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公开(公告)号：US20090149096A1
公开(公告)日：2009-06-11
申请号：US12268470
申请日：2008-11-11
IPC分类号： B32B27/12 , B32B27/04 , B32B27/00 , C08F220/24
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的氟烷基单体或单体混合物，（b）约5％至约80％ ：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的非氟化可聚合纳米颗粒。
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公开(公告)号：US20090148653A1
公开(公告)日：2009-06-11
申请号：US12237446
申请日：2008-09-25
IPC分类号： B32B5/02 , C08L67/06 , C08L81/00 , C08L79/02 , D03D27/00 , B32B27/10 , C08L77/00 , C08L63/00 , C08L83/00
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, of formula (I) Rf1-L-X—C(O)—C(R)═CH2 (I) whereinRf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having from about 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least about 2:1 and no oxygen atoms are bonded to each other;L is a linear or branched divalent linking group having 1 to about 20 carbon atoms; optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting or —O—, —NR1—, —S—, —SO—, —SO2—, —N(R1)C(O)—; wherein R1 is H or C1 to C6 alkyl;X is —O—, —NR1—, or —S—;R is hydrogen, Cl, F or CH3; (b) from about 5% to about 80% of at least one of: (i) an alkyl(meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的氟代烷基单体或单体混合物<？在线公式描述=“In 线型式“end =”lead“→Rf1-LXC（O）-C（R）-CH2（I）<βin-line-formula description =”In-line Formulas“end =”tail“？>其中 Rf1是具有约2至约100个碳原子的单价，部分或完全氟化的直链或支链烷基; 任选地被1至约50个氧原子中断; 其中碳原子与氧原子的比例为至少约2:1且没有氧原子彼此键合; L是具有1至约20个碳原子的直链或支链二价连接基团; 任选地被1至大约4个选自以下的杂原子中断：-NR 1 - ， - S - ， - SO - ， - SO 2 - ， - N（R 1）C（O） - ; 其中R1是H或C1-C6烷基; X是-O-，-NR1-或-S-; R是氢，Cl，F或CH 3; （b）约5％至约80％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的可聚合纳米颗粒。
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公开(公告)号：US08314037B2
公开(公告)日：2012-11-20
申请号：US12268470
申请日：2008-11-11
CPC分类号： C08F220/24 , C08F2/44 , Y10T428/23986 , Y10T428/249921 , Y10T428/3154 , Y10T428/31993 , Y10T442/20 , Y10T442/2172
摘要： A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.
摘要翻译： 一种含氟聚合物组合物，其包含按以下重量百分比共聚的单体：（a）约20％至约95％的氟烷基单体或单体混合物，（b）约5％至约80％ ：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）一种或多种可离子化的水可溶性单体; 和（c）约0.05％至约2％的非氟化可聚合纳米颗粒。
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公开(公告)号：US07829477B2
公开(公告)日：2010-11-09
申请号：US11978290
申请日：2007-10-29
申请人： Peter Michael Murphy , Jessica Sinks , Ying Wang
发明人： Peter Michael Murphy , Jessica Sinks , Ying Wang
IPC分类号： B32B5/02
CPC分类号： C09D133/16 , C08F220/04 , C08F220/24 , C08F220/32 , C08F220/38 , C08F220/58 , Y10T428/23986 , Y10T428/31544 , Y10T442/2172 , Y10T442/2279 , Y10T442/2287
摘要： A method of providing water repellency, oil repellency, soil resistance, soil release, stain resistance and stain release to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula 1 in any sequence: wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 2 to about 15 carbon atoms, —O(CnH2n)—, —(CH2CF2)m(CH2)n—, —CONR1(CnH2n)—, —(CnH2n)OCONR1(CnH2n)—, (—CONR1CH2)2CH—, —SO2N(R1)(CnH2n)—, or —(CnH2n)SO2N(R1)(CnH2n)—, each R1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, Z is hydrogen or methyl, x is a positive integer, y is zero or a positive integer, t is a positive integer, and M is H+, alkali metal cation, alkaline earth metal cation, or ammonium.
摘要翻译： 提供防水性，拒油性，耐土壤性，污垢释放，耐污染性和对基材的污迹释放的方法，包括使所述底物与包含具有任何顺序的具有式1的重复单元的共聚物的组合物接触的组合物接触：其中Rf是直链或支链 具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，2至约15个碳原子的羟基亚烷基，-O （CnH2n） - ， - （CH2CF2）m（CH2）n-，-CONR1（CnH2n） - ， - （CnH2n）OCONR1（CnH2n） - ，（-CONR1CH2）2CH-，-SO2N（R1）（CnH2n） 或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，m各自独立地为1至约4，Z为氢 或甲基，x为正整数，y为零或正整数，t为正整数，M为H +，碱金属阳离子，碱 地球金属阳离子或铵。
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公开(公告)号：US20080202384A1
公开(公告)日：2008-08-28
申请号：US11712324
申请日：2007-02-28
申请人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
发明人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
CPC分类号： C08F214/18 , C08F214/186 , C08F220/18 , C08F220/24 , C08F220/28 , C08F220/58 , C09D133/16 , D06M15/263 , D06M15/267 , D06M15/277 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): Rf—(CH2CF2)q(CH2CH2)r-Z-C(O)—C(R)═CH2 (I) wherein q and r are each independently integers of 1 to 3; Rf is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR1— or —S—; R is hydrogen, Cl, F or CH3; R1 is hydrogen, or a C1 to C4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is as defined above; each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.
