公开(公告)号：US11335913B2

公开(公告)日：2022-05-17

申请号：US16757953

申请日：2018-10-23

申请人： GLOBAL FRONTIER CENTER FOR MULTISCALE ENERGY SYSTEMS ,  SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION ,  KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Sung Soo Shin ,  Man Soo Choi ,  Jeong Hun Kim ,  Hyoungchul Kim ,  Ji-Won Son

IPC分类号： H01M4/88 ,  H01M8/1213 ,  H01M8/1246

摘要： The present invention presents a method for manufacturing a negative electrode of a solid oxide cell in a three-dimensional structure by using a pressurization process. In addition, the present invention proposes a structure in which the entire interface of a solid oxide cell is manufactured on the manufactured three-dimensional negative electrode substrate, through various deposition methods, in a three-dimensional structure so as to maximize a reaction area.

公开(公告)号：US11177482B2

公开(公告)日：2021-11-16

申请号：US16759822

申请日：2018-12-06

申请人： GLOBAL FRONTIER CENTER FOR MULTISCALE ENERGY SYSTEMS ,  KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY ,  SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION

发明人： Man Soo Choi ,  Jeong Hun Kim ,  Hyoungchul Kim ,  Ji-Won Son ,  Sung Soo Shin ,  Seung Yong Lee

IPC分类号： H01M4/88 ,  B05D1/04 ,  B05D3/02 ,  H01M4/86 ,  H01M8/1213 ,  H01M8/124

摘要： Disclosed is a method for infiltrating a porous structure with a precursor solution by means of humidification. The infiltration method with a precursor solution using moisture control comprises the steps of: (S1) providing a substrate having porous structures deposited thereon; (S2) depositing, by electrospraying, a precursor solution on the substrate having porous structures deposited thereon; (S3) humidifying the porous structures having the precursor solution deposited thereon; and (S4) sintering the humidified porous structures.

公开(公告)号：US11515544B2

公开(公告)日：2022-11-29

申请号：US16815871

申请日：2020-03-11

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Hae-Weon Lee ,  Ho Il Ji ,  Byung Kook Kim ,  Jong Ho Lee ,  Ji-Won Son ,  Kyung Joong Yoon ,  Hyoungchul Kim ,  Sungeun Yang ,  Sangbaek Park ,  Junseok Kim ,  Jisu Shin

IPC分类号： H01M4/88 ,  H01M8/1226 ,  H01M4/90 ,  H01M4/86 ,  H01M8/248 ,  H01M8/1253 ,  H01M8/12

摘要： Disclosed is a method of manufacturing a solid oxide fuel cell using a calendering process. The method includes preparing a stack including an anode support layer (ASL) and an anode functional layer (AFL), calendering the stack to obtain an anode, stacking an electrolyte layer on the anode to obtain an assembly, calendering the assembly to obtain an electrolyte substrate, sintering the electrolyte substrate, and forming a cathode on the electrolyte layer of the electrolyte substrate.

公开(公告)号：US09893367B1

公开(公告)日：2018-02-13

申请号：US15399066

申请日：2017-01-05

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Ji-Won Son ,  Thieu Cam Anh ,  Jongsup Hong ,  Hyoungchul Kim ,  Kyung Joong Yoon ,  Jong Ho Lee ,  Hae-Weon Lee ,  Byung Kook Kim

IPC分类号： B05D5/12 ,  H01M4/88 ,  C23C14/28 ,  H01M8/1246 ,  H01M4/92 ,  C23C14/34 ,  H01M8/124 ,  B05D7/00

CPC分类号： H01M4/8871 ,  B05D5/12 ,  B05D7/50 ,  C23C14/08 ,  C23C14/185 ,  C23C14/22 ,  C23C14/5806 ,  H01M4/8657 ,  H01M4/8889 ,  H01M4/9025 ,  H01M4/928 ,  H01M2004/8684 ,  H01M2008/1293

摘要： Provided is an interlayer for a thin electrolyte solid oxide cell, a thin electrolyte solid oxide cell including the same, and a method of forming the same. In various embodiments, functional elements (a fuel electrode, an electrolyte and a cathode) of the solid oxide cell are formed by means of a thin film process, and thus a nanostructure of the catalyst is not seriously lost due to agglomeration, different from a powder process. Thus, it is possible to accomplish catalyst activation according to a high specific surface area.

