摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20.degree. C. of 15 or more and the minimum value of dynamic modulus E' at a frequency of 110 Hz in the temperature range of 150-200.degree. C., of 1.times.1O.sup.9 dyn/cm.sup.2 or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherability, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要翻译:本发明提供一种热固性有机溶剂型涂料,其能够在20℃下的TUKON硬度形成15或更高的固化涂膜,并且在110℃的频率下在110Hz的频率下形成动态模量E'的最小值 150-200℃,为1×10 9 dyn / cm 2以上。 与由用作汽车面漆的常规有机溶剂型涂料形成的固化膜(例如含有含羟基的丙烯酸树脂的主要成分的有机溶剂型涂料)相比,由涂层形成的固化膜 三聚氰胺树脂或羧基环氧型涂料)在耐候性,外观,耐酸性等方面至少相当,并且耐污染性优异。
摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20° C. of 15 or more and the minimum value of dynamic modulus E′ at a frequency of 110 Hz in the temperature range of 150-200° C., of 1×109 dyn/cm or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherabiIity, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要:
The present invention provides a thermosetting organic solvent type coating capable of forming a cured coating film having a TUKON hardness at 20° C. of 15 or more and the minimum value of dynamic modulus E′ at a frequency of 110 Hz in the temperature range of 150-200° C., of 1×109 dyn/cm2 or more. The cured film formed from the coating, as compared with the cured films formed from conventional organic solvent type coatings used as a top coat for automobile (e.g. an organic solvent type coating containing, as main components, a hydroxyl group-containing acrylic resin and a melamine resin, or a carboxylic-epoxy type coating), is at least equivalent in weatherability, finish appearance, acid resistance, etc. and superior in stain resistance.
摘要翻译:本发明提供一种热固性有机溶剂型涂料,其能够在20℃下形成具有15℃以上的TUKON硬度的固化涂膜,在110Hz的温度范围内形成频率为110Hz的动态模量E'的最小值 150-200℃,1×10 9 dyn / cm 2以上。 与由用作汽车面漆的常规有机溶剂型涂料形成的固化膜(例如含有含羟基的丙烯酸树脂的主要成分的有机溶剂型涂料)相比,由涂层形成的固化膜 三聚氰胺树脂或羧基环氧型涂料)在耐候性,外观,耐酸性等方面至少相当,并且耐污染性优异。
摘要:
There is disclosed a novel organic solvent type coating composition capable of making the solid content concentration at the time of coating to higher than 70% by weight, without lowering the properties, which urethane type coating materials have, such as acid resistance, scratch resistance, finishing appearance etc. The composition comprises (A) a vinyl type polymer having both hydroxyl groups and alkoxysilyl groups in the molecule and having a number-average molecular weight in a range of 2,000 to 10,000; (B) a polyol compound having a number-average molecular weight of less than 1,000 and having a hydroxyl value in a range of 120 to 1,000 mgKOH/g; (C) a polyisocyanate compound having a number-average molecular weight of less than 2,000; and (D) a silanol group forming catalyst.
摘要:
An organic solvent-based heat-curable high solid coating composition comprising:(A) a carboxyl-containing compound having an acid value of 50 to 500 mg KOH/g wherein 20 mol % or more of the carboxyl groups are silylated carboxyl groups,(B) at least one epoxide selected from (B-1) an epoxy-, hydroxyl- and hydrolyzable alkoxysilyl-containing vinyl polymer, (B-2) the vinyl polymer (B-1) wherein 20 mol % or more of the hydroxyl groups are silylated hydroxyl groups, and (B-3) an epoxy compound having a number average molecular weight less than 1,000, and(C) a crosslinked particulate polymer,the composition having a solid content of 65 wt. % or more; and a method for forming a topcoat using the composition. The composition of the invention has a sufficiently high solid content, is capable of forming a coating film with high resistance to acids and the like, and is excellent in low-temperature curability, storage stability and recoat adhesion.
摘要:
The present invention provides(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and a polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
摘要:
The present invention provides a process for preparing a self-curing resin having a blocked isocyanate group and a hydroxyl group in the molecule from a polymer 500 to 50000 in number average molecular weight and having a tertiary amino group and/or a quaternary ammonium group, and at least two isocyanate groups in the molecule, the process comprising the steps of partly blocking the isocyanate groups in the skeleton of the polymer, and reacting the remaining unblocked isocyanate groups with an alkanolamine to introduce hydroxyl groups into the polymer.
摘要:
The present invention provides:(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and an acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
摘要:
A self-crosslinkable resin useful as, for example, adhesive compositions and coating compositions. The resin contains complementary reactive groups, that is, a blocked isocyanate group and a hydroxyl group, in the same molecule. The resin is prepared by reacting a hydroxy-containing vinyl monomer with some isocyanate groups on the skeleton of a vinyl polymer having at least two isocyanate groups in the molecule so to introduce a polymerizable double bond into the polymer, and subsequently completely blocking the isocyanate group(s) remaining on the polymer skeleton with a blocking agent, or vice versa. Thereafter an unsaturated monomer component consisting essentially of a hydroxyl-containing vinyl monomer is polymerized with the polymerizable double bond introduced.
摘要:
The present invention provides a method for forming a multi-layer coating film by applying a clear coating (B) on the film of a leafing type aluminum flake-containing metallic coating (A), which method comprises forming a film of the metallic coating (A), curing the film, applying thereon a composition (C) containing a polymer formed from an unsaturated monomer having a phosphoric acid group represented by --O--PO(OH)(R.sub.1) (wherein R.sub.1 is a hydroxyl group, a phenyl group or a C.sub.1-20 alkyl group) and a hydroxyl group-containing unsaturated monomer, and then applying the clear coating (B) on the film of the composition (C). The method can form a multi-layer coating film improved in interlayer adhesivity between the metallic coating film and the clear coating film, without reducing the excellent effects and metallic feeling provided by a metallic coating film containing leafing type aluminum flake.