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公开(公告)号：US6013176A
公开(公告)日：2000-01-11
申请号：US216573
申请日：1998-12-18
摘要： The invention relates to a process for demetallating a petroleum stream by contacting a metals-containing petroleum feed in the presence of a base selected from Group IA and IIA hydroxides and carbonates and ammonium hydroxide and carbonates and mixtures thereof an oxygen containing gas and a phase transfer agent at a temperature of up to 180.degree. C. for a time sufficient to produce a treated petroleum feed having a decreased metals content. The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries due to their metals, e.g., Ni and V content.
摘要翻译： 本发明涉及一种用于使含金属的石油原料在选自IAA和IIA氢氧化物的碱的存在下与碳酸盐和氢氧化铵和碳酸盐及其混合物与含氧气体和相转移 试剂在高达180℃的温度下持续足以产生具有降低的金属含量的经处理的石油进料的时间。 本发明提供了一种增强石油饲料价值的方法，其传统上由于其金属，例如Ni和V含量在炼油厂中的使用受限。
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公开(公告)号：US06488840B1
公开(公告)日：2002-12-03
申请号：US09551010
申请日：2000-04-18
IPC分类号： C10G2700
摘要： This invention relates to reducing the amount of thiols (mercaptans) in petroleum streams, specifically, mercaptans above the five carbon molecular weight range.
摘要翻译： 本发明涉及减少石油流中硫醇（硫醇）的量，特别是五碳分子量范围以上的硫醇。
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3.发明授权
公开(公告)号：US5965008A
公开(公告)日：1999-10-12
申请号：US771108
申请日：1996-12-20
CPC分类号： C10G32/02
摘要： The present invention provides for a method for decreasing the Conradson carbon content of petroleum streams by forming a mixture of the petroleum stream and an essentially aqueous electrolysis medium, and passing an electric current through the mixture at an anodic voltage and pH sufficient to produce a petroleum fraction having decreased Conradson carbon content. The anodic voltage is from +0.5 to +1.5V vs. SCE. Preferably the pH is acidic. The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries.
摘要翻译： 本发明提供了一种通过形成石油流和基本上含水的电解介质的混合物并使电流以足以产生石油的阳极电压和pH的电流通过混合物来降低石油流的康拉多森碳含量的方法 Conradson碳含量降低。 与SCE相比，阳极电压为+0.5至+ 1.5V。 优选pH为酸性。 本发明提供了一种提高石油饲料价值的方法，该方法传统上在炼油厂中使用有限。
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公开(公告)号：US5817228A
公开(公告)日：1998-10-06
申请号：US771107
申请日：1996-12-20
IPC分类号： C10G32/02
CPC分类号： C10G32/02
摘要： The invention is a method for demetallating petroleum streams by subjecting a hydrocarbon soluble metals-containing petroleum stream and an aqueous electrolysis medium to a sufficient anodic potential at a pH sufficient to produce a treated petroleum stream having a decreased metals content. The invention is useful for enhancing the value of petroleum streams that traditionally have limited use in refineries due to their content of metals, particularly Ni and V.
摘要翻译： 本发明是一种通过在足以产生具有降低的金属含量的经处理的石油流的pH下对含烃可溶性金属的石油物流和含水电解介质进行足够的阳极电位来脱金属石油流的方法。 本发明对于提高由于其金属含量，特别是Ni和V而在炼油厂中传统使用有限的石油流的价值是有用的。
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5.发明授权Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US08529752B2
公开(公告)日：2013-09-10
申请号：US13327403
申请日：2011-12-15
申请人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
发明人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
IPC分类号： B01J29/70 , C07C5/02 , C07C5/10 , C07C5/52 , C07C2/66 , C07C2/86 , C07C5/41 , C07C4/06 , C07C7/13 , B01J29/72
CPC分类号： B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
摘要： This invention relates to a process for hydrocarbon conversion comprising contacting a hydrocarbon feedstock with a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, under conversion conditions to form a conversion product, said crystalline molecular sieve comprising unit cells with MWW topology and is characterized by diffraction streaking from the unit cell arrangement in the c direction as evidenced by the arced hk0 patterns of electron diffraction pattern.
摘要翻译： 本发明涉及烃转化方法，其包括在转化条件下使烃原料与其结晶分子筛以其铵交换形式或其煅烧形式接触以形成转化产物，所述结晶分子筛包含具有MWW拓扑结构的单元电池 并且其特征在于沿c方向的单元电池布置的衍射条纹，其特征在于电子衍射图案的弧形hk0图案证明。
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6.发明申请Molecular Sieve Composition (EMM-10), Its Method of Making, and Use for Hydrocarbon Conversions 有权分子筛组成（EMM-10），其制备和用于烃转化的方法公开(公告)号：US20120226084A1
公开(公告)日：2012-09-06
申请号：US13327403
申请日：2011-12-15
申请人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
发明人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
IPC分类号： C07C2/66
CPC分类号： B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
摘要： This invention relates to a process for hydrocarbon conversion comprising contacting a hydrocarbon feedstock with a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, under conversion conditions to form a conversion product, said crystalline molecular sieve comprising unit cells with MWW topology and is characterized by diffraction streaking from the unit cell arrangement in the c direction as evidenced by the arced hk0 patterns of electron diffraction pattern.
