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24 条记录 (耗时 0.023 秒)

    Process for coal liquefaction in staged dissolvers
    1.
    发明授权
    Process for coal liquefaction in staged dissolvers 失效
    阶梯式溶解器中煤液化过程

    公开(公告)号：US4421630A

    公开(公告)日：1983-12-20

    申请号：US308639

    申请日：1981-10-05

    申请人： George W. Roberts ,  Edwin N. Givens ,  Ronald W. Skinner

    发明人： George W. Roberts ,  Edwin N. Givens ,  Ronald W. Skinner

    IPC分类号： C10G1/00

    CPC分类号： C10G1/006

    摘要： There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a pasting oil, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. In accordance with the improved process, the first dissolver is operated at a higher temperature than the second dissolver. This temperature sequence produces improved product selectivity and permits the incorporation of sufficient hydrogen in the solvent for adequate recycle operations.

    摘要翻译： 描述了一种改进的液化过程，其中煤转化为低灰分和低硫碳质材料，其可以以环境可接受的方式用作燃料，而不需要昂贵的气体洗涤设备。 在此过程中，煤用粘贴的油浆化，在富含氢气的气体存在下，在升高的温度和压力下，通过预热器和至少两个溶解器串联。 固体，包括矿物灰和未转化的煤矿，与冷凝的反应器流出物分离。 根据改进的方法，第一溶解器在比第二溶解器更高的温度下操作。 该温度序列产生改善的产物选择性，并允许在溶剂中引入足够的氢以进行充分的循环操作。

    Iron catalyzed coal liquefaction process
    3.
    发明授权
    Iron catalyzed coal liquefaction process 失效
    铁催化煤液化过程

    公开(公告)号：US4411766A

    公开(公告)日：1983-10-25

    申请号：US352282

    申请日：1982-02-25

    申请人： Diwakar Garg ,  Edwin N. Givens

    发明人： Diwakar Garg ,  Edwin N. Givens

    IPC分类号： C10G1/06 ,  C07C1/00 ,  C10G1/08

    CPC分类号： C10G1/086 ,  C07C1/00 ,  C07C2523/745 ,  C07C2527/043

    摘要： A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

    摘要翻译： 描述了将煤的溶剂精炼成气体产物，液体产物和通常为固体的溶解产物的方法。 颗粒煤和独特的助催化剂体系悬浮在煤溶剂中，并在煤液化反应器，优选沸腾床反应器中加工。 助催化剂体系包括化学计量过量的氧化铁和黄铁矿的组合，其主要在反应区域中还原成活性硫化铁催化剂。 该催化剂体系导致催化活性增加，伴随改善的煤转化率和提高的油产物分布以及减少的硫化物流出物。 氧化铁以化学计量过量的量使用，与原料煤中的硫反应所需的量以及在将黄铁矿催化剂还原成硫化铁时产生的氧化铁。

    Novel reforming catalysts
    5.
    发明授权
    Novel reforming catalysts 失效
    新型重整催化剂

    公开(公告)号：US4141859A

    公开(公告)日：1979-02-27

    申请号：US757113

    申请日：1977-01-05

    申请人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

    发明人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

    IPC分类号： B01J29/068 ,  B01J29/076 ,  B01J37/04 ,  C10G35/095 ,  B01J29/06 ,  B01J27/06

    CPC分类号： B01J29/068 ,  B01J29/076 ,  B01J37/04 ,  C10G35/095

    摘要： Crystalline aluminosilicate zeolites are mixed with conventional reforming catalysts to produce new catalytic compositions with high catalytic activity and selectivity and excellent aging characteristics. These new catalytic compositions may be utilized alone or in conjunction with conventional reforming catalysts. The acidic activity of the total catalyst system is controlled within defined limits. When so controlled the utility of these catalyst systems in reforming hydrocarbon mixtures is to reduce the C.sub.1 and C.sub.2 concentrations in reformer gas product, while increasing the C.sub.3 and C.sub.4 concentrations and maintaining high liquid yield at high octane numbers.

    摘要翻译： 将结晶硅铝酸盐沸石与常规重整催化剂混合以产生具有高催化活性和选择性以及优异的老化特性的新催化组合物。 这些新的催化组合物可以单独使用或与常规重整催化剂结合使用。 总催化剂体系的酸性活性控制在规定的限度内。 如果这样控制，这些催化剂体系在重整烃混合物中的效用是降低重整器气体产物中的C1和C2浓度，同时增加C3和C4浓度，并保持高辛烷值下的高液体产率。

    Process for solvent refining of coal using a denitrogenated and dephenolated solvent
    6.
    发明授权
    Process for solvent refining of coal using a denitrogenated and dephenolated solvent 失效
    使用脱氮和去苯酚溶剂对煤进行溶剂精制的方法