公开(公告)号：US10483550B2

公开(公告)日：2019-11-19

申请号：US15630471

申请日：2017-06-22

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Kyung Joong Yoon ,  Seung-Hwan Lee ,  Mansoo Park ,  Jongsup Hong ,  Hyoungchul Kim ,  Ji-Won Son ,  Jong Ho Lee ,  Byung Kook Kim ,  Hae-Weon Lee

IPC分类号： H01M4/88 ,  H01M4/90 ,  H01M8/12 ,  H01M8/1253 ,  H01M8/124

摘要： Provided is a solid oxide cell including a fuel electrode layer, electrolyte layer and an air electrode layer, wherein a diffusion barrier layer is provided between the air electrode layer and the electrolyte layer, the diffusion barrier layer includes: a first diffusion barrier layer formed on the electrolyte layer and including a sintered ceria-based metal oxide containing no sintering aid; and a second diffusion barrier layer formed on the first diffusion barrier layer and including a sintered product of a ceria-based metal oxide mixed with a sintering aid, the first diffusion barrier layer includes a sintered product of nanopowder and macropowder of a ceria-based metal oxide, and the first diffusion barrier layer and the second diffusion barrier layer are sintered at the same time. The diffusion barrier layer is densified, shows high interfacial binding force and prevents formation of a secondary phase derived from chemical reaction with the electrolyte.

公开(公告)号：US09966624B2

公开(公告)日：2018-05-08

申请号：US15346105

申请日：2016-11-08

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Kyung Joong Yoon ,  Seung-Hwan Lee ,  Mansoo Park ,  Jongsup Hong ,  Hyoungchul Kim ,  Ji-Won Son ,  Jong Ho Lee ,  Byung Kook Kim ,  Hae-Weon Lee

IPC分类号： H01M8/12 ,  H01M8/1253 ,  H01M8/126 ,  H01M8/124

CPC分类号： H01M8/1253 ,  C01F17/0018 ,  C01G51/006 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C04B35/50 ,  C04B35/6281 ,  C04B35/62815 ,  C04B35/62823 ,  C04B35/62886 ,  C04B35/62892 ,  C04B2235/3203 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/443 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/9615 ,  H01M8/126 ,  H01M2008/1293 ,  H01M2300/0074 ,  H01M2300/0077

摘要： Provided is a method for manufacturing a sintered body for an electrolyte and an electrolyte for a fuel cell using the same. More particularly, the following disclosure relates to a method for preparing an electrolyte having a firm thin film layer by using a sintered body having controlled sintering characteristics, and application of the electrolyte to a solid oxide fuel cell. It is possible to control the sintering characteristics of a sintered body through a simple method, such as controlling the amounts of crude particles and nanoparticles. In addition, an electrode using the obtained sintered body having controlled sintering characteristics is effective for forming a firm thin film layer. Further, such an electrolyte having a firm thin film layer formed thereon inhibits combustion of fuel with oxygen when it is applied to a fuel cell, and thus shows significantly effective for improving the quality of a cell.

公开(公告)号：US10923733B2

公开(公告)日：2021-02-16

申请号：US16256905

申请日：2019-01-24

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY ,  INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

发明人： Kyung Joong Yoon ,  Yun Jung Lee ,  Ji-su Shin ,  Mansoo Park ,  Ho Il Ji ,  Hyoungchul Kim ,  Ji-Won Son ,  Jong Ho Lee ,  Byung Kook Kim ,  Hae-Weon Lee

IPC分类号： H01M4/00 ,  H01M4/90 ,  H01M8/1246 ,  H01M4/86 ,  H01M8/124

摘要： The present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell and a method for preparing the same. More particularly, the present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell obtained by forming a ceramic nanocatalyst including a noble metal dispersed therein in an atomic unit and contained in an ionic state having an oxidation number other than 0 through an in situ infiltration process in the internal pores of a porous electrode, and to application of the nanocatalyst to a solid oxide fuel cell having significantly higher electrochemical characteristics as compared to the solid oxide fuel cells including the conventional nickel-based anode and oxide anode, and particularly showing excellent characteristics at an intermediate or low temperature of 600° C. or less.

