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1.发明授权Precatalyzed catalyst compositions, process for preparing epoxy resins, curable compositions, articles resulting from curing the resultant compositions 失效预催化剂组合物，制备环氧树脂的方法，可固化组合物，由固化所得组合物得到的制品
公开(公告)号：US5360886A
公开(公告)日：1994-11-01
申请号：US144983
申请日：1993-10-27
CPC分类号： B01J31/0268 , B01J31/0267 , C08G59/688
摘要： The reaction between epoxy compounds and active hydrogen-containing compounds or anhydrides is catalyzed with a phosphine or phosphonium compound containing at least three C.sub.1 to C.sub.4 alkyl phenyl groups attached to the phosphorous atom per molecule.
摘要翻译： 环氧化合物和含活性氢的化合物或酸酐之间的反应用每分子连接至磷原子上至少三个C1-C4烷基苯基的膦或鏻化合物催化。
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2.发明授权Precatalyzed catalyst compositions, process for preparing epoxy resins curable compositions, articles resulting from curing the resultant compositions 失效预催化催化剂组合物，制备环氧树脂可固化组合物的方法，固化所得组合物得到的制品
公开(公告)号：US5202407A
公开(公告)日：1993-04-13
申请号：US825466
申请日：1992-01-24
CPC分类号： B01J31/0268 , B01J31/0267 , C08G59/688
摘要： The reaction between epoxy compounds and active hydrogen-containing compounds or anhydrides is catalyzed with a phosphine or phosphonium compound containing at least three C.sub.1 to C.sub.4 alkyl phenyl groups attached to the phosphorus atom per molecule.
摘要翻译： 环氧化合物和含活性氢的化合物或酸酐之间的反应用含有每分子连接到磷原子上的至少三个C1-C4烷基苯基的膦或鏻化合物催化。
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3.发明授权Precatalyzed catalyst compositions, process for preparing resins, curable compositions, articles resulting from curing the resultant compositions 失效预催化剂组合物，制备树脂的方法，可固化组合物，由固化所得组合物得到的制品
公开(公告)号：US5310853A
公开(公告)日：1994-05-10
申请号：US6876
申请日：1993-01-21
CPC分类号： B01J31/0268 , B01J31/0267 , C08G59/688
摘要： The reaction between epoxy compounds and active hydrogen-containing compounds or anhydrides is catalyzed with a phosphine or phosphonium compound containing at least three C.sub.1 to C.sub.4 alkyl phenyl groups attached to the phosphorous atom per molecule.
摘要翻译： 环氧化合物和含活性氢的化合物或酸酐之间的反应用每分子连接至磷原子上至少三个C1-C4烷基苯基的膦或鏻化合物催化。
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公开(公告)号：US20080287595A1
公开(公告)日：2008-11-20
申请号：US10589713
申请日：2005-03-24
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L63/00 , C08L63/10 , C08L67/06 , C09D5/033 , C09D153/00 , C09D167/06 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： A composition comprising (1) a thermosettable resin selected from the group consisting of an epoxy resin, an epoxy vinyl ester resin, an unsaturated polyester resin or a mixture thereof, and (2) an amphiphilic mock copolymer dispersed in the thermosettable resin; fiber-reinforced plastics (FRP), coatings and composites prepared therefrom; and methods of preparing these.
摘要翻译： 一种组合物，其包含（1）选自环氧树脂，环氧乙烯基酯树脂，不饱和聚酯树脂或其混合物的热固性树脂，和（2）分散在所述可热固化树脂中的两亲模拟共聚物; 纤维增强塑料（FRP），由其制备的涂料和复合材料; 及其制备方法。
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5.发明授权Advancing epoxy resins in presence of amino group-containing phosphonium catalyst 失效含氨基磷酸酯催化剂存在下环氧树脂的研究进展
公开(公告)号：US5109099A
公开(公告)日：1992-04-28
申请号：US568290
申请日：1990-08-16
CPC分类号： C08G59/688
摘要： The process of reacting an epoxy resin with a reactive hydrogen-containing compound or a carboxylic acid anhydride in the presence of a phosphonium catalyst is improved by employing a phosphonium compound having an amino substituent on the cation portion of the phosphonium compound as the catalyst. The invention also concerns precatalyzed epoxy resin compositions, curable compositions and cured compositions.
