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公开(公告)号：US06916891B2
公开(公告)日：2005-07-12
申请号：US10051002
申请日：2002-01-22
申请人： George F. Salem , Robert J. Zagata
发明人： George F. Salem , Robert J. Zagata
IPC分类号： B01J21/08 , B01J23/44 , B01J23/52 , B01J32/00 , B01J37/00 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15 , C08F2/00 , B01J20/02
CPC分类号： B01J37/0045 , B01J21/08 , B01J23/44 , B01J23/52 , C07C67/055 , Y10T428/2982 , Y10T428/2989 , C07C69/01 , C07C69/15
摘要： Microspheroidal particles, suitable as fluidized bed catalyst supports, are prepared by incorporating a portion of small, preferably recycled, particles into a slurry of inorganic oxide sol and inorganic particles which is spray dried to form microspheroidal particles.
摘要翻译： 适合作为流化床催化剂载体的微球形颗粒通过将一部分小的，优选再循环的颗粒掺入无机氧化物溶胶和无机颗粒的浆料中来制备，其被喷雾干燥以形成微球形颗粒。
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2.发明授权Method of preparation of high active phase (AMM)oxidation catalysts with improved performance and attrition resistance 失效具有改进性能和耐磨性的高活性相（AMM）氧化催化剂的制备方法
公开(公告)号：US4659689A
公开(公告)日：1987-04-21
申请号：US836269
申请日：1986-03-05
CPC分类号： C07C253/26 , B01J23/28 , Y02P20/52
摘要： A process for the preparation of bismuth molybdate catalyst comprising (1) adding a dried mixture of metal salts of the active phase of the catalyst to an aqueous sol containing a support material for the active phase, (2) adding an acid to this slurry, (3) heating the slurry to dryness and (4) calcining the dried precursor to form the catalyst.
摘要翻译： 一种制备钼酸铋催化剂的方法，包括（1）将催化剂活性相的金属盐的干燥混合物加入含有活性相载体材料的水性溶胶中，（2）向该浆料中加入酸， （3）将浆料加热至干，（4）煅烧干燥的前体以形成催化剂。
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3.发明授权Preparation of maleic anhydride from n-butene in a one-reactor, fluid-bed system using two different catalysts 失效在单反应器，流化床系统中使用两种不同的催化剂从正丁烯制备马来酸酐
公开(公告)号：US4075232A
公开(公告)日：1978-02-21
申请号：US556092
申请日：1975-03-06
IPC分类号： C07D307/60 , B01J23/00 , B01J23/887 , B01J27/00 , B01J27/186 , B01J35/00 , C07B61/00 , C07C51/25
CPC分类号： B01J35/0006 , B01J23/8876 , B01J27/186 , C07C51/252 , B01J2523/00
摘要： Maleic anhydride is prepared by reacting n-butene with molecular oxygen at a temperature of about 200.degree. to about 600.degree. C in a fluid-bed reactor using a catalyst charge containing two different catalysts--the first catalyst being one that is especially effective for preparing butadiene from the n-butylenes; and the second catalyst being one that is especially effective for preparing maleic anhydride from butadiene. Unexpectedly, substantial yields of maleic anhydride are obtained.
摘要翻译： 马来酸酐通过使用含有两种不同催化剂的催化剂装料在流化床反应器中在约200至约600℃的温度下使正丁烯与分子氧反应来制备 - 第一种催化剂是对于 从正丁烯制备丁二烯; 第二催化剂是从丁二烯制备马来酸酐特别有效的催化剂。 出人意料的是，获得了大量的马来酐。
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公开(公告)号：US4170570A
公开(公告)日：1979-10-09
申请号：US866572
申请日：1978-01-03
IPC分类号： B01J23/28 , B01J23/88 , B01J23/887 , B01J23/888 , C07C51/215 , C07C51/25 , B01J27/14 , B01J29/00 , B01J29/10 , B01J29/16
CPC分类号： B01J23/8878 , B01J23/28 , B01J23/8885 , C07C51/215 , C07C51/252 , B01J2523/00
摘要： A process for preparing an attrition resistant molybdenum-containing oxidation catalyst comprising; heat-treating the active catalytic components in an oxidizing atmosphere at a temperature in excess of 175.degree. C.; refluxing the heat-treated oxide catalyst in an aqueous slurry of the required amount of support material; ball milling the resulting catalyst mixture; and subjecting the ball milled catalyst to a second heat-treating step in an oxidizing atmosphere, at a temperature in excess of 200.degree. C.
摘要翻译： 一种制备耐磨耗的含钼氧化催化剂的方法，包括： 在超过175℃的温度下在氧化气氛中热处理活性催化组分; 将热处理的氧化物催化剂回流到所需量的载体材料的水性浆料中; 球磨所得催化剂混合物; 在氧化气氛中，在超过200℃的温度下对球磨的催化剂进行第二热处理步骤。
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5.发明授权
公开(公告)号：US4060545A
公开(公告)日：1977-11-29
申请号：US691052
申请日：1976-05-28
CPC分类号： C07C67/39
摘要： The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
摘要翻译： 通过丙烯或异丁烯的氧化酯化制备的丙烯酸酯和甲基丙烯酸酯的制备，其中气态反应物与一种或多种催化剂和乙烯或醇接触可以有利地在单一流化床反应器中进行以获得所需的酯。
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