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公开(公告)号：US4608348A
公开(公告)日：1986-08-26
申请号：US794841
申请日：1985-11-04
CPC分类号： C03C10/16
摘要： This invention is directed to the production of glass-ceramic articles exhibiting great toughness, a modulus of rupture of at least 20,000 psi, and, in the form of bars having dimensions 5".times.0.5".times.0.1", sagging during the crystallization heat treatment of no more than 0.2" over a 4" span, and wherein potassium fluorrichterite constitutes the predominant crystal phase but wherein cristobalite is also present in an amount of at least 10% by volume. The inventive articles having an overall composition consisting essentially, in weight percent on the oxide basis, of:______________________________________ SiO.sub.2 65-69 Na.sub.2 O 1.5-3.3 Al.sub.2 O.sub.3 0.75-3.5 K.sub.2 O 4.2-6.0 MgO 13.5-17.5 BaO 0-2.5 CaO 3-4.8 P.sub.2 O.sub.5 `0-2.5 Li.sub.2 O 0.5-2.0 F 3.3-5.5 ______________________________________
摘要翻译： 本发明涉及生产具有很高韧性，断裂模量至少20,000psi的玻璃陶瓷制品，以及具有尺寸为5'0.5'0.1“的条形状的下垂 在结晶热处理期间在4“跨度处不超过0.2”的结晶热处理中，并且其中氟代氟铁矿构成主要结晶相，但其中方英石也以至少10体积％的量存在。 具有基本上以氧化物为基准的重量百分数的本发明制品为：-SiO 2 65-69 Na 2 O 1.5-3.3 -Al 2 O 3 0.75-3.5 K 2 O 4.2-6.0 -MgO 13.5-17.5 BaO 0-2.5 -CaO 3 -4.8 P2O5'0-2.5 -Li2O 0.5-2.0 F 3.3-5.5 -
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公开(公告)号：US4467039A
公开(公告)日：1984-08-21
申请号：US492953
申请日：1983-05-09
CPC分类号： C03C10/16
摘要： There is disclosed a highly crystalline glass-ceramic article exhibiting superior toughness against fracture propagation, a modulus of rupture in excess of 20,000 psi, a predominant crystal phase of potassium fluorrichterite, and having an overall composition consisting essentially ofSiO.sub.2 : 50-70CaO: 4-15MgO: 8-25F: 3-8Na.sub.2 O: 2-9K.sub.2 O: 2-12Li.sub.2 O: 0-3Al.sub.2 O.sub.3 : 0-7Canasite may be a secondary phase, but a crystal phase composed essentially of potassium fluorrichterite is preferred for dinnerware.
摘要翻译： 公开了一种高度结晶的玻璃陶瓷制品，其显示出优异的抗裂纹扩展韧性，破裂模量超过20,000psi，氟化钾的主要结晶相，并且具有基本上由SiO 2：50-70 CaO： 4-15 MgO：8-25 F：3-8 Na2O：2-9 K2O：2-12 Li2O：0-3 Al2O3：0-7硅藻土可以是次相，但是基本上由氟化钾合金组成的结晶相是 首选餐具。
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公开(公告)号：US4582760A
公开(公告)日：1986-04-15
申请号：US735660
申请日：1985-05-20
CPC分类号： C03C8/12
摘要： The present invention is concerned with the preparation of glazes which are especially suitable for application to glass-ceramic articles containing potassium fluorrichterite as substantially the sole crystal phase. The glazes consist essentially, expressed in terms of weight percent on the oxide basis, ofSiO.sub.2 :46-50Al.sub.2 O.sub.3 :5-8ZrO.sub.2 :0.3-1Li.sub.2 O:1-2Na.sub.2 O:2-3.5K.sub.2 O:1-2CaO:1-4ZnO:2-6SrO:2-6B.sub.2 O.sub.3 :9-11PbO:20-25.