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6.发明授权Preparation of advanced epoxy resins from epoxy resins and dihydric phenols in the presence of phosphonium compounds 失效在鏻化合物存在下，由环氧树脂和二元酚制备高级环氧树脂
公开(公告)号：US4808692A
公开(公告)日：1989-02-28
申请号：US157671
申请日：1988-02-18
申请人： Ha Q. Pham , Loan A. Ho
发明人： Ha Q. Pham , Loan A. Ho
CPC分类号： C08G59/066 , C08G59/688
摘要： Advanced epoxy resins are prepared from glycidyl ethers of bisphenols or biphenols in the presence of cycloalkyl triphenyl phosphonium catalysts.
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公开(公告)号：US08552104B2
公开(公告)日：2013-10-08
申请号：US10589713
申请日：2005-03-24
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L63/00 , C08L63/10 , C08L67/06 , C09D5/033 , C09D153/00 , C09D167/06 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： A composition comprising (1) a thermosettable resin selected from the group consisting of an epoxy resin, an epoxy vinyl ester resin, an unsaturated polyester resin or a mixture thereof, and (2) an amphiphilic mock copolymer dispersed in the thermosettable resin; fiber-reinforced plastics (FRP), coatings and composites prepared therefrom; and methods of preparing these.
摘要翻译： 一种组合物，其包含（1）选自环氧树脂，环氧乙烯基酯树脂，不饱和聚酯树脂或其混合物的热固性树脂，和（2）分散在所述可热固化树脂中的两亲模拟共聚物; 纤维增强塑料（FRP），由其制备的涂料和复合材料; 及其制备方法。
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公开(公告)号：US20120172493A1
公开(公告)日：2012-07-05
申请号：US13389028
申请日：2010-09-21
申请人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
发明人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
CPC分类号： C08G59/64 , C08G59/621 , C08J5/24 , C08J2363/02
摘要： A curable epoxy resin composite composition including a reinforcing material and an epoxy resin composition, and a process for preparing a composite from such composition; wherein a combination of at least one alkanolamine and at least one styrenated phenol are present in the epoxy resin composition in a sufficient amount to increase the rate of reaction of the at least one epoxy resin and the at least one alkanolamine curing agent while maintaining the thermal and mechanical properties of the composite upon curing of the epoxy resin composition.
摘要翻译： 包含增强材料和环氧树脂组合物的可固化环氧树脂复合组合物及其制备方法。 其中至少一种链烷醇胺和至少一种苯乙烯化酚的组合以足够的量存在于环氧树脂组合物中以提高至少一种环氧树脂和至少一种链烷醇胺固化剂的反应速率同时保持热 以及环氧树脂组合物固化时复合材料的机械性能。
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公开(公告)号：US5401814A
公开(公告)日：1995-03-28
申请号：US135712
申请日：1993-10-13
CPC分类号： C08G59/688 , C08G59/621
摘要： Poly(hydroxy ethers) are prepared by reacting a dihydric phenol with a diepoxide in the presence of a catalyst selected from the group consisting of bis(trihydrocarbylphosphoranylidene)ammonium salt, bis[tris(dihydrocarbylamino)phosphoranylidene]ammonium salt, and tetrakis[tris(dihydrocarbylamino)phosphoranylideneamino]phosphonium salt. The reaction between the dihydric phenol and the diepoxide is conducted in an ether or hydroxy ether solvent at a temperature sufficiently high to produce a poly(hydroxy ether). Polymers prepared by the new process are more highly branched than those produced by known methods.
摘要翻译： 聚（羟基醚）通过二选苯酚与二环氧化物在选自双（三烃基亚正膦基）铵盐，双[三（二烃基氨基）亚正膦基]铵盐和四[三 二烃基氨基）正膦亚基氨基]鏻盐。 二羟基酚和二环氧化物之间的反应在足够高的温度下在醚或羟基醚溶剂中进行以产生聚（羟基醚）。 通过新方法制备的聚合物比通过已知方法制备的聚合物分枝得多。
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公开(公告)号：US4933420A
公开(公告)日：1990-06-12
申请号：US248509
申请日：1988-09-23
申请人： Ha Q. Pham , Loan A. Ho
发明人： Ha Q. Pham , Loan A. Ho
CPC分类号： C08G59/621 , C08G59/42 , C08G59/688
摘要： Epoxide compounds and phenolic compounds are reacted in the presence of phosphonium compounds represented by the formula .crclbar.Z'R.sup.1 R.sup.2 R.sup.3 P.sym.-Z-P.sym.R.sup.1 R.sup.2 R.sup.3 Z'.crclbar. wherein each R.sup.1, R.sup.2 and R.sup.3 is independently an aromatic group or an inertly substituted aromatic group; Z is --(C(R.sup.4).sub.2).sub.a --; each R.sup.4 is independently hydrogen or a hydrocarbyl group containing from 1 to about 20 carbon atoms; Z' is any suitable anion and a has a value of at least 4.
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