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86 条记录 (耗时 0.033 秒)

    Continuous in-situ combination process for upgrading heavy oil
    1.
    发明授权
    Continuous in-situ combination process for upgrading heavy oil 失效
    连续原位组合工艺提升重油

    公开(公告)号：US5695632A

    公开(公告)日：1997-12-09

    申请号：US433914

    申请日：1995-05-02

    申请人： Glen B. Brons ,  Ronald Myers ,  Roby Bearden, Jr.

    发明人： Glen B. Brons ,  Ronald Myers ,  Roby Bearden, Jr.

    IPC分类号： C10G53/12 ,  C10G19/00

    CPC分类号： C10G53/12

    摘要： The invention relates to an integrated, continuous process for the removal of organically bound sulfur (e.g., mercaptans, sulfides and thiophenes) comprising the steps of contacting a heavy oil, sodium hydroxide, hydrogen and water at a temperature of from about 380.degree. C. to 450.degree. C. to partially desulfurize the heavy oil and to form sodium sulfide, contacting said sodium sulfide with a transition metal in water to form a transition metal sulfide, sodium hydroxide and hydrogen. The sodium hydroxide is recirculated and the transition metal sulfide is removed. The partially desulfurized, dewatered heavy oil is treated with sodium metal under desulfurizing conditions, typically at a temperature of from about 340.degree. C. to about 450.degree. C., under a hydrogen pressure of at least about 50 psi to essentially desulfurize the oil, and form sodium sulfide. Optionally, the sodium salt generated can be regenerated to sodium metal using regeneration technology. The process advantageously produces essentially sulfur-free product oils having reduced nitrogen, oxygen and metals contents and reduced viscosity, density, molecular weight and heavy ends.

    摘要翻译： 本发明涉及用于去除有机结合硫（例如硫醇，硫化物和噻吩）的一体化连续方法，包括以下步骤：在约380℃的温度下使重质油，氢氧化钠，氢气和水接触。 将重硫部分地脱硫并形成硫化钠，使硫化钠与过渡金属在水中接触形成过渡金属硫化物，氢氧化钠和氢气。 将氢氧化钠再循环并除去过渡金属硫化物。 部分脱硫的脱水重油在脱硫条件下，通常在约340℃至约450℃的温度下，在至少约50psi的氢气压力下用金属钠处理以使油基本上脱硫， 并形成硫化钠。 任选地，所生成的钠盐可以使用再生技术再生成金属钠。 该方法有利地产生具有降低的氮，氧和金属含量以及降低的粘度，密度，分子量和重量的基本上无硫产品油。

    Process for the desulfurization of heavy oils and bitumens
    3.
    发明授权
    Process for the desulfurization of heavy oils and bitumens 有权
    重油和沥青脱硫工艺

    公开(公告)号：US07862708B2

    公开(公告)日：2011-01-04

    申请号：US12287744

    申请日：2008-10-14

    申请人： Michael Siskin ,  Rustom M. Billimoria ,  David W. Savage ,  Roby Bearden, Jr.

    发明人： Michael Siskin ,  Rustom M. Billimoria ,  David W. Savage ,  Roby Bearden, Jr.

    IPC分类号： C10G45/04

    CPC分类号： C10G45/02 ,  C10G19/02

    摘要： The present invention relates to a process for desulfurizing bitumen and other heavy oils such as low API gravity, high viscosity crudes, tar sands bitumen, or shale oils with alkali metal compounds under conditions to promote in-situ regeneration of the alkali metal compounds. The present invention employs the use of superheated water and hydrogen under conditions to improve the desulfurization and alkali metal hydroxide regeneration kinetics at sub-critical temperatures.

    摘要翻译： 本发明涉及一种在碱性金属化合物的原位再生条件下使沥青和其它重油如API重力低，高粘度原油，焦油砂沥青或页岩油脱硫的方法。 本发明使用过热水和氢气条件来改善亚临界温度下的脱硫和碱金属氢氧化物再生动力学。

    Integrated catalytic cracking and olefin producing process using staged backflow regeneration
    6.
    发明授权
    Integrated catalytic cracking and olefin producing process using staged backflow regeneration 失效
    综合催化裂化和烯烃生产过程使用分级回流再生

    公开(公告)号：US5447622A

    公开(公告)日：1995-09-05

    申请号：US154828

    申请日：1993-11-19

    申请人： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

    发明人： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

    IPC分类号： C10G11/18 ,  C10G57/00 ,  C10G51/06 ,  C07C1/00

    CPC分类号： C10G57/00 ,  C10G11/18

    摘要： Disclosed is a method which combines catalytic cracking and olefin production using a coked catalytic cracking catalyst as a dehydrogenation catalyst to dehydrogenate an alkane feed stream and form an olefin rich product stream. The method uses a staged backmixed regeneration system to form the dehydrogenation catalyst and to fully reactivate deactivated cracking catalyst for reuse in the cracking reaction. The catalyst preferably comprises a crystalline tetrahedral framework oxide component.

