摘要:
Non-coordinating anions or anion precursors are disclosed. These non-coordinating anions serve as the activator for olefin polymerization catalyst systems. As such, they abstract an alkyl leaving group from a metallocene catalyst precursor leaving an activated catalyst charge balanced by a non-coordinating anion. These anions are formed by 3 or 4 partially fluorinated naphthyl ligands coordinated around boron (or other Group-13 element) creating corresponding tris-borane or tetrakis-borate complexes.
摘要:
Ethylene propylene copolymers, substantially free of diene, are described. The copolymers will have a uniform distribution of both tacticity and comonomer between copolymer chains. Further, the copolymers will exhibit a statistically insignificant intramolecular difference of tacticity. The copolymers are made in the presence of a metallocene catalyst.
摘要:
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要:
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要:
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要:
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要:
The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer with propylene and/or 1-butene which comprises: (A) polymerizing ethylene, and as an α-olefin comonomer propylene and/or 1-butene under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 30% and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min, preferably from 0.1 to 20, and an I21/I2 of from 30 to 400. The invention also relates to polymers made by such processes containing as α-olefin comonomer propylene and/or 1-butene, having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min and an I21/I2 of from 30 to 400 obtained by solution polymerization using a transition metal complex as a catalyst and a non-coordinating anion to provide a level of NCA derived residue, as determined by boron content, less than 0.5 ppm. as determined by ICP, preferably undetectable by ICP. The polymers may be blended with EP rubber elastomers and be used for electrical cable insulation.
摘要翻译:本发明涉及用丙烯和/或1-丁烯制备无规乙烯互聚物的连续聚合方法,其包括:(A)在连续无规聚合条件下聚合乙烯和作为α-烯烃共聚单体丙烯和/或1-丁烯 在使用具有屏蔽中心带电荷原子的环状配体的离子活化剂的单中心催化剂体系存在下,在140℃至250℃的温度下,乙烯的转化率为80-99%,共聚单体转化率 至少30%,(B)使该聚合物脱挥发分,得到密度为0.85至0.92g / cm 3的乙烯共聚物,MI为0.01至100g / 10min,优选为 本发明还涉及通过这样的方法制备的聚合物,该聚合物含有α-烯烃共聚单体丙烯和/或 /或1-丁烯,密度为0.85至0.92g / cm 3,MI为0.0 通过使用过渡金属络合物作为催化剂的溶液聚合获得的30至400的1至100g / 10min和1〜20wt%的非配位性 阴离子,以提供由硼含量确定的NCA衍生残基的水平小于0.5ppm。 由ICP测定,优选不能通过ICP检测。 聚合物可与EP橡胶弹性体共混并用于电缆绝缘。
摘要:
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要:
The invention relates to viscosity modifier polymers, concentrate and lubricant formulations utilizing a diblock polymer having one block A and one block B, block A contributing from 15 to 30% of the total chain length and block B from 70 to 85% of the total chain length, wherein block A comprises at least 93 wt % of ethylene and at least one other alpha-olefin and block B comprises an ethylene content between 40 and 75 wt % and at least one other alpha-olefin and wherein the resulting block copolymer has an average ethylene content of between about 60 wt % to 80 wt % ethylene, a fast Gaussian NMR relaxation signal between 17 and 22% and a slow exponential NMR relaxation signal between 58 and 68% of the total NMR relaxation signal, a SSI of at least 35% and a TE of at least 3.5 in order to obtain improvements in fuel economy.