    公开(公告)号：US4472263A

    公开(公告)日：1984-09-18

    申请号：US399671

    申请日：1982-07-19

    申请人： Diwakar Garg ,  Edwin N. Givens ,  Frank K. Schweighardt

    发明人： Diwakar Garg ,  Edwin N. Givens ,  Frank K. Schweighardt

    IPC分类号： C10L9/02 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10L9/04

    CPC分类号： C10G1/083 ,  C10G1/002 ,  C10G1/065

    摘要： A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

    摘要翻译： 公开了一种用于在氢气氛中的高温和高压下使用烃溶剂对非无烟煤进行溶剂精制的方法，在烃溶剂中，在溶剂精制过程中再循环之前，对其进行化学处理，从而提取基本上所有的含氮和酚类成分 溶剂，以改善溶剂精炼过程中煤的转化和油的生产。 溶剂精制过程可以是热还是催化。 含氮化合物的提取可以通过酸接触如氯化氢或氟化物处理进行，而酚提取可以通过苛性碱接触或与二氧化硅和氧化铝的混合物接触进行。

    Converting low molecular weight olefins over zeolites
    8.
    发明授权
    Converting low molecular weight olefins over zeolites 失效
    将低分子量烯烃转化为沸石

    公开(公告)号：US3960978A

    公开(公告)日：1976-06-01

    申请号：US503420

    申请日：1974-09-05

    申请人： Edwin N. Givens ,  Charles J. Plank ,  Edward J. Rosinski

    发明人： Edwin N. Givens ,  Charles J. Plank ,  Edward J. Rosinski

    IPC分类号： C10G29/00 ,  C10G50/00 ,  C07C3/20

    CPC分类号： C10G50/00 ,  C10G2400/02 ,  Y10S585/906

    摘要： Gaseous C.sub.2 -C.sub.5 olefins, either alone or in admixture with paraffins, are converted into an olefinic gasoline blending stock with a good research octane number in good yields by passage over a ZSM-5 type zeolite catalyst of controlled acidity. The catalyst must have reduced activity for cracking of n-hexane or aromatization of olefins or paraffins if it is to be useful for the purpose of this invention.

    摘要翻译： 单独或与链烷烃混合的气态C 2 -C 5烯烃通过通过控制酸度的ZSM-5型沸石催化剂而以良好的研究辛烷值转化为具有良好研究辛烷值的烯烃汽油共混料。 如果催化剂对于本发明的目的是有用的，那么催化剂必须具有降低的正己烷裂解活性或烯烃或链烷烃的芳构化作用。

    Removal of basic nitrogen compounds from hydrocarbon liquids
    9.
    发明授权
    Removal of basic nitrogen compounds from hydrocarbon liquids 失效
    从烃类液体中去除碱性氮化合物

    公开(公告)号：US4521299A

    公开(公告)日：1985-06-04

    申请号：US546789

    申请日：1983-10-31

    申请人： Edwin N. Givens ,  David S. Hoover

    发明人： Edwin N. Givens ,  David S. Hoover

    IPC分类号： C10G25/00

    CPC分类号： C10G25/003

    摘要： A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

    摘要翻译： 提供了一种通过提供固体颗粒碳质吸附剂/燃料材料（例如在其表面上具有活性碱性氮络合位点的煤）和具有烃类的煤的方式来减少在精炼工业中使用的含烃原料流体中的碱性氮化合物浓度的方法 含有碱性氮化合物的原料以便于将碱性氮化合物吸引到络合位点并在煤表面上形成其络合物。 吸附剂煤材料及其上形成的配合物来自原料流体，以提供具有降低的碱式氮化合物浓度的含烃流体。 然后煤可以用作锅炉等的燃料。

    Novel reforming catalysts
    10.
    发明授权
    Novel reforming catalysts 失效
    新型重整催化剂

    公开(公告)号：US4276151A

    公开(公告)日：1981-06-30

    申请号：US134818

    申请日：1980-03-28

    申请人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

    发明人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

    IPC分类号： C10G35/095 ,  C10G35/06

    CPC分类号： C10G35/095

    摘要： ZSM-5 type zeolites as more specifically defined hereinabove, are added to reforming catalysts in order to produce a new catalyst composition with high catalytic activity and excellent selectivity. These new catalysts when utilized in reforming naphtha, reduce the C.sub.1 plus C.sub.2 concentrations in reformer gas product, while increasing the C.sub.3 plus C.sub.4 concentrations.

    摘要翻译： 为了制备具有高催化活性和优异选择性的新催化剂组合物，将重质催化剂加入上文更具体地定义的ZSM-5型沸石。 这些新型催化剂用于重整石脑油时，降低重整气产物中的C1 + C2浓度，同时提高C3 + C4浓度。