摘要翻译： 本发明涉及烃转化方法，其包括在转化条件下使烃原料与其结晶分子筛以其铵交换形式或其煅烧形式接触以形成转化产物，所述结晶分子筛包含具有MWW拓扑结构的单元电池 并且其特征在于沿c方向的单元电池布置的衍射条纹，其特征在于电子衍射图案的弧形hk0图案证明。
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7.发明授权Two stage process for hydrodesulfurizing distillates using bulk multimetallic catalyst 有权使用大量多金属催化剂加氢脱硫馏分的两阶段方法公开(公告)号：US06929738B1
公开(公告)日：2005-08-16
申请号：US09869981
申请日：2000-01-14
申请人： Kenneth Llyod Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
发明人： Kenneth Llyod Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
IPC分类号： C01G53/00 , B01J23/00 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/888 , B01J37/03 , B01J37/08 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G47/12 , C10G49/04 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G45/04
CPC分类号： C08F8/00 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： A two stage hydrodesulfurizing process for producing low sulfur distillates. A distillate boiling range feedstock containing in excess of about 3,000 wppm sulfur is hydrodesulfurized in a first hydrodesulfurizing stage containing one or more reaction zones in the presence of hydrogen and a hydrodesulfurizing catalyst. The liquid product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid product stream, which has a substantially lower sulfur and nitrogen content then the original feedstream is passed to a second hydrodesulfurizing stage also containing one or more reaction zones where it is reacted in the presence of hydrogen and a second hydrodesulfurizing catalyst at hydrodesulfurizing conditions. The catalyst in any one or more reaction zones is a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种用于生产低硫馏分的二级加氢脱硫方法。 在含氢和加氢脱硫催化剂的情况下，在含有一个或多个反应区的第一加氢脱硫阶段，加氢脱硫含有超过约3,000wppm硫的馏出物沸程原料。 将其液体产物流送入其中产生气相产物流和液体产物流的第一分离阶段。 具有基本上较低的硫和氮含量的液体产物流然后原始进料流被传递到还含有一个或多个反应区的第二加氢脱硫阶段，其中它在氢气和第二加氢脱硫催化剂的存在下在加氢脱硫条件下反应。 任何一个或多个反应区中的催化剂是由至少一种VIII族非贵金属和至少两种VIB族金属组成的大量多金属催化剂。
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8.发明授权Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US08110176B2
公开(公告)日：2012-02-07
申请号：US11824742
申请日：2007-07-02
申请人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
发明人： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
CPC分类号： B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
摘要： This invention relates to a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, comprising unit cells with MWW topology, said crystalline molecular sieve is characterized by diffraction streaking from the unit cell arrangement in the c direction. The crystalline molecular sieve is further characterized by the arced hk0 patterns of electron diffraction pattern. The crystalline molecular sieve is further characterized by the unit cells streaking along c direction. This invention also relates to a method of making thereof.
摘要翻译： 本发明涉及以铵交换形式或其煅烧形式的包含具有MWW拓扑结构的单元电池的结晶分子筛，所述结晶分子筛的特征在于沿c方向从单元电池排列衍射衍射。 结晶分子筛的特征还在于电子衍射图案的弧形hk0图案。 结晶分子筛的特征还在于沿c方向分布的单位细胞。 本发明还涉及其制备方法。
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公开(公告)号：US06582590B1
公开(公告)日：2003-06-24
申请号：US09869982
申请日：2001-08-22
申请人： Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
发明人： Kenneth Lloyd Riley , Darryl Patrick Klein , Zhiguo Hou , Stuart Leon Soled , Michael Charles Kerby , Gary Brice McVicker , Edward Stanley Ellis , Michele Sue Touvelle , Sabato Miseo
IPC分类号： C10G4500
CPC分类号： B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
摘要： Sulfur content of distillate feedstock, which is greater than 3,000 wppm, is reduced using multi-stage hydrodesulfurization by reacting the feestream in stages with reaction zone(s) containing bulk multimetallic catalyst comprised of Group VIII non-noble metal(s) and at least two group VIB metals. The ratio of Group VIB to Group VIII non-noble metals is 10:1 to 1:10.
摘要翻译： 通过使用多级加氢脱硫，通过使包含阶段的发泡与包含第VIII族非贵金属的多体金属催化剂和至少包含第一组的多元金属催化剂的反应区反应来减少大于3,000wppm的馏出物原料的硫含量 两组VIB金属。 VIB族与VIII族非贵金属的比例为10：1〜1:10。
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10.发明申请Molecular Sieve Composition (EMM-10-P), Its Method of Making, and Use for Hydrocarbon Conversions 有权分子筛组成（EMM-10-P），其制备和用于烃转化的方法公开(公告)号：US20120269718A1
公开(公告)日：2012-10-25
申请号：US13536159
申请日：2012-06-28
IPC分类号： C01B39/48
CPC分类号： C01B39/46 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J37/0009 , B01J2229/42 , C01B37/02 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , Y02P20/52 , Y10S208/02 , C07C15/085
摘要： This invention relates to a crystalline molecular sieve having, in its as-synthesized form, an X-ray diffraction pattern including d-spacing maxima at 13.18±0.25 and 12.33±0.23 Angstroms, wherein the peak intensity of the d-spacing maximum at 13.18±0.25 Angstroms is at least as great as 90% of the peak intensity of the d-spacing maximum at 12.33±0.23 Angstroms. This invention also relates to a method of making thereof.
摘要翻译： 本发明涉及一种结晶分子筛，其以其合成形式具有包括在13.18±0.25和12.33±0.23埃处的d间距最大值的X射线衍射图，其中d间距最大值的峰值强度为13.18 ±0.25埃至少高达12.33±0.23埃处d间距最大峰值强度的90％。 本发明还涉及其制备方法。
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