Photosensitive recording element containing an ionic polymer
    3.
    发明授权
    Photosensitive recording element containing an ionic polymer 失效
    含有离子聚合物的感光记录元件

    公开(公告)号:US4916045A

    公开(公告)日:1990-04-10

    申请号:US330964

    申请日:1989-03-30

    摘要: The invention provides a novel photosensitive recording material in the shape of a multilayer element comprising(i) a photopolymerizable or photocrosslinkable relief-forming layer (RL) of a thickness from 0.1 to 6000 .mu.m and(ii) a dimensionally stable support layer.The said relief-forming layer (RL) consists essentially of an ionic polymer, of one or more photoinitiators and, if desired, of one or more photopolymerizable monomers.The said ionic polymer contains(A) from about 45 to 90% by weight, based on the ionic polymer, of a polymer main chain formed from an alkadiene polymer A',(B) from about 6 to about 45% by weight, based on the ionic polymer, of one or mored olefinically unsaturated side radicals having the structure (I), ##STR1## where R.sup.1 and R.sup.2 are different and are each H or a carbon atom of A',R.sup.3 is a polyvalent, straight-chain or branched C.sub.1 -C.sub.20 -alkylene radical whose chain or branches may be interrupted by --O--, --N-- or --S--,X is --O--, --S-- or --NH--,Y is a polar group,Z is --CH.sub.2 --, --O--, ##STR2## R.sup.4 is H or CH.sub.3, Q is --COOH or --COO.sup..crclbar.,m is an integer from 1 to 3, and(C) from about 0.5 to about 10% by weight, based on the ionic polymer, of cations selected from the group consisting of cations of elements of the main groups I to V, of the subgroups I to VIII and of the lanthanide series of the periodic table of elements, of ammonia, of polyfunctional organic amines, and of hydrazine.In addition, the said ionic polymer may contain further side radicals D which are not photopolymerizable.The novel photosensitive recording material is highly suited for the production of printing plates, relief plates and photoresists.

    摘要翻译: 本发明提供了一种多层元件形式的新型感光记录材料,其包括(i)厚度为0.1至6000μm的可光聚合或光致交联凸版形成层(RL)和(ii)尺寸稳定的支撑层。 所述浮雕形成层(RL)基本上由一种或多种光引发剂的离子聚合物组成,如果需要,由一种或多种光聚合单体组成。 所述离子聚合物含有(A)基于离子聚合物的约45至90重量%的由链烯二烯聚合物A',(B)形成的聚合物主链,基于约6至约45重量% 在离子聚合物上,具有结构(I)的一种或多种烯属不饱和侧基,其中R 1和R 2不同并且各自为H或A'的碳原子,R 3为多价直链 链或支链可以被-O-,-N-或-S-间隔的链或支链C1-C20亚烷基,X是-O - , - S-或-NH-,Y是极性基团, Z为-CH 2 - , - O - , - R 4为H或CH 3,Q为-COOH或-COO( - ),m为1至3的整数,(C)约0.5至约10% 选自基于离子聚合物的阳离子选自由亚组I至VIII中的主要组I至V的元素的阳离子和元素周期表的镧系元素的氨的阳离子 多官能有机胺和肼。 此外,所述离子聚合物可以含有不可光聚合的其它侧基D。 新型感光记录材料非常适用于生产印版,浮雕版和光致抗蚀剂。

    Continuous preparation of linear high molecular weight polyamides having
regulated amino and carboxyl end group content
    4.
    发明授权
    Continuous preparation of linear high molecular weight polyamides having regulated amino and carboxyl end group content 失效
    连续制备具有调节氨基和羧基端基含量的线性高分子量聚酰胺

    公开(公告)号:US5140098A

    公开(公告)日:1992-08-18

    申请号:US729787

    申请日:1991-07-10

    IPC分类号: C08G69/28

    CPC分类号: C08G69/28

    摘要: Linear high molecular weight polyamides containing a regulated level of amino and carboxyl end groups are prepared in a continuous process by reacting polyamides in the melt with polyamide-forming diamines or dicarboxylic acids by continuous mixing for a residence time of .ltoreq.10 minutes, granulating the polyamide, and further condensing the polyamide granules thus obtained in solid phase in the presence of inert gases until the viscosity has reached the desired level.

