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公开(公告)号：US20090148653A1
公开(公告)日：2009-06-11
申请号：US12237446
申请日：2008-09-25
IPC分类号： B32B5/02 , C08L67/06 , C08L81/00 , C08L79/02 , D03D27/00 , B32B27/10 , C08L77/00 , C08L63/00 , C08L83/00
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, of formula (I) Rf1-L-X—C(O)—C(R)═CH2 (I) whereinRf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having from about 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least about 2:1 and no oxygen atoms are bonded to each other;L is a linear or branched divalent linking group having 1 to about 20 carbon atoms; optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting or —O—, —NR1—, —S—, —SO—, —SO2—, —N(R1)C(O)—; wherein R1 is H or C1 to C6 alkyl;X is —O—, —NR1—, or —S—;R is hydrogen, Cl, F or CH3; (b) from about 5% to about 80% of at least one of: (i) an alkyl(meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的氟代烷基单体或单体混合物<？在线公式描述=“In 线型式“end =”lead“→Rf1-LXC（O）-C（R）-CH2（I）<βin-line-formula description =”In-line Formulas“end =”tail“？>其中 Rf1是具有约2至约100个碳原子的单价，部分或完全氟化的直链或支链烷基; 任选地被1至约50个氧原子中断; 其中碳原子与氧原子的比例为至少约2:1且没有氧原子彼此键合; L是具有1至约20个碳原子的直链或支链二价连接基团; 任选地被1至大约4个选自以下的杂原子中断：-NR 1 - ， - S - ， - SO - ， - SO 2 - ， - N（R 1）C（O） - ; 其中R1是H或C1-C6烷基; X是-O-，-NR1-或-S-; R是氢，Cl，F或CH 3; （b）约5％至约80％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的可聚合纳米颗粒。
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公开(公告)号：US20090149096A1
公开(公告)日：2009-06-11
申请号：US12268470
申请日：2008-11-11
IPC分类号： B32B27/12 , B32B27/04 , B32B27/00 , C08F220/24
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的氟烷基单体或单体混合物，（b）约5％至约80％ ：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的非氟化可聚合纳米颗粒。
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公开(公告)号：US08314037B2
公开(公告)日：2012-11-20
申请号：US12268470
申请日：2008-11-11
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的氟烷基单体或单体混合物，（b）约5％至约80％ ：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的非氟化可聚合纳米颗粒。
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公开(公告)号：US20080004394A1
公开(公告)日：2008-01-03
申请号：US11479904
申请日：2006-06-30
IPC分类号： C09D5/02
CPC分类号： C08G73/02 , C08F220/18 , C08F220/22 , C08G61/124 , C08G61/125 , C09D133/16 , D06M15/263 , D06M15/277 , D06M15/285 , D06M15/576
摘要： A method of providing water repellency, alcohol repellency, oil repellency, and soil resistance to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula 1 in any sequence: [Rf(CH2)kOC(O)NH(CH2)kOC(O)C(T)CH2]m—[Wq]p—Formula 1 wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each k is independently a positive integer from 1 to about 6, T is hydrogen or methyl, m is a positive integer, q is zero or a positive integer, p is zero or a positive integer, and W is or or —[R1—X—Y—C(O)—CZ-CH2]—, wherein X is an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing a triazole, oxygen, nitrogen, or sulfur, or a combination thereof, Y is O or N(R) wherein R is H or C1 to C20 alkyl, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, Rx is C(O)O(R1), C(O)N(R2)2, OC(O)(R1), SO2(R1), C6(R3)gH(5-g), O(R1), halide, or R1; each R1 is independently H, CnH2n+1, CnH2n—CH(O)CH2, [CH2CH2O]iR4, [CnC2n]N(R4)2 or [CnH2n]CnF2n+1, n is 1 to about 40, R4 is H or CsH2s+1, s=0 to about 40, i=1 to about 200, each R2 is independently H, or CtH2t+1 wherein t is 1 to 20, each R3 is independently R4, COOR1, halogen, N(R1)2, OR1, SO2NHR1, CH═CH2, or SO3M, g is 1 to 5, and M is H, alkali metal salt, alkaline earth metal salt, or ammonium.
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公开(公告)号：US20080202384A1
公开(公告)日：2008-08-28
申请号：US11712324
申请日：2007-02-28
申请人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
发明人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
CPC分类号： C08F214/18 , C08F214/186 , C08F220/18 , C08F220/24 , C08F220/28 , C08F220/58 , C09D133/16 , D06M15/263 , D06M15/267 , D06M15/277 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): Rf—(CH2CF2)q(CH2CH2)r-Z-C(O)—C(R)═CH2 (I) wherein q and r are each independently integers of 1 to 3; Rf is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR1— or —S—; R is hydrogen, Cl, F or CH3; R1 is hydrogen, or a C1 to C4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is as defined above; each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.