摘要翻译： 本发明涉及特别适用于玻璃陶瓷制品的釉料的制备，所述玻璃陶瓷制品含有基本上唯一的结晶相的氟化钾。 釉料基本上以氧化物的重量百分数表示，SiO 2：46-50 Al 2 O 3：5-8 ZrO 2：0.3-1 Li 2 O：1-2Na 2 O：2-3.5K 2 O：1-2 CaO：1 -4 ZnO：2-6 SrO：2-6 B2O3：9-11 PbO：20-25。
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公开(公告)号：US4323653A
公开(公告)日：1982-04-06
申请号：US254901
申请日：1981-04-16
摘要： The instant invention is directed to the production of spontaneous opal glass compositions which limit the generation of CaF.sub.2 and crystals having a xonotlite structure therein when heat treated at temperatures higher than the annealing point, but lower than the softening point of the glass. The glasses consist essentially, as analyzed in weight percent on the oxide basis, of about:______________________________________ SiO.sub.2 64.5 .+-. 2.0 Al.sub.2 O.sub.3 6.25 .+-. 0.5 Na.sub.2 O 3.0 .+-. 0.5 K.sub.2 O 3.0 .+-. 0.5 MgO 1.25 .+-. 0.3 B.sub.2 O.sub.3 4.5 .+-. 0.7 F 3.25 .+-. 0.5 CaO 14.5 .+-. 1.0 ______________________________________
摘要翻译： 本发明涉及生产自发的蛋白石玻璃组合物，其在高于退火点但低于玻璃的软化点的温度下进行热处理时，限制了CaF 2的产生和其中具有黑云母结构的晶体。 基本上按照以氧化物为基准的重量百分比分析的玻璃基本上包含：-SiO 2 64.5 +/- 2.0 -Al 2 O 3 6.25 +/- 0.5 -Na 2 O 3.0 +/- 0.5-K 2 O 3.0 +/- 0.5 -MgO 1.25 + / - 0.3 -B2O3 4.5 +/- 0.7 -F 3.25 +/- 0.5 -CaO 14.5 +/- 1.0 -
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公开(公告)号：US4329400A
公开(公告)日：1982-05-11
申请号：US103415
申请日：1979-12-13
摘要： There is disclosed an integral vitreous article composed of an opacified interior portion encased within a surface layer of glass that is transparent except for an opacified zone of predetermined configuration. The article may be produced by momentarily contacting an exposed surface on a molten glass charge with a chilling member before forming the glass.
摘要翻译： 公开了一种整体玻璃制品，其由遮盖在玻璃表面层内的不透明的内部部分组成，除了具有预定构型的不透明区域之外，其是透明的。 制品可以在形成玻璃之前通过使熔融玻璃装料上的暴露表面与冷却构件接触来制造。
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公开(公告)号：US4023953A
公开(公告)日：1977-05-17
申请号：US602649
申请日：1975-08-07
CPC分类号： C03B17/025
摘要： There is disclosed a method of making composite glass tubing, and a molten glass feeding apparatus uniquely designed to carry out such method. The feeder apparatus comprises concentrically-arranged cylindrical containers, a blow tube located within the central container, and a plug member mounted on the base of the blow tube. The bottom portion of each cylindrical wall is downwardly and inwardly directed to provide restricted annular bottom openings. The bottom edges of the cylindrical walls and of the plug are positioned in such relation to each other that orifices are provided through which annular streams of molten glass may flow and contact adjacent streams in the fluid state, thereby forming composite glass tubing having at least three layers.
摘要翻译： 公开了制造复合玻璃管的方法和专门设计用于实施这种方法的熔融玻璃供给装置。 送料装置包括同心圆柱形容器，位于中央容器内的吹塑管，以及安装在吹塑管底部上的塞子件。 每个圆柱形壁的底部向下并向内指向以提供受限制的环形底部开口。 圆柱形壁和塞子的底部边缘以彼此关系的方式定位，所述孔被设置成通过该孔，熔融玻璃的环形流可通过该孔流动并且以流体状态接触邻近的流，从而形成具有至少三个 层。
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公开(公告)号：US4331769A
公开(公告)日：1982-05-25
申请号：US270340
申请日：1981-06-04
