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    Impact-resistant thermoplastic molding materials with improved stress-cracking resistance
    2.
    发明授权
    Impact-resistant thermoplastic molding materials with improved stress-cracking resistance 失效
    耐冲击热塑性成型材料具有改善的耐应力开裂性

    公开(公告)号：US4330641A

    公开(公告)日：1982-05-18

    申请号：US204527

    申请日：1980-11-06

    申请人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

    发明人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

    IPC分类号： C08F255/06 ,  C08F279/02 ,  C08F279/04 ,  C08F279/06

    CPC分类号： C08F255/06 ,  C08F279/02

    摘要： Thermoplastic molding materials which contain a copolymer which has been made impact-resistant with a rubber. The copolymer is produced by polymerizing a mixture of a monovinyl-aromatic compound and an acrylic acid derivative or methacrylic acid derivative in the presence of a rubber. The folding materials contain a specific proportion of soft component. The diameter of the particles of the soft component, and the swelling index of the soft component, lie within a specific range, and the tensile strength of the molding material is higher than the yield strength.

    摘要翻译： 含有已经用橡胶抗冲击的共聚物的热塑性成型材料。 共聚物通过在橡胶存在下聚合单乙烯基 - 芳族化合物和丙烯酸衍生物或甲基丙烯酸衍生物的混合物来制备。 折叠材料含有特定比例的软组分。 软组分的颗粒直径和软组分的溶胀指数在特定范围内，成型材料的拉伸强度高于屈服强度。

    Process for the continuous preparation of rubber-modified polymers of vinylaromatics
    3.
    发明授权
    Process for the continuous preparation of rubber-modified polymers of vinylaromatics 失效
    连续制备乙烯基芳烃橡胶改性聚合物的方法

    公开(公告)号：US4427826A

    公开(公告)日：1984-01-24

    申请号：US273689

    申请日：1981-06-15

    申请人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

    发明人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

    IPC分类号： C08F2/38 ,  C08F4/00 ,  C08F279/02

    CPC分类号： C08F279/02

    摘要： A process, carried out without a diluent or in solution, in more than 2 reaction zones, for the continuous preparation of rubber-modified polymers of vinylaromatics, wherein a monomeric aromatic vinyl compound and an elastomeric polymer, in an amount of from 3 to 16% by weight based on the monomer, are polymerized, in the absence of a free radical initiator, but in the presence of a mercaptan as a chain transfer agent, at from 80.degree. to 180.degree. C. in a first reaction zone, with stirring, up to a maximum monomer conversion, U.sub.max, given by the equationU.sub.max =K-1where K is the amount of rubber in % by weight based on monomer, and, in a second reaction zone, polymerization is continued, with stirring, to a conversion of up to about 50% by weight, after which a chain transfer agent is introduced in an amount of from 0.01 to 0.2% by weight, based on vinyl-aromatic monomer, and polymerization is continued, if appropriate in more than one reaction zone, up to a monomer conversion of less than 85% by weight. The polymer is treated in a devolatilization zone to remove vinyl-aromatic monomer and solvent, if any, and these constituents are recycled to the process. The process produces products which exhibit good gloss coupled with good mechanical properties, and which can be employed for conventional applications.

    摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中没有稀释剂或在溶液中，在多于2个反应区中进行，其中单体芳族乙烯基化合物和弹性体聚合物的量为3-16 基于单体的重量％在不存在自由基引发剂的情况下，在作为链转移剂的硫醇存在下，在第一反应区中在80-180℃下进行聚合，同时搅拌 ，达到最大单体转化率，Umax，由方程式Umax = K-1给出，其中K是基于单体的以重量％计的橡胶量，并且在第二反应区中，在搅拌下继续聚合至 高达约50重量％的转化率，之后以基于乙烯基芳族单体的0.01至0.2重量％的量引入链转移剂，并且如果适当的话在多于一个反应中继续聚合 区域，单体转化率小于 85重量％。 将聚合物在脱挥发区进行处理以除去乙烯基芳族单体和溶剂（如果有的话），并将这些组分再循环到该方法中。 该方法产生具有良好光泽性和良好机械性能的产品，并且其可用于常规应用。

    Impact resistant thermoplastic molding composition and use thereof
    4.
    发明授权
    Impact resistant thermoplastic molding composition and use thereof 失效
    耐冲击热塑性成型用组合物及其用途