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公开(公告)号：US20110178260A1
公开(公告)日：2011-07-21
申请号：US12690674
申请日：2010-01-20
申请人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
发明人： Sheng Peng , Stephen James Getty , Patrick Henry Fitzgerald , Peter Michael Murphy , Ying Wang , Ernest Byron Wysong
IPC分类号： C08F220/22
CPC分类号： C08F220/24 , C08F2220/1891 , D06M15/263 , D06M15/267 , D06M15/277 , D06M15/295 , D06M2200/01 , C08F2220/1858 , C08F2220/281 , C08F220/58 , C08F2220/325 , C08F2220/286
摘要： A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): Rf—(CH2CF2)q(CH2CH2)r—Z—C(O)—C(R)═CH2 (I) wherein q and r are each independently integers of 1 to 3; Rf is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR1— or —S—; R is hydrogen, Cl, F or CH3; R1 is hydrogen, or a C1 to C4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is as defined above; each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.
摘要翻译： 包含按以下重量百分比共聚单体的组合物：（a）约20％至约95％的式（I）单体或单体混合物：Rf-（CH 2 CF 2）q（CH 2 CH 2）r-Z -C（O）-C（R）= CH 2（I）其中q和r各自独立地为1至3的整数; Rf是具有2-6个碳原子的直链或支链全氟烷基; Z是-O-，-NR1-或-S-; R是氢，Cl，F或CH 3; R1是氢或C1-C4烷基; 和（b）约5％至约80％的至少一种：（i）具有6至18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（ii）式（II）的单体：（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R定义同上; 每个R 2独立地为C 1至C 4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物; 所述组合物对与其接触的基材提供拒油性，拒水性和耐污染性; 和用这种共聚物组合物处理底物的方法; 被披露。
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公开(公告)号：US20090111344A1
公开(公告)日：2009-04-30
申请号：US11978290
申请日：2007-10-29
申请人： Peter Michael Murphy , Jessica Sinks , Ying Wang
发明人： Peter Michael Murphy , Jessica Sinks , Ying Wang
CPC分类号： C09D133/16 , C08F220/04 , C08F220/24 , C08F220/32 , C08F220/38 , C08F220/58 , Y10T428/23986 , Y10T428/31544 , Y10T442/2172 , Y10T442/2279 , Y10T442/2287
摘要： A method of providing water repellency, oil repellency, soil resistance, soil release, stain resistance and stain release to substrates comprising contacting said substrate with a composition comprising a copolymer having repeating units of Formula I in any sequence: wherein Rf is a straight or branched perfluoroalkyl group having from about 2 to about 8 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 2 to about 15 carbon atoms, —O(CnH2n)—, —(CH2CF2)m(CH2)n—, —CONR1(CnH2n)—, —(CnH2n)OCONR1(CnH2n)—, (—CONR1CH2)2CH—, —SO2N(R1)(CnH2n)—, or —(CnH2n)SO2N(R1)(CnH2n)—, each R1 is independently H or alkyl of 1 to about 4 carbon atoms, each n is independently 1 to about 15, each m is independently 1 to about 4, Z is hydrogen or methyl, x is a positive integer, y is zero or a positive integer, t is a positive integer, and M is H+, alkali metal cation, alkaline earth metal cation, or ammonium.
