摘要:
This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid (i.e. a mixture of liquid hydrocarbon and a hydrogen-containing gas) at a rate insufficient to levitate or ebullate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion, such as in a large pilot plant run, with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed. At the desired flow rate, such catalyst continually flows in a plug-like manner downwardly through the reactor vessel by introducing fresh catalyst at the top of the catalyst bed by laminarly flowing such catalyst in a liquid stream on a periodic or semicontinuous basis. Catalyst is similarly removed by laminarly flowing catalyst particles in a liquid stream out of the bottom of the catalyst bed. Intake for such flow is out of direct contact with the stream of gas flowing through the bed and the flow path is substantially constant in cross-sectional area and greater in diameter by several times than the diameter of the catalyst particles. The catalyst of this invention produces a plug-flowing substantially packed bed of hydroprocessing catalyst which occupies at least about 75% by volume of the reactor volume.
摘要:
This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid (i.e. a mixture of liquid hydrocarbon and a hydrogen-containing gas) at a rate insufficient to levitate or ebullate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion, such as in a large pilot plant run, with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed. At the desired flow rate, such catalyst continually flows in a plug-like manner downwardly through the reactor vessel by introducing fresh catalyst at the top of the catalyst bed by laminarly flowing such catalyst in a liquid stream on a periodic or semicontinuous basis. Catalyst is similarly removed by laminarly flowing catalyst particles in a liquid stream out of the bottom of the catalyst bed. Intake for such flow is out of direct contact with the stream of gas flowing through the bed and the flow path is substantially constant in cross-sectional area and greater in diameter by several times than the diameter of the catalyst particles. The catalyst of this invention produces a plug-flowing substantially packed bed of hydroprocessing catalyst which occupies at least about 75% by volume of the reactor volume.
摘要:
This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid at a rate insufficient to levitate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed. At the desired flow rate, such catalyst continually flows in a plug-like manner downwardly through the reactor vessel by introducing fresh catalyst at the top of the catalyst bed by laminarly flowing such catalyst in a liquid stream on a periodic or semicontinuous basis. Catalyst is removed by laminarly flowing catalyst particles in a liquid stream out of the bottom of the catalyst bed. Intake for such flow is out of direct contact with the stream of gas flowing through the bed and the flow path is substantially constant in cross-sectional area and greater in diameter by several times than the diameter of the catalyst particles. The catalyst produces a plug-flowing substantially packed bed of hydroprocessing catalyst which occupies at least about 75% by volume of the reactor volume.
摘要:
On-stream catalyst replacement apparatus for countercurrent upstream flow of a gas and hydrocarbon liquid through a downward moving catalyst bed in a reactor vessel. A mixed feed stream of gas and liquid hydrocarbon components enters a reservoir formed between the lower end of the reactor and a conical screen supporting the lower end of a catalyst bed. A wall across the vessel divides the reservoir into a lower surge chamber for receiving the mixed feed and an upper plenum chamber for separating the components into alternate feed rings of gas and hydrocarbon liquid under the conical screen. The mixed feed enters the plenum chamber through a plurality of tubes extending downwardly from the wall to the same depth in the surge chamber that prevents establishing preferential paths for gas to independently enter the plenum chamber. Excessive separation of the gas and liquid components from the mixed feed in the plenum chamber is prevented by use of a plurality of concentric baffles abutting the underside of the conical screen and which are closely spaced apart only sufficient to create adjacent and alternate feed rings of gas and liquid. The depth of the lower end of each baffle is intermediate the depth of the two radially adjacent concentric baffles.Catalyst is continuously or periodically added to, or removed from, the vessel through tubing and a full-bore valve having uniform diameters throughout their lengths to maintain laminar flow of catalyst to or from a pressurizable hopper vessel.
