Aminoplast curable compositions containing disulfonic acid esters as
latent acid catalysts
    9.
    发明授权
    Aminoplast curable compositions containing disulfonic acid esters as latent acid catalysts 失效
    含有二磺酸酯作为潜酸催化剂的氨基塑料可固化组合物

    公开(公告)号:US4501854A

    公开(公告)日:1985-02-26

    申请号:US551388

    申请日:1983-11-14

    CPC分类号: C07C309/00 C08K5/42

    摘要: An improved curable composition capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent and a sulfonate as latent acid catalyst. The catalyst is represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, hydroxyl, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, and C.sub.6 to C.sub.18 aryl;R.sup.1 is independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, hydroxyalkyl, and hydroxycycloalkyl;y is an integer from 0 to 4,w is an integer from 0 to 2, andx is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 3.

    摘要翻译: 能够进行酸催化交联的改进的可固化组合物由含活性氢的树脂,固化剂和作为潜酸催化剂的磺酸盐组成。 催化剂由以下结构式表示:其中:Z是独立地选自C 1至C 20烷基,C 3至C 20环烷基,C 6至C 18芳基,卤素,烷氧基,羟基和芳氧基的基团; R独立地选自氢,C1至C20烷基,C3至C20环烷基和C6至C18芳基; R 1独立地选自C 1至C 20烷基,C 3至C 20环烷基,羟基烷基和羟基环烷基; y是0至4的整数,w是0至2的整数,x是1至3的整数,条件是当w为0时,y为1至4的整数,x为整数 2〜3,y为0时,w为1〜2的整数,x为1〜3的整数。

    Aromatic acid catalysts providing improved humidity resistance
    10.
    发明授权
    Aromatic acid catalysts providing improved humidity resistance 失效
    提供改善的耐湿性的芳香族酸催化剂

    公开(公告)号:US4500680A

    公开(公告)日:1985-02-19

    申请号:US551389

    申请日:1983-11-14

    CPC分类号: C08K5/42

    摘要: Curable compositions with improved humidity resistance are composed of an active hydrogen-containing resin which is essentially free of glycidyl groups, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a sulfonic acid having a molecular weight of less than 500 and represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl and C.sub.6 to C.sub.18 aryl;y is an integer from 0 to 4; w is an integer from 0 to 2;x is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 2.

    摘要翻译: 具有改善的耐湿性的可固化组合物由基本上不含缩水甘油基的活性含氢树脂,外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂和催化量的磺酸 分子量小于500并由以下结构式表示的酸:其中:Z是独立地选自C 1至C 20烷基,C 3至C 20环烷基,C 6至C 18芳基,卤素,烷氧基和芳氧基 ; R独立地选自氢,C1至C20烷基,C3至C20环烷基和C6至C18芳基; y为0〜4的整数; w为0〜2的整数; x为1〜3的整数,条件是当w为0时,y为1〜4的整数,x为2〜3的整数,y为0时,w为1〜2的整数, x是1到2的整数。