    摘要翻译: 通过使熔体中的聚酰胺与形成聚酰胺的二胺或二羧酸反应,通过连续混合10分钟的停留时间,制备含有调节氨基和羧基端基水平的线性高分子量聚酰胺,制粒 聚酰胺,并且在惰性气体的存在下,将由此获得的聚酰胺颗粒进一步冷凝,直到粘度达到所需水平。

    Salts of polyvalent cations with block polymers of vinylaromatics and
conjugated dienes
    5.
    发明授权
    Salts of polyvalent cations with block polymers of vinylaromatics and conjugated dienes 失效
    多价阳离子与乙烯基芳烃和共轭二烯的嵌段聚合物的盐

    公开(公告)号:US5003010A

    公开(公告)日:1991-03-26

    申请号:US420710

    申请日:1989-10-12

    IPC分类号: C08F8/42 C08F8/44 C08F297/04

    CPC分类号: C08F8/44

    摘要: Block polymers of vinylaromatics and conjugated dienes which posses acidic terminal groups and are in the form of salts which contain divalent or polyvalent metal cations or cation complexes. A process for the preparation of such salts of block polymers containing acid groups, and the use of these polymers as thermoplastic materials, as thermoplastic elastomers, for modifying thermoplastic materials, as viscosity index improvers in lubricating oils or as components in hot melt adhesives.

    摘要翻译: 乙烯基芳烃和共轭二烯的嵌段聚合物,其具有酸性端基并且为含有二价或多价金属阳离子或阳离子络合物的盐形式。 制备这种含酸基团的嵌段聚合物盐的方法,以及这些聚合物作为热塑性材料的热塑性弹性体用作改性热塑性材料,作为润滑油中的粘度指数改进剂或热熔粘合剂中的组分的用途。

    Ion implantation apparatus with a cooled structure controlling the
surface potential of a target surface
    6.
    发明授权
    Ion implantation apparatus with a cooled structure controlling the surface potential of a target surface 失效
    具有控制目标表面的表面电位的冷却结构的离子注入装置

    公开(公告)号:US4118630A

    公开(公告)日:1978-10-03

    申请号:US794275

    申请日:1977-05-05

    摘要: In an ion beam apparatus a structure for controlling the surface potential of the target comprising an electron source adjacent to the beam for providing electrons to the beam and means between the target and source for inhibiting rectilinear radiations, i.e., electron and other particle and photon radiations between said source and said target. This prevents heating of the target by the electron source and cross-contamination between the source and the target. The apparatus further includes means for maintaining said shield means at a lower temperature than said target. A further structure is provided for the measurement of the ion beam current while controlling said surface potential of the target which includes: walls adjacent to and electrically insulated from the target and surrounding the beam whereby the walls and target provide a Faraday Cage, means for introducing variable quantities of electrons into the beam within the Faraday Cage, means for measuring the target current, means for combining and measuring the target and wall currents to provide said ion beam current measurement and means for varying the quantities of introduced electrons to control the target current and thereby the target surface potential. Likewise, this apparatus further includes means for maintaining said shielding means at a temperature lower than said target.

