Methods, treatment fluids and systems for differential acidizing of a siliceous material

    公开(公告)号:US11505738B2

    公开(公告)日:2022-11-22

    申请号:US16908371

    申请日:2020-06-22

    摘要: The rapid reaction of hydrofluoric acid with siliceous materials can make it difficult to increase the permeability of subterranean formations containing siliceous minerals. Methods for stimulating a subterranean formation can comprise: providing a latent hydrofluoric acid composition comprising a degradable matrix, and a hydrofluoric acid precursor dispersed in the degradable matrix; introducing a first treatment fluid containing the latent hydrofluoric acid composition in a non-dissolved form into a wellbore penetrating a subterranean formation comprising a siliceous material; differentially depositing the latent hydrofluoric acid composition upon a portion of the siliceous material in one or more locations; degrading at least a portion of the degradable matrix, thereby exposing at least a portion of the hydrofluoric acid precursor; converting the exposed hydrofluoric acid precursor into hydrofluoric acid; and reacting the hydrofluoric acid with the siliceous material where the latent hydrofluoric acid composition was deposited.

    Corrosion inhibition of HCL treatment fluids with environmentally compatible solvent

    公开(公告)号:US11066749B2

    公开(公告)日:2021-07-20

    申请号:US16780488

    申请日:2020-02-03

    IPC分类号: C23F11/04 C09K8/74 C09K8/54

    摘要: A method of treating in a subterranean formation including placing a corrosion inhibitor composition into a subterranean formation, where the formation includes an acidic environment having a pH of about 5 or below, where the composition includes: an organic solvent comprising an alcohol with a flash point of at least about 75° C.; a nitrogen containing compound; an aqueous acid solution comprising HCl; and contacting a metal surface with the corrosion inhibitor composition. A corrosion inhibitor composition includes an organic solvent comprising an alcohol with a flash point of at least about 75° C.; a nitrogen containing compound; and an aqueous acid solution comprising HCl.

    Corrosion Inhibition of HCL Treatment Fluids with Environmentally Compatible Solvent

    公开(公告)号:US20200173034A1

    公开(公告)日:2020-06-04

    申请号:US16780488

    申请日:2020-02-03

    IPC分类号: C23F11/04 C09K8/54 C09K8/74

    摘要: A method of treating in a subterranean formation including placing a corrosion inhibitor composition into a subterranean formation, where the formation includes an acidic environment having a pH of about 5 or below, where the composition includes: an organic solvent comprising an alcohol with a flash point of at least about 75° C.; a nitrogen containing compound; an aqueous acid solution comprising HCl; and contacting a metal surface with the corrosion inhibitor composition. A corrosion inhibitor composition includes an organic solvent comprising an alcohol with a flash point of at least about 75° C.; a nitrogen containing compound; and an aqueous acid solution comprising HCl.