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公开(公告)号：US07829477B2
公开(公告)日：2010-11-09
申请号：US11978290
申请日：2007-10-29
申请人： Peter Michael Murphy , Jessica Sinks , Ying Wang
发明人： Peter Michael Murphy , Jessica Sinks , Ying Wang
IPC分类号： B32B5/02
CPC分类号： C09D133/16 , C08F220/04 , C08F220/24 , C08F220/32 , C08F220/38 , C08F220/58 , Y10T428/23986 , Y10T428/31544 , Y10T442/2172 , Y10T442/2279 , Y10T442/2287
摘要： A method of providing water repellency, oil repellency, soil resistance, soil release, stain resistance and stain release to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula 1 in any sequence: wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 2 to about 15 carbon atoms, —O(CnH2n)—, —(CH2CF2)m(CH2)n—, —CONR1(CnH2n)—, —(CnH2n)OCONR1(CnH2n)—, (—CONR1CH2)2CH—, —SO2N(R1)(CnH2n)—, or —(CnH2n)SO2N(R1)(CnH2n)—, each R1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, Z is hydrogen or methyl, x is a positive integer, y is zero or a positive integer, t is a positive integer, and M is H+, alkali metal cation, alkaline earth metal cation, or ammonium.
摘要翻译： 提供防水性，拒油性，耐土壤性，污垢释放，耐污染性和对基材的污迹释放的方法，包括使所述底物与包含具有任何顺序的具有式1的重复单元的共聚物的组合物接触的组合物接触：其中Rf是直链或支链 具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，2至约15个碳原子的羟基亚烷基，-O （CnH2n） - ， - （CH2CF2）m（CH2）n-，-CONR1（CnH2n） - ， - （CnH2n）OCONR1（CnH2n） - ，（-CONR1CH2）2CH-，-SO2N（R1）（CnH2n） 或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，m各自独立地为1至约4，Z为氢 或甲基，x为正整数，y为零或正整数，t为正整数，M为H +，碱金属阳离子，碱 地球金属阳离子或铵。
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公开(公告)号：US20110178260A1
公开(公告)日：2011-07-21
申请号：US12690674
申请日：2010-01-20
申请人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
发明人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
IPC分类号： C08F220/22
CPC分类号： C08F220/24 , C08F2220/1891 , D06M15/263 , D06M15/267 , D06M15/277 , D06M15/295 , D06M2200/01 , C08F2220/1858 , C08F2220/281 , C08F220/58 , C08F2220/325 , C08F2220/286
摘要： A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): Rf—(CH2CF2)q(CH2CH2)r—Z—C(O)—C(R)═CH2 (I) wherein q and r are each independently integers of 1 to 3; Rf is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR1— or —S—; R is hydrogen, Cl, F or CH3; R1 is hydrogen, or a C1 to C4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is as defined above; each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.
摘要翻译： 包含按以下重量百分比共聚单体的组合物：（a）约20％至约95％的式（I）单体或单体混合物：Rf-（CH 2 CF 2）q（CH 2 CH 2）r-Z -C（O）-C（R）= CH 2（I）其中q和r各自独立地为1至3的整数; Rf是具有2-6个碳原子的直链或支链全氟烷基; Z是-O-，-NR1-或-S-; R是氢，Cl，F或CH 3; R1是氢或C1-C4烷基; 和（b）约5％至约80％的至少一种：（i）具有6至18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）式（II）的单体：（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R定义同上; 每个R 2独立地为C 1至C 4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物; 所述组合物对与其接触的基材提供拒油性，拒水性和耐污染性; 和用这种共聚物组合物处理底物的方法; 被披露。
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公开(公告)号：US20090111344A1
公开(公告)日：2009-04-30
申请号：US11978290
申请日：2007-10-29
申请人： Peter Michael Murphy , Jessica Sinks , Ying Wang
发明人： Peter Michael Murphy , Jessica Sinks , Ying Wang
CPC分类号： C09D133/16 , C08F220/04 , C08F220/24 , C08F220/32 , C08F220/38 , C08F220/58 , Y10T428/23986 , Y10T428/31544 , Y10T442/2172 , Y10T442/2279 , Y10T442/2287
摘要： A method of providing water repellency, oil repellency, soil resistance, soil release, stain resistance and stain release to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula I in any sequence: wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 2 to about 15 carbon atoms, —O(CnH2n)—, —(CH2CF2)m(CH2)n—, —CONR1(CnH2n)—, —(CnH2n)OCONR1(CnH2n)—, (—CONR1CH2)2CH—, —SO2N(R1)(CnH2n)—, or —(CnH2n)SO2N(R1)(CnH2n)—, each R1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, Z is hydrogen or methyl, x is a positive integer, y is zero or a positive integer, t is a positive integer, and M is H+, alkali metal cation, alkaline earth metal cation, or ammonium.