    摘要翻译： 公开了一种使用焦化催化裂化催化剂作为脱氢催化剂将催化裂化和烯烃生产组合以使烷烃进料流脱氢并形成富烯烃产物流的方法。 该方法使用分级回混再生系统形成脱氢催化剂，并在破裂反应中完全还原失活的裂化催化剂以供再利用。 催化剂优选包含结晶四面体骨架氧化物组分。

    Integrated fluid coking paraffin dehydrogenation process
    7.
    发明授权
    Integrated fluid coking paraffin dehydrogenation process 失效
    综合流体焦化石蜡脱氢工艺

    公开(公告)号：US5435905A

    公开(公告)日：1995-07-25

    申请号：US144984

    申请日：1993-10-27

    申请人： Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

    发明人： Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

    IPC分类号： C07C5/333 ,  C10G51/02 ,  C10G57/00 ,  C07C5/00

    CPC分类号： C10G57/00 ,  C07C5/3335 ,  C10G51/023

    摘要： An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to the scrubbing zone after first being reduced in temperature by introduction of an effective amount of diluent, such as steam. A light paraffin stream is introduced into this stream of hot solids between the point where the diluent is added and the scrubbing zone. The hot particles act to catalyze the dehydrogenation of paraffins to olefins.

    摘要翻译： 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 在通过引入有效量的稀释剂如蒸汽首先降低温度后，来自气化器的单独的热固体物流被传送到洗涤区。 在添加稀释剂的点和洗涤区之间，将轻质石蜡流引入该热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。

    Hydroconversion process using a sulfided molybdenum catalyst concentrate
    8.
    发明授权
    Hydroconversion process using a sulfided molybdenum catalyst concentrate 失效
    使用硫化钼催化剂浓缩物的加氢转化法

    公开(公告)号：US5039392A

    公开(公告)日：1991-08-13

    申请号：US532728

    申请日：1990-06-04

    申请人： Roby Bearden, Jr. ,  Clyde L. Aldridge

    发明人： Roby Bearden, Jr. ,  Clyde L. Aldridge

    IPC分类号： C10G47/26

    CPC分类号： C10G47/26

    摘要： A process for converting a heavy hydrocarbonaceous chargestock to lower boiling products which process comprises reacting the chargestock with a catalyst concentrate in the presence of hydrogen, at hydroconversion conditions, said catalyst concentrate having been prepared by the steps comprising: (a) forming a precursor catalyst concentrate by mixing together: (i) a hydrocarbonaceous oil comprising constituents boiling above about 1050.degree. F.; (ii) a metal compound, said metal being selected from the group consisting of Groups II, III, IV, V, VIB, VIIB, and VIII of the Periodic Table of the Elements, in an amount to provide from about 0.2 to 2 wt. % metal, based on said hydrocarbonaceous oil; (b) heating the precursor concentrate to an effective temperature to produce a catalyst concentrate, wherein elemental sulfur is used an a sulfiding agent in an amount such that the atomic ratio of sulfur to metal is from about 1/1 to 8/1.

    摘要翻译： 一种将重质含烃物料转化成较低沸点产物的方法，该方法包括在氢气存在下，在加氢转化条件下使所述原料与催化剂浓缩物反应，所述催化剂浓缩物已经通过以下步骤制备，所述步骤包括：（a）形成前体催化剂 通过混合在一起浓缩：（i）包含沸点高于约1050°F的组分的含烃油; （ii）金属化合物，所述金属选自元素周期表的第II，III，IV，V，VIB，VIIB和VIII族，其量为约0.2至2wt 。 基于所述烃油的％金属; （b）将前体浓缩物加热到有效温度以产生催化剂浓缩物，其中元素硫使用硫化剂，其量使得硫与金属的原子比为约1/1至8/1。