摘要:
The present invention relates to a cracking catalyst composition for cracking heavy hydrocarbon and processes for preparing the catalyst. The process can include treating zeolite with sodium free basic compound with or without phosphate, treating an alumina with a dilute acid, acidifying a colloidal silica, preparing a fine slurry of clay with a source of phosphate, adding alumina slurry and/or acidified colloidal silica to clay phosphate slurry, adding treated zeolite and spray-drying the slurry and calcining the same to obtain a cracking catalyst having adequate ABD and attrition resistance property.
摘要:
The present invention relates to a cracking catalyst composition for cracking heavy hydrocarbon and processes for preparing the catalyst. The process can include treating zeolite with sodium free basic compound with or without phosphate, treating an alumina with a dilute acid, acidifying a colloidal silica, preparing a fine slurry of clay with a source of phosphate, adding alumina slurry and/or acidified colloidal silica to clay phosphate slurry, adding treated zeolite and spray-drying the slurry and calcining the same to obtain a cracking catalyst having adequate ABD and attrition resistance property.
摘要:
The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.
摘要:
The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.
摘要:
The present disclosure provides a ready-to-use seed composition water, a source of silica, a source of alumina, and Na20, wherein the molar ratio of H20:Na20 ranges from 5 to 20, Na20:SiO2 ranges from 0.4 to 5 and SiO2:Al203 ranges from 1.3 to 5 used in the preparation of a synthetic faujasite zeolite which has high thermal stability and higher crystallite size. It further provides a process for preparing the ready-to-use seed composition for preparation of synthetic faujasite zeolite that requires lower crystallization time. The present disclosure provides a seed composition that does not require maturing time and a reaction gel composition that has low water and soda content. The present disclosure further provides a process for the preparation of synthetic faujasite zeolite by blending seed and reaction gel reaction composition to form a seed gel composition and subjecting it to crystallization.
摘要:
The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour−1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.
摘要:
A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 440 to 520° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a hydrocarbon fraction having a boiling point in the range of 380 to 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 460 to 540° C., pressure in the range of 2 to 20 kg/cm2 in presence of added quantity of steam for formation of a mesophase carbonaceous structure which on steam stripping and cooling forms a solid crystalline coke suitable for manufacturing of graphite electrode of large diameter having co-efficient of thermal expansion lower than 1.1×10−6/° C. measured on graphite artifact in the temperature range of 25 to 525° C.
摘要:
A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 440 to 520° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a hydrocarbon fraction having a boiling point in the range of 380 to 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 460 to 540° C., pressure in the range of 2 to 20 kg/cm2 in presence of added quantity of steam for formation of a mesophase carbonaceous structure which on steam stripping and cooling forms a solid crystalline coke suitable for manufacturing of graphite electrode of large diameter having co-efficient of thermal expansion lower than 1.1×10−6/° C. measured on graphite artifact in the temperature range of 25 to 525° C.
摘要翻译:公开了一种用于从具有不超过0.7重量%的硫的重大气压蒸馏残余物生产针状焦炭的方法,该方法包括将原料加热至440-520℃范围内的温度以进行浸泡中的热裂解 柱在1至10kg / cm 2范围内的压力下分离易分解的易吸收材料,将裂化产物在骤冷塔和蒸馏塔中分离,然后将来自底部的烃馏分 骤冷塔和具有沸点在380-480℃范围内的沸点在380-480℃范围内的烃馏分和/或任何其它合适的较重的烃流以一定的比例取决于某些特征参数与第二次均热中的热裂解 在460至540℃的温度下,在存在用于形成中间相碳质结构的添加量的蒸汽的存在下,在2至20kg / cm 2范围内的压力,其中 在蒸汽汽提和冷却时,形成适用于制造热膨胀系数小于1.1×10 -6 /℃的大直径石墨电极的固体结晶焦炭,其温度在石墨伪影上测量 范围为25至525℃
摘要:
The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2(g) and weight hourly space velocity in range of 0.1 to 20 hour−1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.
摘要翻译:本发明涉及一种将95%真实沸点低于400℃的烃流转化成非常高产率的进料和高辛烷值汽油的45-65重量%的液化石油气的方法, 所述方法包括使用固体可流化催化剂催化裂化烃,所述固体可流化催化剂包含具有或不具有Y-沸石的中孔结晶铝硅酸盐,非结晶酸性物质或其组合,其在400至550℃的温度范围内操作的流化密床反应器 ℃,压力范围为2至20kg / cm 2(g),重时空速为0.1至20小时的范围,其中所述致密的 床反应器与催化剂汽提器和再生器流动连通,用于在存在空气和/或含氧气体的情况下连续再生焦化催化剂,催化剂在反应器 - 再生器系统之间连续循环。
摘要:
A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 460 to 540° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a heavy gas oil fraction having 10% true boiling point more than 370° C. and 90% true boiling point not less than 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 440 to 520° C., pressure in the range of 2 to 20 kg/cm2 in presence of added quantity of steam for formation of a mesophase carbonaceous structure which on steam stripping and cooling forms a solid crystalline coke suitable for manufacturing of graphite electrode of large diameter having co-efficient of thermal expansion lower than 1.1×10−6/° C. measured on graphite artifact in the temperature range of 25 to 525° C.
摘要翻译:公开了一种用于从具有不超过0.7重量%的硫的重大气压蒸馏残余物生产针状焦炭的方法,该方法包括将原料加热至在460至540℃范围内的温度以进行浸泡中的热裂解 柱在1至10kg / cm 2范围内的压力下分离易分解的易溶材料,将裂化产物在骤冷塔和蒸馏塔中分离,然后将来自底部的烃馏分 淬火塔和具有10%真实沸点大于370℃的重质瓦斯油馏分和来自蒸馏塔和/或任何其它合适的较重烃流的确定的90%真实沸点不低于480℃ 的比例取决于某些特征参数与第二均热塔中的热裂解在440至520℃的温度下,在2至20kg / cm 2范围内的压力,在加入量 蒸汽格式化 n的中间相碳质结构,其在蒸汽汽提和冷却时形成适于制造热膨胀系数小于1.1×10 -6 /℃的大直径石墨电极的固体结晶焦炭。 在25至525℃的温度范围内测量石墨伪影。