摘要翻译： 提供防水性，拒油性，耐土壤性，污垢释放，耐污染性和对底物的污迹释放的方法，包括使所述底物与包含具有以下任何顺序的式I重复单元的共聚物的组合物接触的组合物：其中Rf是直链或支链 具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，2至约15个碳原子的羟基亚烷基，-O （CnH2n） - ， - （CH2CF2）m（CH2）n-，-CONR1（CnH2n） - ， - （CnH2n）OCONR1（CnH2n） - ，（-CONR1CH2）2CH-，-SO2N（R1）（CnH2n） 或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，m各自独立地为1至约4，Z为氢 或甲基，x为正整数，y为零或正整数，t为正整数，M为H +，碱金属阳离子，碱土金属阳离子或 onium。
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公开(公告)号：US20090030114A1
公开(公告)日：2009-01-29
申请号：US11881129
申请日：2007-07-25
申请人： Ying Wang , Peter Michael Murphy , Sheng Peng
发明人： Ying Wang , Peter Michael Murphy , Sheng Peng
IPC分类号： C08K9/10 , C08F120/06
CPC分类号： C08F259/06 , C08F265/04 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/27 , D06M15/277 , D06M15/29 , D06M2200/11 , D06M2200/12 , C08F220/24
摘要： A core-shell emulsion polymer comprising A) a core composition comprising components (a) and (b): (a) from about 40 to about 95% of styrene, alkyl substituted styrene, or alkyl (meth)acrylate; and (b) from about 5 to about 60% of vinylidene chloride, vinyl chloride, or combinations thereof; and B) a shell composition components (c) and (d): (c) from about 50 to about 85% of (I) Rf1(CH2)m Z-C(O)—C(R1)═CH2 (II) Rf2(CH2CF2)q(CH2CH2)rZ-C(O)—C(R1)═CH2, or (III) Rf3O(CF2CF2)q(CH2CH2)rZ-C(O)—C(R1)═CH2 wherein R1 is hydrogen, Cl, F or CH3; Z is —O—, —NH— or —S—; Rf1 and Rf2 are each a C4 or C6 perfluoroalkyl; and Rf3 is a C2 to C7 perfluoroalkyl optionally interrupted by one to three ether oxygens; and (d) from about 15 to about 50% of styrene, alkyl substituted styrene, or alkyl (meth)acrylate, provided that i) the core composition comprises from about 20 to about 75% of the polymer; ii) when Rf1 or Rf2 has 4 carbons, R1 is CH3; and iii) when Rf3 has 2 or 3 carbons, R1 is CH3.
摘要翻译： 一种核 - 壳乳液聚合物，其包含A）包含组分（a）和（b）的核心组合物：（a）约40至约95％的苯乙烯，烷基取代的苯乙烯或（甲基）丙烯酸烷基酯; 和（b）约5至约60％的偏二氯乙烯，氯乙烯或其组合; （C）和（d）的壳组合物组分（c）约50-约85％的（I）Rf1（CH2）mZC（O）-C（R1）-CH2（Ⅱ）Rf2（ CH 2 CH 2）q（CH 2 CH 2）rZ-C（O）-C（R 1）-CH 2或（III）Rf 3 O（CF 2 CF 2）q（CH 2 CH 2）rZ-C（O） Cl，F或CH3; Z是-O - ， - NH-或-S-; Rf1和Rf2各自为C4或C6全氟烷基; 并且Rf 3是任选被一至三个醚氧中断的C2至C7全氟烷基; 和（d）约15至约50％的苯乙烯，烷基取代的苯乙烯或（甲基）丙烯酸烷基酯，条件是i）核组合物包含约20至约75％的聚合物; ii）当Rf1或Rf2具有4个碳时，R1是CH3; 和iii）当Rf 3具有2或3个碳时，R 1是CH 3。
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公开(公告)号：US07816005B2
公开(公告)日：2010-10-19
申请号：US12774979
申请日：2010-05-06
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
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