摘要:
The present invention provides a curable resin composition incorporating an oligomer containing blocked hydroxyl group, an epoxy-group containing compound, hydrolytic silyl-group containing compound, and a dissociation catalyst and/or curing catalyst, each possessing a specific molecular weight; a paint which uses this resin composition as a binder; and a coat-finishing method which coat-finishes any desired material using the aforementioned resin composition and paint. According to the present invention, it is possible to reduce viscosity, and consequently increase the coat non-volatile content and hence improve acid resistance, abrasion resistance, and the like. In addition, according to the present invention, it is possible to obtain a curable resin composition, paint using this curable resin composition, and coat-finishing method for this paint in which the aforementioned resin and paint have an extremely high utility and possess a high solid content wherein air bubbles and drip-runs are not generated.
摘要:
The present invention relates to a low solvent content type-coating composition which provides the resultant coating with improved surface appearance, acid resistance, alkali resistance, weathering resistance, scuff resistance and solvent resistance, while the content of an organic solvent of the coating composition can be much reduced to 0 to 30% at 25.degree. C. The low solvent content type-coating composition comprises a vinyl oligomer having a blocked carboxyl group and an additional group selected from an epoxy group, a silanol group, a hydrolyzable silyl group and an acid anhydride group. The vinyl oligomer has a number average molecular weight (Mn) of 600 to 2000, a weight average molecular weight (Mw) of 600 to 5000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1.0 to 2.5. The blocked carboxyl group and an additional group may be present in the same or different vinyl oligomers.
摘要:
The present invention relates to a low solvent content-type resin composition, a low solvent content-type coating composition containing such a resin composition as a binder, and a method for coating such a coating composition. The resin composition comprises an oligomer containing an alicyclic epoxy group in a molecule and having a number average molecular weight (Mn) of 300 to 2000, a weight average molecular weight (Mw) of 300 to 4000 and an Mw/Mn ratio of 1 to 2.5. The coating composition comprises such a resin composition and a cationic polymerization catalyst, wherein the content of an organic solvent content is 0 to 40 wt. %. Since the present composition contains a low molecular weight oligomer, the viscosity of the composition is low even though the solid content is high. Accordingly, the content of the organic solvent can be much reduced.
摘要:
The present invention is to provide a low solvent content type-coating composition by which the resultant coatings with good scuff resistance or water resistance as well as good chipping resistance are produced, while the content of an organic solvent to be used can be much reduced. The low solvent content type-coating composition comprises a polyester oligomer having a hydroxyl group in an amount of 2.0 to 10.0 moles/Kg-resin, a number average molecular weight (Mn) of 300 to 1500, a weight average molecular weight (Mw) of 300 to 3000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1 to 2.0, an amount of a modifying lactone being 31 to 85%, and an aliphatic hydrocarbon group of C4-22 which is not derived from lactones. The present invention is also to provide a process for coating a low solvent content type-coating composition on, for example, a base coating composition by a wet-on-wet coating. The base coating composition comprises a vinyl oligomer having a hydroxyl group and/or a blocked hydroxyl group, a melamine resin containing 50 to 100% of an imino type or methylol type mononucleus melamine and a weak acidic curing catalyst.
摘要:
An electrochemical energy generation device includes an electrochemical device such as a fuel cell having an electrolyte film arranged between an anode and a cathode and a reference electrode maintained at an oxidation-reduction potential between an metal and a metal ion and arranged in contact with the electrolyte film. The electrochemical energy generation device is operated by measuring a potential of the anode and the cathode based on the reference electrode, deciding the operation condition such as a fuel supply amount to the electrochemical device according to the result of the potential measurement of the anode and the cathode, and selling the operation condition such as the fuel supply amount according to the decision, by an operation condition setting unit. An operation method of the device and an electrochemical device constituting the device are also provided.
摘要:
A power supply system is provided that includes a fuel cell as its energy source and has not only high energy density but also high power density and can respond to sharp change in the power consumption with simple means. In a power supply system, a fuel cell is connected to the input terminal of a DC/DC converter, and a lithium-ion secondary battery and a load are connected to the output terminal in parallel. A voltage measurement device that measures the terminal voltage of the secondary battery and a control microcomputer that sets the target output voltage of the converter are provided, and the target output voltage is set slightly higher than the terminal voltage. The fuel cell is operated within a power generation condition offering the highest fuel conversion efficiency.
摘要:
A power supply system is provided that includes a fuel cell as its energy source and has not only high energy density but also high power density and can respond to sharp change in the power consumption with simple means. In a power supply system, a fuel cell is connected to the input terminal of a DC/DC converter, and a lithium-ion secondary battery and a load are connected to the output terminal in parallel. A voltage measurement device that measures the terminal voltage of the secondary battery and a control microcomputer that sets the target output voltage of the converter are provided, and the target output voltage is set slightly higher than the terminal voltage. The fuel cell is operated within a power generation condition offering the highest fuel conversion efficiency. Due to this configuration, the system composed of the fuel cell and the converter functions like a constant voltage/current source that outputs the power generated by the fuel cell with the voltage equal to the terminal voltage of the secondary battery. The excess/deficiency of this output current with respect to the current for driving the load is automatically adjusted by the charge/discharge of the secondary battery.
摘要:
The objective of the present invention is to provide a concrete composition in which the amount of air entrained can be maintained stably and which is excellent in strength and durability, a concrete composition which is excellent in freeze-thaw durability owing to the good quality of foams and is excellent in air content stability with time and which can form curing products excellent in strength and durability, a method of producing such concrete composition, and a cement admixture.
摘要:
A fuel cell and an electronic device equipped therewith are disclosed. The fuel cell is of the type having a cathode and an anode facing each other with a proton conductor interposed therebetween, with at least either of the cathode or anode having an enzyme as a catalyst immobilized thereon, wherein at least a first cathode, a first proton conductor, an anode, a second proton conductor, and a second cathode are sequentially placed thereon, and in fuel is held in contact with at least part of the anode.
摘要:
There is provided: a (meth)acrylic acid (salt) polymer which has high properties and is little colored; and a process which can produce this polymer with a high polymerization conversion without causing the corrosion of the reaction vessel. When a (meth)acrylic acid (salt) polymer is obtained by carrying out polymerization of an unsaturated monocarboxylic monomer (a) and an unsaturated polyalkylene glycolic monomer (b) with a polymerization initiator, either a redox polymerization initiator including hydrogen peroxide and a reducing agent is used as the polymerization initiator in a specific amount, or the unsaturated polyalkylene glycolic monomer is subjected to the polymerization in the form of an esterification reaction product as obtained by a process including the steps of: esterifying the unsaturated monocarboxylic monomer and a polyalkylene glycol in a specific charging ratio in the presence of an acid catalyst in a manner for a portion of the residual unsaturated monocarboxylic monomer as a starting raw material to remain; and then neutralizing the acid catalyst and the residual unsaturated monocarboxylic monomer (a) with a basic substance after the esterification; and the polymerization is carried out under conditions where the pH during the polymerization is in the range of 3.2 to 7.0.