unsaturated monomeric unit as a constituent component. With use of said phosphoric acid group-containing non-aqueous dispersion, there can be improved interlayer adhesivity between a metallic coating film, which is formed from a leafing type aluminum flake pigment, and another coating film adjacent thereto, without reducing the excellent effects such as dense metallic feeling of the coated surface, a chrome plating-like finish, and strong brightness feeling and strong flip-flop perperties, which are produced by such a metallic coating film.