摘要翻译： 提供防水性，拒油性，耐土壤性，污垢释放，耐污染性和对底物的污迹释放的方法，包括使所述底物与包含具有以下任何顺序的式I重复单元的共聚物的组合物接触的组合物：其中Rf是直链或支链 具有约2至约8个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，Q为1至约15个碳原子的亚烷基，2至约15个碳原子的羟基亚烷基，-O （CnH2n） - ， - （CH2CF2）m（CH2）n-，-CONR1（CnH2n） - ， - （CnH2n）OCONR1（CnH2n） - ，（-CONR1CH2）2CH-，-SO2N（R1）（CnH2n） 或 - （C n H 2n）SO 2 N（R 1）（C n H 2n） - ，每个R 1独立地为H或1至约4个碳原子的烷基，每个n独立地为1至约15，m各自独立地为1至约4，Z为氢 或甲基，x为正整数，y为零或正整数，t为正整数，M为H +，碱金属阳离子，碱土金属阳离子或 onium。
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公开(公告)号：US20090030114A1
公开(公告)日：2009-01-29
申请号：US11881129
申请日：2007-07-25
申请人： Ying Wang , Peter Michael Murphy , Sheng Peng
发明人： Ying Wang , Peter Michael Murphy , Sheng Peng
IPC分类号： C08K9/10 , C08F120/06
CPC分类号： C08F259/06 , C08F265/04 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/27 , D06M15/277 , D06M15/29 , D06M2200/11 , D06M2200/12 , C08F220/24
摘要： A core-shell emulsion polymer comprising A) a core composition comprising components (a) and (b): (a) from about 40 to about 95% of styrene, alkyl substituted styrene, or alkyl (meth)acrylate; and (b) from about 5 to about 60% of vinylidene chloride, vinyl chloride, or combinations thereof; and B) a shell composition components (c) and (d): (c) from about 50 to about 85% of (I) Rf1(CH2)m Z-C(O)—C(R1)═CH2 (II) Rf2(CH2CF2)q(CH2CH2)rZ-C(O)—C(R1)═CH2, or (III) Rf3O(CF2CF2)q(CH2CH2)rZ-C(O)—C(R1)═CH2 wherein R1 is hydrogen, Cl, F or CH3; Z is —O—, —NH— or —S—; Rf1 and Rf2 are each a C4 or C6 perfluoroalkyl; and Rf3 is a C2 to C7 perfluoroalkyl optionally interrupted by one to three ether oxygens; and (d) from about 15 to about 50% of styrene, alkyl substituted styrene, or alkyl (meth)acrylate, provided that i) the core composition comprises from about 20 to about 75% of the polymer; ii) when Rf1 or Rf2 has 4 carbons, R1 is CH3; and iii) when Rf3 has 2 or 3 carbons, R1 is CH3.
摘要翻译： 一种核 - 壳乳液聚合物，其包含A）包含组分（a）和（b）的核心组合物：（a）约40至约95％的苯乙烯，烷基取代的苯乙烯或（甲基）丙烯酸烷基酯; 和（b）约5至约60％的偏二氯乙烯，氯乙烯或其组合; （C）和（d）的壳组合物组分（c）约50-约85％的（I）Rf1（CH2）mZC（O）-C（R1）-CH2（Ⅱ）Rf2（ CH 2 CH 2）q（CH 2 CH 2）rZ-C（O）-C（R 1）-CH 2或（III）Rf 3 O（CF 2 CF 2）q（CH 2 CH 2）rZ-C（O） Cl，F或CH3; Z是-O - ， - NH-或-S-; Rf1和Rf2各自为C4或C6全氟烷基; 并且Rf 3是任选被一至三个醚氧中断的C2至C7全氟烷基; 和（d）约15至约50％的苯乙烯，烷基取代的苯乙烯或（甲基）丙烯酸烷基酯，条件是i）核组合物包含约20至约75％的聚合物; ii）当Rf1或Rf2具有4个碳时，R1是CH3; 和iii）当Rf 3具有2或3个碳时，R 1是CH 3。
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公开(公告)号：US11378601B2
公开(公告)日：2022-07-05
申请号：US13877514
申请日：2011-10-07
申请人： Alessio Filippi , Ronald Rietman , Ying Wang , Ashish Vijay Pandharipande , Paul Anthony Shrubsole
发明人： Alessio Filippi , Ronald Rietman , Ying Wang , Ashish Vijay Pandharipande , Paul Anthony Shrubsole
IPC分类号： G01R19/25 , G01D4/00 , G01R21/133 , G01R35/00 , G06Q50/06 , H02J3/12 , H02J3/00 , H02J3/14 , H02J3/16
摘要： The invention relates to an operational state determination apparatus (1) for determining whether a variation in a determined electrical parameter of an electrical network (2) is caused by a variation in an operational state of an electrical consumer of the electrical network. The electrical network comprises multiple electrical consumers (3, 4, 5) and a voltage source (6), wherein a variation classification unit (10) determines whether a variation in the determined electrical parameter of the electrical network is caused by a variation in the operational state of an electrical consumer of the network depending on a decision variable which depends on a variation in a measured voltage and a variation in a measured current of the electrical network. This determination can be performed, without directly using the variation in the determined electrical parameter of the electrical network and is therefore less influenced by random voltage fluctuations in the electrical network.
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公开(公告)号：US20190212257A1
公开(公告)日：2019-07-11
申请号：US16327572
申请日：2017-04-10
申请人： Ying Wang , Yuqing Chang
发明人： Ying Wang , Yuqing Chang
CPC分类号： G01N21/3103 , G01N1/405 , G01N21/73 , G01N2223/076 , G01N2223/652
摘要： The present invention relates to a method of detecting one or more metals in as liquid sample. The method includes the step of extracting the metal from the liquid sample and retaining the metal on a binding material. The detection of the extracted metal can be performed with the metal retained on the binding material or alter the elution of the metal off the binding material.
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