    公开(公告)号：US5011871A

    公开(公告)日：1991-04-30

    申请号：US323753

    申请日：1989-03-15

    申请人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

    发明人： Rainer Bueschl ,  Adolf Echte ,  Konrad Schulte ,  Hans Mittnacht

    IPC分类号： C08F279/02

    CPC分类号： C08F279/02

    摘要： An impact resistance thermoplastic molding composition contains, each percentage being based on A+B, from 80 to 55% by weight of a hard matrix A of a copolymer containing at least 95% by weight of an aromatic vinyl monomer a.sub.11 of from 8 to 10 carbon atoms and at least one comonomer a.sub.12 in a proportion of 0.1 to 5% by weight, based on A, and from 45 to 20% by weight of a soft phase B which, uniformly dispersed in the hard matrix, has an average particle diameter d.sub.50 (volume average) of from 3.5 to 9 .mu.m and is obtainable by polymerization of the mixture of monomers a.sub.11 and a.sub.12 in the presence of an elastomer (rubber) and subsequent isolation of the useful product, wherein the comonomer a.sub.12 has the general formula I ##STR1## where X is --OR.sup.2, --COOR.sup.2 or --CONHR.sup.3,R.sup.1 is hydrogen or methyl andR.sup.2 and R.sup.3 are each alkyl of from 1 or 2 to 10 carbon atoms with at least one OH or epoxy group or at least one other polar group.

    摘要翻译： 抗冲击性热塑性成型组合物含有以百分比为基准的A + B，80〜55重量％的含有至少95重量％的芳族乙烯基单体a11为8〜10的共聚物的硬质基质A 碳原子和至少一种共聚单体a 12，其比例为0.1至5重量％，基于A，和45至20重量％的均匀分散在硬质基质中的软相B具有平均粒径 d50（体积平均）为3.5至9μm，可通过在弹性体（橡胶）存在下聚合单体a11和a12的混合物，随后分离有用的产物而获得，其中共聚单体a12具有通式 （I）其中X是-OR2，-COOR2或-CONHR3，R1是氢或甲基，R2和R3各自为具有1或2至10个碳原子的烷基，具有至少一个OH或环氧基团或在 至少另一个极地组。

    Thermoplastics impact modified with functionalized polymers and use thereof for producing moldings
    5.
    发明授权
    Thermoplastics impact modified with functionalized polymers and use thereof for producing moldings 失效
    用功能化聚合物改性的热塑性塑料及其制造模具的用途

    公开(公告)号：US5055527A

    公开(公告)日：1991-10-08

    申请号：US541078

    申请日：1990-06-20

    申请人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

    发明人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

    IPC分类号： C08L9/00 ,  C08L25/04 ,  C08L35/06 ,  C08L53/02

    CPC分类号： C08L25/04 ,  C08L35/06 ,  C08L53/02 ,  C08L9/00

    摘要： Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting ofa1) 60-99.5 percent by weight of an aromatic vinyl compound present as copolymerized units,a2) 0.5-20 percent by weight of an unsaturated carboxylic anhydride present as copolymerized units anda3) 014 35 percent by weight of an alkenylnitrile present as copolymerized units,B) from 1 to 40 percent by weight of a polymeric flexibilizing component consisting ofb1) 100-60 percent by weight of a monomer from the group of the 1,4-dienes which is present as copolymerized units andb2) 0-40 percent by weight of an aromatic vinyl compound present as copolymerized units. and optionallyC) customary additives in customary amounts, the polymers of flexibilizing component B having amino end groups, are used for producing moldings.

    摘要翻译： 组分A，B和任选C的抗冲改性热塑性共混物，由以下组成：A）99-60％重量的由a1）60-99.5％（重量）以共聚单元形式存在的芳族乙烯基化合物组成的聚合刚性基质， a2）0.5-20重量％作为共聚单元存在的不饱和羧酸酐和a3）作为共聚单元存在的作为共聚单元的链烯基腈的重量比为35重量％，B）1〜40重量％的由b1 ）100-60重量％的作为共聚单元存在的1,4-二烯基的单体，和b2）0-40重量％作为共聚单元存在的芳族乙烯基化合物。 和任选的C）常规量的常规添加剂，具有氨基端基的增韧组分B的聚合物用于生产模制品。

