公开(公告)号：US5447622A

公开(公告)日：1995-09-05

申请号：US154828

申请日：1993-11-19

Applicant: Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

Inventor： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

IPC: C10G11/18 ,  C10G57/00 ,  C10G51/06 ,  C07C1/00

CPC classification number: C10G57/00 ,  C10G11/18

Abstract: Disclosed is a method which combines catalytic cracking and olefin production using a coked catalytic cracking catalyst as a dehydrogenation catalyst to dehydrogenate an alkane feed stream and form an olefin rich product stream. The method uses a staged backmixed regeneration system to form the dehydrogenation catalyst and to fully reactivate deactivated cracking catalyst for reuse in the cracking reaction. The catalyst preferably comprises a crystalline tetrahedral framework oxide component.

Abstract translation: 公开了一种使用焦化催化裂化催化剂作为脱氢催化剂将催化裂化和烯烃生产组合以使烷烃进料流脱氢并形成富烯烃产物流的方法。 该方法使用分级回混再生系统形成脱氢催化剂，并在破裂反应中完全还原失活的裂化催化剂以供再利用。 催化剂优选包含结晶四面体骨架氧化物组分。

公开(公告)号：US5435905A

公开(公告)日：1995-07-25

申请号：US144984

申请日：1993-10-27

Applicant: Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

Inventor： Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

IPC: C07C5/333 ,  C10G51/02 ,  C10G57/00 ,  C07C5/00

CPC classification number: C10G57/00 ,  C07C5/3335 ,  C10G51/023

Abstract: An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to the scrubbing zone after first being reduced in temperature by introduction of an effective amount of diluent, such as steam. A light paraffin stream is introduced into this stream of hot solids between the point where the diluent is added and the scrubbing zone. The hot particles act to catalyze the dehydrogenation of paraffins to olefins.

Abstract translation: 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 在通过引入有效量的稀释剂如蒸汽首先降低温度后，来自气化器的单独的热固体物流被传送到洗涤区。 在添加稀释剂的点和洗涤区之间，将轻质石蜡流引入该热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。

公开(公告)号：US5597474A

公开(公告)日：1997-01-28

申请号：US339109

申请日：1994-11-14

Applicant: Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis ,  LeRoy Clavenna

Inventor： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis ,  LeRoy Clavenna

IPC: C10B55/10 ,  C10G9/32 ,  C10J3/54 ,  C10G51/00

CPC classification number: C10J3/54 ,  C10B55/10 ,  C10G9/32 ,  C10J3/482 ,  C10J3/721 ,  C10K1/026 ,  C10K1/08 ,  C10J2200/09

Abstract: The present invention relates to an integrated fluid coking/hydrogen production process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to the scrubbing zone of the reactor. Methane and steam are introduced into the stream of hot solids passing from the gasifier to the scrubbing zone. The hot particles act to catalyze the conversion of methane to carbon monoxide and hydrogen in the presence of steam.

Abstract translation: 本发明涉及一体化流体焦化/氢生产方法。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 来自气化器的单独的热固体物流进入反应器的洗涤区。 将甲烷和蒸汽引入从气化器通向洗涤区的热固体物流中。 热颗粒起催化甲烷在蒸汽存在下转化为一氧化碳和氢气的作用。

公开(公告)号：US5472596A

公开(公告)日：1995-12-05

申请号：US194557

申请日：1994-02-10

Applicant: Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

Inventor： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

IPC: C07C5/327 ,  C10G9/32 ,  C10G9/28

CPC classification number: C10G9/32 ,  C07C5/327

Abstract: An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor and a heater with hot solids recycling between the coker reactor and the heater. A light paraffin stream is introduced into the line wherein the hot particles are recycled to the coking zone. The hot particles act to catalyze the dehydrogenation of the paraffins to olefins.

Abstract translation: 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流化焦化反应器和在焦化器反应器和加热器之间循环热固体的加热器组成。 将轻链烷烃流引入管线，其中热颗粒被再循环到焦化区。 热颗粒起催化链烷烃脱氢成烯烃作用。

公开(公告)号：US5414181A

公开(公告)日：1995-05-09

申请号：US154832

申请日：1993-11-19

Applicant: Roby Bearden, Jr. ,  Michael C. Kerby ,  Stephen M. Davis

Inventor： Roby Bearden, Jr. ,  Michael C. Kerby ,  Stephen M. Davis

IPC: C10G11/18 ,  C10G57/00 ,  C07C5/32 ,  C07C5/333 ,  C10G11/05

CPC classification number: C10G57/00 ,  C10G11/18

Abstract: Disclosed is a method which combines catalytic cracking and olefin production using a coked catalytic cracking catalyst to dehydrogenate an alkane feed stream and form an olefin rich product stream. Preferably, the coked catalytic cracking catalyst has a carbon content of about 0.2-10 wt. %. The catalyst preferably comprises a crystalline tetrahedral framework oxide component.

Abstract translation: 公开了一种使用焦化催化裂化催化剂将催化裂化和烯烃生产组合以使烷烃进料流脱氢并形成富烯烃产物流的方法。 优选地，焦化催化裂化催化剂的碳含量为约0.2-10重量％ ％。 催化剂优选包含结晶四面体骨架氧化物组分。

公开(公告)号：US5437782A

公开(公告)日：1995-08-01

申请号：US144969

申请日：1993-10-27

Applicant: Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

Inventor： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

IPC: C07C5/333 ,  C10G57/00 ,  C07C5/00

CPC classification number: C10G57/00 ,  C07C5/3335

Abstract: The present invention relates to an integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to a satellite reactor. A light paraffin stream is introduced into directly into this stream of hot solids passing to the satellite reactor or into the satellite reactor. The hot particles act to catalyze the dehydrogenation of the paraffins to olefins.