摘要:
This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid at a rate insufficient to levitate the bed and with catalyst selected by a density, shape and size at a design feed rate of liquids and gas to prevent ebulation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion in a large pilot plant run with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed. At the desired flow rate, such catalyst continually flows in a plug-like manner downwardly through the vessel by introducing fresh catalyst at the top of the bed by laminarly flowing such catalyst in a liquid stream on a periodic or semicontinuous basis. Catalyst is similarly removed by laminarly flowing catalyst particles in a liquid stream out of the bottom of the bed. Intake for such flow is out of direct contact with the stream of gas flowing through the bed and the flow path is substantially constant in cross-sectional area and greater in diameter by several times than the diameter of the catalyst particles.
摘要:
A method, and a reactor, for hydroprocessing a hydrocarbon feed stream through multistage moving catalyst beds contained within a single onstream reactor vessel, with separate catalyst addition and withdrawal systems for each of the multistages of moving catalyst beds. The reactor contains two or more different and distinct moving catalyst beds for any hydroprocessing application. The method includes serially passing, without leaving the reactor vessel, at least a partially treated hydrocarbon stream from one hydroconversion reaction zone containing a moving catalyst bed with a first set of catalytic characteristics to another hydroconversion reaction zone containing a moving catalyst bed with a second set of catalytic characteristics that differ in catalytic abilities from the first set of catalytic characteristics.
摘要:
A method is disclosed for withdrawing particulate spent catalyst particles from a packed, non-fluidized bed of such particles in contact with a liquid medium within a vessel having a withdrawal conduit or pipe which has an inlet that opens within the bottom of the bed and faces generally downwardly so that a first section extends upwardly from the inlet, and a second section extends downwardly, and the spent catalyst particles exits the packed bed through a uniform and continuous flow path opening into a solids recovery vessel whose pressure is controlled to regulate flow of such spent catalyst from the reaction vessel independent of the rate of flow through the withdrawal conduit.
摘要:
Methods for discovering optimum catalyst systems for the conversion of syngas to higher molecular weight products via Fischer-Tropsch synthesis are disclosed. A combinatorial approach is used to identify combinations of catalyst systems useful for performing the reactions. The combinations of catalyst systems include Fischer-Tropsch catalysts and olefin isomerization catalysts. The method can advantageously be used to generate a database of combinations of catalyst systems and/or reaction conditions that provide various product streams, such that as market conditions vary and/or product requirements change, conditions suitable for forming desired products can be identified with little or no downtime. The catalysts are combined in a logical manner, for example in the form of arrays. The combinations of catalysts can be evaluated using varied reaction conditions, which can provide a) a combinatorial library of product streams and a database including the combination of catalysts and reaction conditions to provide each product stream and/or b) the optimum combination of catalysts and reaction conditions for obtaining a desired product stream.
摘要:
Methods for discovering optimum catalysts and/or reaction conditions for performing endo-or exothermic reactions, in particular gas-to-liquid reactions, are disclosed. A combinatorial approach is used to identify optimum catalysts and/or reaction conditions for performing the reactions. The reactions are performed in the channels of a microchannel reactor. These results can be used directly to optimize large scale reactions performed in a plurality of microchannel reactors, or can be correlated to useful catalysts and reaction conditions for use in large scale reactors by taking into consideration the heat transfer effects in the microchannel reactor and the large scale reactor. The method can advantageously be used to generate a database of combinations of catalyst systems and/or reaction conditions which provide various product streams, such that as market conditions vary and/or product requirements change, conditions suitable for forming desired products can be identified with little or no downtime. The catalysts can be evaluated using varied reaction conditions, which can provide a) a combinatorial library of product streams and a database including the combination of catalysts and reaction conditions to provide each product stream and/or b) the optimum combination of catalysts and reaction conditions for obtaining a desired product stream.
摘要:
Apparatus for withdrawing particulate spent catalyst particles from a packed, non-fluidized bed of such particles in contact with a liquid medium within a vessel wherein the apparatus is a withdrawal conduit or pipe which has an inlet that opens within the bottom of the bed and faces generally downwardly so that a first section extends upwardly from the inlet, and a second section extends downwardly, and the spent catalyst particles exits the packed bed through a uniform and continuous flow path opening into a solids recovery vessel whose pressure is controlled to regulate flow of such spent catalyst from the reaction vessel independent of the rate of flow through the withdrawal conduit.