    Thermoplastics of polyalkylene terephthalates impact modified with functionalized polymers and use thereof for producing moldings
    8.
    发明授权
    Thermoplastics of polyalkylene terephthalates impact modified with functionalized polymers and use thereof for producing moldings 失效
    用功能性聚合物改性的聚对苯二甲酸十五烷酯的热塑性物质及其制造用模具的用途

    公开(公告)号：US5115022A

    公开(公告)日：1992-05-19

    申请号：US481689

    申请日：1990-02-20

    申请人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

    发明人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

    IPC分类号： C08L67/00 ,  C08L67/02

    CPC分类号： C08L67/02

    摘要： Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting of polybutylene terephthalate or polyethylene terephthalateB) from 1 to 40 percent by weight of a polymeric flexibilizing component comprisingb1) 100-60 percent by weight of a monomer from the group of the 1,3-dienes which is present as copolymerized units andb2) 0-40 percent by weight of an aromatic vinyl compound present as copolymerized units andC) optionally customary additives in customary amounts, the polymers of flexibilizing component B having amino end groups, are used for producing moldings.

    摘要翻译： 组分A，B和任选C的抗冲改性热塑性共混物，由以下组成：A）99-60％重量的由聚对苯二甲酸丁二醇酯或聚对苯二甲酸乙二醇酯组成的聚合物刚性基质B）1至40重量％聚合物柔性 组分包括：b1）100-60重量％的作为共聚单元存在的1,3-二烯的单体，和b2）0-40重量％作为共聚单元存在的芳族乙烯基化合物，和C） 常规用量的常规添加剂，具有氨基端基的增韧组分B的聚合物用于生产模制品。

    Thermoplastic molding materials and their preparation
    10.
    发明授权
    Thermoplastic molding materials and their preparation 失效
    热塑性成型材料及其制备

    公开(公告)号：US4839418A

    公开(公告)日：1989-06-13

    申请号：US141098

    申请日：1988-01-05

    申请人： Hans-Dieter Schwaben ,  Adolf Echte ,  Rainer Bueschl ,  Rainer Schlichtmann ,  Peter Klaerner ,  Hubert Kindler

    发明人： Hans-Dieter Schwaben ,  Adolf Echte ,  Rainer Bueschl ,  Rainer Schlichtmann ,  Peter Klaerner ,  Hubert Kindler

    IPC分类号： C08F287/00 ,  C08L25/06 ,  C08L51/00

    CPC分类号： C08F287/00 ,  C08L25/06 ,  C08L51/00

    摘要： A thermoplastic molding material contains, in each case based on the molding material comprising A+B,A from 80 to 60% by weight of a hard matrix composed of polystyrene andB from 20 to 40% by weight of a soft phase which is obtainable by polymerization of styrene in the presence of a linear styrene/butadienne block copolymer which has an ill defined transition, contains from 35 to 45% by weight of styrene and from 65 to 55% by weight of butadiene and has a block polystyrene content of from 25 to 35% by weight, the soft phase being uniformly distributed in the hard matrix and having a particle diameter of less than 0.8 .mu.m.The typical features of the said molding material are that the median particle diameter d.sub.50 (volume average of the soft phase B is from 0.25 to 0.38 .mu.m, the width of the particle size distribution, (d.sub.95 14 d.sub.5), is from 0.2 to 0.6 .mu.m, the d.sub.60 value is from 0.26 to 0.40 .mu.m and the d.sub.90 value is from 0.40 to 0.75.

    摘要翻译： 在各种情况下，热塑性成型材料基于包含A + B的成型材料，80-60重量％的由聚苯乙烯和B组成的硬质基质的A含有20-40重量％的软相， 在具有不规则转变的线性苯乙烯/丁二烯嵌段共聚物的存在下苯乙烯的聚合包含35-45％（重量）的苯乙烯和65-55％（重量）的丁二烯，并且具有 25〜35重量％，软相均匀分布在硬质基质中，粒径小于0.8μm。 所述成型材料的典型特征是中值粒径d50（软相B的体积平均值为0.25至0.38μm，粒度分布的宽度（d9514d5））为0.2至0.6μm m，d60值为0.26〜0.40μm，d90为0.40〜0.75。