摘要： The instant invention is concerned with the production of spontaneous opal glasses exhibiting tints ranging from ivory-through-beige-through-tan-to-brown, depending upon the shade sought, and demonstrating a Fe.sup.+3 reading between about 6.5-9 consisting essentially, expressed in weight percent on the oxide basis, of about______________________________________ SiO.sub.2 64.5 .+-. 2.0 Al.sub.2 O.sub.3 6.25 .+-. 0.5 Na.sub.2 O 3.0 .+-. 0.5 K.sub.2 O 3.0 .+-. 0.5 MgO 1.25 .+-. 0.3 B.sub.2 O.sub.3 4.5 .+-. 0.7 F 3.25 .+-. 0.5 CaO 14.5 .+-. 1.0 NiO 0.02 - 1.0 ______________________________________
摘要翻译： 本发明涉及自发的蛋白石玻璃的生产，其显示出根据所寻求的色调而从象牙色到米色至棕褐色至棕色的色调，并且显示基本上为约6.5-9之间的Fe + 3读数 ，以氧化物为基准，以约-SiO 2 64.5 +/- 2.0 -Al 2 O 3的重量百分比表示。6.25 +/- 0.5-Na 2 O 3.0 +/- 0.5-K 2 O 3.0 +/- 0.5 -MgO 1.25 +/- 0.3 -B 2 O 3 4.5 +/- 0.7 -F 3.25 +/- 0.5 -CaO 14.5 +/- 1.0 -NiO 0.02-1.0 -
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公开(公告)号：US4211820A
公开(公告)日：1980-07-08
申请号：US8480
申请日：1979-02-02
CPC分类号： H05B3/74 , C03C10/0045 , Y10T428/315
摘要： This invention relates to the production of essentially transparent glass-ceramic sheet useful as surfaces for smoothtop cooking stoves which will display a warm brown coloration sufficiently dark to conceal the heating element when not in use, but permitting visible observation thereof when in operation. The products consist essentially, on an analyzed basis, of 2.5-4.5% Li.sub.2 O, 1-2% MgO, 1-2% ZnO, 19.5-21% Al.sub.2 O.sub.3, 66.5-68% SiO.sub.2, 4-5% TiO.sub.2, and 0.02-0.2% V.sub.2 O.sub.5.
摘要翻译： 本发明涉及生产基本上透明的玻璃陶瓷片材，它们可用作光面烹饪灶具的表面，这些表面将在不使用的情况下显示出足够暗的暖棕色着色以隐藏加热元件，但是在操作时允许可见的观察。 该产品基本上分析了2.5-4.5％Li2O，1-2％MgO，1-2％ZnO，19.5-21％Al2O3,66.5-68％SiO2，4-5％TiO2和0.02％ 0.2％V2O5。
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公开(公告)号：US3958052A
公开(公告)日：1976-05-18
申请号：US478584
申请日：1974-06-12
IPC分类号： C03B23/203 , C03C17/02 , C03C27/10 , C03C27/12 , B32B7/02
CPC分类号： C03C17/02 , B32B17/06 , C03B23/203 , C03C27/10 , Y10T428/23 , Y10T428/24967 , Y10T428/315
摘要： Subsurface-fortified glass laminates exhibiting improved breakage characteristics and increased resistance to delayed breakage are described. Such laminates have particular utility in the fabrication of glass tableware.
摘要翻译： 描述了具有改进的断裂特性和增加的延迟断裂抗性的表面强化的玻璃层压板。 这种层压板在玻璃餐具的制造中具有特别的用途。
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公开(公告)号：US4311529A
公开(公告)日：1982-01-19
申请号：US160388
申请日：1980-06-17
摘要： The present invention is concerned with the production of spontaneous opal glasses which, after thermal tempering, demonstrate a dense coloration ranging from ivory through yellow-beige to tan to a grayish-brown appearance, consisting essentially, by weight on the oxide basis, of 8-9% Na.sub.2 O, 2-2.5% K.sub.2 O, 5-6.5% CaO, 8-10% ZnO, 1-2% B.sub.2 O.sub.3, 10-11% Al.sub.2 O.sub.3, 3-4% F, 0.005-0.1% NiO, 0-2% CeO.sub.2, 0-4%TiO.sub.2, 0.5-6% CeO.sub.2 +TiO.sub.2, 0-0.5% As.sub.2 O.sub.3, and 57-61% SiO.sub.2.
摘要翻译： 本发明涉及自发的蛋白石玻璃的生产，其在热回火之后表现出从象牙到黄褐色到棕褐色到灰褐色外观的稠密着色，其基本上由氧化物的重量组成，为8 -9％Na2O，2-2.5％K2O，5-6.5％CaO，8-10％ZnO，1-2％B2O3，10-11％Al2O3,3.4％F，0.005-0.1％NiO，0-2 ％CeO 2，0-4％TiO 2，0.5-6％CeO 2 + TiO 2，0-0.5％As 2 O 3和57-61％SiO 2。
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