公开(公告)号：US10790540B2

公开(公告)日：2020-09-29

申请号：US15994269

申请日：2018-05-31

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Hyoungchul Kim ,  Hae-Weon Lee ,  Byung Kook Kim ,  Jong Ho Lee ,  Ji-Won Son ,  Hun-Gi Jung ,  Eu Deum Jung ,  Sung Jun Choi ,  Bin Na Yoon

IPC分类号： H01M10/0562 ,  C01B17/02 ,  C01B17/22 ,  H01M4/02 ,  H01M10/052

摘要： The present invention relates to a lithium-ion-conductive sulfide-based solid electrolyte which contains lithium (Li), sulfur (S), phosphorus (P), indium (In) and selenium (Se) and has a crystal structure of InSe and a method for preparing the same.

公开(公告)号：US20240154143A1

公开(公告)日：2024-05-09

申请号：US18225218

申请日：2023-07-24

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Sungeun YANG ,  Ho Il Ji ,  Yeji Lim ,  Jong Ho Lee ,  Wan-jae Lee ,  Junseok Kim ,  Ji-Won Son ,  Kyung Joong Yoon ,  Deok-Hwang Kown

IPC分类号： H01M8/1253 ,  H01M4/90 ,  H01M8/1213 ,  H01M8/126

CPC分类号： H01M8/1253 ,  H01M4/9033 ,  H01M8/1213 ,  H01M8/126

摘要： In an embodiment of the present invention, a proton conductive oxide fuel cell comprising an electrode substrate, a proton conductive oxide electrolyte layer positioned on the electrode substrate, a proton conductive oxide reaction prevention layer positioned on the electrolyte layer, and a proton conductive oxide air electrode layer positioned on the reaction prevention layer, wherein the reaction prevention layer is composed of ABO3-δ structured perovskite proton conductive oxide, may be provided.

公开(公告)号：US09276272B2

公开(公告)日：2016-03-01

申请号：US14153250

申请日：2014-01-13

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Sung-Il Lee ,  Ji-Won Son ,  Jong Ho Lee ,  Hae June Je ,  Kyung Joong Yoon ,  Hae-Weon Lee ,  Byung Kook Kim

IPC分类号： H01M8/02

CPC分类号： H01M8/0217 ,  H01M8/021 ,  H01M8/0228 ,  H01M8/18 ,  H01M2008/1293 ,  Y02E60/528

摘要： Disclosed is a metal separator for a solid oxide regenerative fuel cell coated with a conductive spinel oxide film. In the conductive spinel oxide film, yttrium is added to a manganese-cobalt spinel oxide to suppress growth of an insulating oxide film on the surface of the metal separator and volatilization of metal. In the conductive oxide film coated on the metal separator, yttrium is segregated at the grain boundaries of the spinel so that migration of oxygen through the grain boundaries can be suppressed. Therefore, the surface of the metal separator can be protected from exposure to the atmosphere and water vapor when the solid oxide regenerative fuel cell is operated at high temperature. In addition, poisoning of electrodes by metal volatilization from the surface of the metal separator and growth of an insulating oxide film on the surface of the metal separator can be prevented. Therefore, the stability of the solid oxide regenerative fuel cell stack can be markedly improved.

摘要翻译： 公开了一种涂覆有导电尖晶石氧化物膜的固体氧化物再生燃料电池的金属隔板。 在导电性尖晶石氧化物膜中，将钇添加到锰 - 钴尖晶石氧化物中以抑制金属隔板表面上的绝缘氧化物膜的生长和金属的挥发。 在涂覆在金属隔板上的导电氧化膜中，钇在尖晶石的晶界处分离，从而可以抑制氧通过晶界的迁移。 因此，当固体氧化物再生燃料电池在高温下运行时，可以保护金属隔板的表面不暴露于大气和水蒸汽。 此外，可以防止从金属隔板的表面金属挥发引起的电极中毒和金属隔板表面上的绝缘氧化膜的生长。 因此，可以显着提高固体氧化物再生燃料电池堆的稳定性。