Abstract translation: 本发明涉及一体化流体焦化/石蜡脱氢方法。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 来自气化器的单独的热固体物流被传送到卫星反应器。 将轻链烷烃流直接引入到通过卫星反应器或卫星反应器的热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。

公开(公告)号：US5430217A

公开(公告)日：1995-07-04

申请号：US144972

申请日：1993-10-27

Applicant: Roby Bearden, Jr. ,  Michael C. Kerby ,  Stephen M. Davis

Inventor： Roby Bearden, Jr. ,  Michael C. Kerby ,  Stephen M. Davis

IPC: C10B55/10 ,  C10G51/02 ,  C10G57/00 ,  C07C4/02 ,  C07C1/00 ,  C10B55/00 ,  C10G51/06

CPC classification number: C10G51/023 ,  C10B55/10 ,  C10G57/00

Abstract: An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to the scrubbing zone or to a satellite fluidized reactor. A first stream containing an effective amount of C.sub.1 to C.sub.2 paraffins is introduced into this stream of hot solids between the point where the diluent is added and the scrubbing zone. The hot particles act to catalyze the dehydrogenation of paraffins to olefins. A second stream containing C.sub.3 to C.sub.10 paraffins is introduced downstream of the introduction of said first stream.

Abstract translation: 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 来自气化器的单独的热固体物流被传送到洗涤区或卫星流化反应器。 在添加稀释剂的点和洗涤区之间，将含有有效量的C1至C2链烷烃的第一物流引入该热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。 在引入所述第一流的下游引入含有C3至C10链烷烃的第二料流。

公开(公告)号：US5430216A

公开(公告)日：1995-07-04

申请号：US144971

申请日：1993-10-27

Applicant: Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

Inventor： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

IPC: C10B55/10 ,  C10G57/00 ,  C07C4/02 ,  C07C1/00 ,  C10B55/00 ,  C10G51/06

CPC classification number: C10B55/10 ,  C10G57/00

Abstract: An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is diluted with hot solids from the heater then passed to the scrubbing zone of the coker reactor. A light paraffin stream is introduced into this stream of hot solids between the point where the heater solids are introduced and the scrubbing zone. The hot particles act to catalyze the dehydrogenation of the paraffins to olefins.

Abstract translation: 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 将来自气化器的单独的热固体物流从加热器中用热固体稀释，然后通入焦化反应器的洗涤区。 在引入加热器固体的点和洗涤区之间，将轻质石蜡流引入该热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。

公开(公告)号：US08636976B2

公开(公告)日：2014-01-28

申请号：US13536159

申请日：2012-06-28

Applicant: Wieslaw J. Roth ,  Thomas Yorke ,  Michael C. Kerby ,  Simon C. Weston

Inventor： Wieslaw J. Roth ,  Thomas Yorke ,  Michael C. Kerby ,  Simon C. Weston

IPC: C01B39/46 ,  C01B39/48 ,  B01J29/70 ,  B01J29/72 ,  C07C5/02 ,  C07C5/10 ,  C07C5/52 ,  C07C2/66 ,  C07C2/86 ,  C07C5/41 ,  C07C4/06 ,  C07C7/13

CPC classification number: C01B39/46 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/7276 ,  B01J37/0009 ,  B01J2229/42 ,  C01B37/02 ,  C01B39/48 ,  C07C2/66 ,  C07C2/864 ,  C07C4/06 ,  C07C5/02 ,  C07C5/10 ,  C07C5/412 ,  C07C5/52 ,  C07C7/13 ,  C07C2529/70 ,  C07C2529/72 ,  C07C2529/74 ,  Y02P20/52 ,  Y10S208/02 ,  C07C15/085

Abstract: This invention relates to a crystalline molecular sieve having, in its as-synthesized form, an X-ray diffraction pattern including d-spacing maxima at 13.18±0.25 and 12.33±0.23 Angstroms, wherein the peak intensity of the d-spacing maximum at 13.18±0.25 Angstroms is at least as great as 90% of the peak intensity of the d-spacing maximum at 12.33±0.23 Angstroms. This invention also relates to a method of making thereof.

Abstract translation: 本发明涉及一种结晶分子筛，其以其合成形式具有包括在13.18±0.25和12.33±0.23埃处的d间距最大值的X射线衍射图，其中d间距最大值的峰值强度为13.18 ±0.25埃至少高达12.33±0.23埃处d间距最大峰值强度的90％。 本发明还涉及其制备方法。

公开(公告)号：US08524964B2

公开(公告)日：2013-09-03

申请号：US13026742

申请日：2011-02-14

Applicant: Wieslaw J. Roth ,  Jane C. Cheng ,  Mohan Kalyanaraman ,  Michael C. Kerby ,  Terry E. Helton

Inventor： Wieslaw J. Roth ,  Jane C. Cheng ,  Mohan Kalyanaraman ,  Michael C. Kerby ,  Terry E. Helton

IPC: C07C2/66

CPC classification number: C07C2/66 ,  B01J29/70 ,  B01J37/0009 ,  B01J2229/42 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/02 ,  C07C15/085 ,  C07C15/08

Abstract: This disclosure relates to a process for hydrocarbon conversion comprising contacting, under conversion conditions, a feedstock suitable for hydrocarbon conversion with a catalyst comprising an EMM-10 family molecular sieve.

Abstract translation: 本公开涉及一种烃转化方法，其包括在转化条件下将适于烃转化的原料与包含EMM-10族分子筛的催化剂接触。