    摘要翻译: 在离子束装置中,用于控制靶的表面电位的结构包括与光束相邻的电子源,用于向光束提供电子,并且用于抑制直线辐射的靶和源之间的装置,即电子和其它粒子和光子辐射 在所述源和所述目标之间。 这防止了电子源对靶的加热和源与靶之间的交叉污染。 该装置还包括用于将所述屏蔽装置保持在比所述目标低的温度的装置。 提供另外的结构用于测量离子束电流,同时控制靶的表面电位,其包括:与靶相邻并与靶电绝缘并围绕光束的壁,由此壁和靶提供法拉第笼,用于引入 可变量的电子进入法拉第笼内的光束,用于测量目标电流的手段,用于组合和测量目标和壁电流以提供所述离子束电流测量的装置,以及用于改变引入的电子的量以控制目标电流的装置 从而达到目标表面电位。 同样,该装置还包括用于将所述屏蔽装置保持在低于所述目标的温度的装置。

    Centrifugal support for workpieces
    7.
    发明授权
    Centrifugal support for workpieces 失效
    离心支持工件

    公开(公告)号:US3993018A

    公开(公告)日:1976-11-23

    申请号:US631013

    申请日:1975-11-12

    摘要: A chuck for a workpiece, rotatable in spaced relation to and about an axis of rotation, and having a clamp jaw radially movable under centrifugal force to engage the workpiece against fixed mating clamp members. The structure can also have optional means enabling the chuck to tilt, with the workpiece, from a home position to a preselected angle under the rotation thereof about a pivot axis perpendicular to and spaced from the axis of rotation with return of the chuck to the home position under gravitational force when rotation thereof is stopped.

    摘要翻译: 一种用于工件的卡盘,可以与旋转轴线间隔开并围绕旋转轴线旋转,并且具有可在离心力下径向移动的夹钳,以将工件接合固定的配合夹紧构件。 该结构还可以具有可选的装置,使得卡盘能够与工件一起从原始位置转动到其旋转周围的预定角度,该旋转轴线绕着旋转轴线垂直并与旋转轴线间隔开并且与卡盘回到家中 当转动停止时重力作用下的位置。

    Catalytic, solid state process for the preparation of linear polyamides
    8.
    发明授权
    Catalytic, solid state process for the preparation of linear polyamides 失效
    用于制备线性聚氨酯的催化,固态过程

    公开(公告)号:US5128442A

    公开(公告)日:1992-07-07

    申请号:US681255

    申请日:1991-04-08

    IPC分类号: C08G69/30 C08G69/28

    CPC分类号: C08G69/28

    摘要: A process for the preparation of a linear polyamide by reacting the appropriate dicarboxylic acid and diamine in a liquid reaction medium with the addition of a catalytically effective phosphorus compound, removing the reaction medium to give a solid salt, precondensing the latter in the solid phase at a temperature of from 140.degree. C. to 5.degree. C. below the melting point of the salt and continuing condensation at a temperature above that used for the precondensation until the desired degree of condensation is reached.

    摘要翻译: 通过在液体反应介质中使合适的二羧酸和二胺与添加催化有效的磷化合物反应来制备线性聚酰胺的方法,除去反应介质以得到固体盐,将固相的预冷凝 温度低于盐的熔点为140℃至5℃,并在高于用于预缩合直到达到所需缩合度的温度下继续冷凝。

    Salts of polyvalent cations of polymers of conjugated dienes
    9.
    发明授权
    Salts of polyvalent cations of polymers of conjugated dienes 失效
    共轭二烯聚合物的多价阳离子盐

    公开(公告)号:US4835221A

    公开(公告)日:1989-05-30

    申请号:US920078

    申请日:1986-10-17

    CPC分类号: C08C19/44

    摘要: Polymers and copolymers of conjugated dienes and aromatic vinyl compound which have a carboxyl end group and are present as salts, the salts containing metal cations or metal cation complexes which are bivalent or polyvallent and also a process for preparing such salts of polymers which contain carboxyl end groups and their use for modifying thermoplastic materials or as vulcanizable materials.

    摘要翻译: 具有羧基端基并以盐形式存在的共轭二烯和芳族乙烯基化合物的聚合物和共聚物,含有二价或多元醇的金属阳离子或金属阳离子络合物的盐,以及含有羧基末端的聚合物盐的制备方法 基团及其用于改性热塑性材料或作为可硫化材料的用途。