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公开(公告)号：US20050176924A1
公开(公告)日：2005-08-11
申请号：US10510475
申请日：2003-04-10
摘要： A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [ML1aL2b]cm+Zc·m/nn− (I) where M is a metal of group VIII; L1 is a ligand having at least one π-electron pair; each L2 is independently tetrahydrofuran or a ligand which is displaceable by tetrahydrofuran; Z is an anion; a is 1 or 2; b is an integer from 0 to 4; c is 1 or 2; and m and n are integers from 1 to 4.
摘要翻译： 描述了通过使甲醛源与式I的催化剂接触而制备聚甲醛的方法，该方法式为：式中：=“引线”→[ML 1] b （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是第VIII组的金属; L 1是具有至少一个π-电子对的配体; 每个L 2独立地是四氢呋喃或可由四氢呋喃置换的配体; Z是阴离子; a是1或2; b为0〜4的整数; c为1或2; m和n为1〜4的整数。
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公开(公告)号：US07112651B2
公开(公告)日：2006-09-26
申请号：US10510475
申请日：2003-04-10
IPC分类号： C08G65/34
摘要： A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [ML1aL2b]cm+Zc·m/nn− (I) where M is a metal of group VIII; L1 is a ligand having at least one π-electron pair; each L2 is independently tetrahydrofuran or a ligand which is displaceable by tetrahydrofuran; Z is an anion; a is 1 or 2; b is an integer from 0 to 4; c is 1 or 2; and m and n are integers from 1 to 4.
摘要翻译： 描述了通过使甲醛源与式I的催化剂接触而制备聚甲醛的方法，该方法式为：式中：=“引线”→[ML 1] b （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是第VIII组的金属; L 1是具有至少一个π-电子对的配体; 每个L 2独立地是四氢呋喃或可由四氢呋喃置换的配体; Z是阴离子; a是1或2; b为0〜4的整数; c为1或2; m和n为1〜4的整数。
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公开(公告)号：US07064177B2
公开(公告)日：2006-06-20
申请号：US10510477
申请日：2003-04-10
摘要： A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [CpvMLw]m+Zm/nn− (I) where M is Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh or Ir, Cp is a cyclopentadienyl ligand C5H(5-u)R1u, where u is from 0 to 5 and R1 is alkyl, alkenyl, aryl, heteroaryl, aralkyl, COOR2, COR2, CN or NO2, and R2 is H, alkyl, aryl or aralkyl, v is 1 or 2, each L is independently a nitrile, CO or a ligand displaceable by CO, w is an integer from 0 to 4, Z is an anion, and m and n are each independently an integer from 1 to 3.
摘要翻译： 描述了通过使甲醛源与式I的催化剂接触来制备聚甲醛的方法，该方法式为：式中：=“引线”→[Cp （I） =“In-line Formulas”end =“tail”？>其中M是Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh或Ir ，Cp是环戊二烯基配体C 5 H（5-u）R 1，其中u是 0至5，R 1是烷基，烯基，芳基，杂芳基，芳烷基，COOR 2，COR 2，CN或NO 2，且R 2是H，烷基，芳基或芳烷基，v是1或2，每个L独立地是腈，CO或可被CO取代的配体，w是整数 0至4，Z是阴离子，m和n各自独立地为1至3的整数。
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公开(公告)号：US20050148755A1
公开(公告)日：2005-07-07
申请号：US10510477
申请日：2003-04-10
摘要： A process is described for preparing polyoxymethylene by contacting a formaldehyde source with a catalyst of the formula I [CpvMLw]m+Zm/nn− (I) where M is Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh or Ir, Cp is a cyclopentadienyl ligand C5H(5−u)R1u, where u is from 0 to 5 and R1 is alkyl, alkenyl, aryl, heteroaryl, aralkyl, COOR2, COR2, CN or NO2, and R2 is H, alkyl, aryl or aralkyl, v is 1 or 2, each L is independently a nitrile, CO or a ligand displaceable by CO, w is an integer from 0 to 4, Z is an anion, and m and n are each independently an integer from 1 to 3.
摘要翻译： 描述了通过使甲醛源与式I的催化剂接触来制备聚甲醛的方法，该方法式为：式中：=“引线”→[Cp （I） =“In-line Formulas”end =“tail”？>其中M是Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh或Ir ，Cp是环戊二烯基配体C 5 H（5-u）R 1，其中u是 0至5，R 1是烷基，烯基，芳基，杂芳基，芳烷基，COOR 2，COR 2，CN或NO 2，R 2是H，烷基，芳基或芳烷基，v是1或2，每个L独立地是腈，CO或可被CO取代的配体，w是整数 0至4，Z是阴离子，m和n各自独立地为1至3的整数。
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公开(公告)号：US20070055011A1
公开(公告)日：2007-03-08
申请号：US10556605
申请日：2004-05-06
申请人： Markus Schmid , Mubarik Chowdhry , Peter Preishuber-Pflugl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
发明人： Markus Schmid , Mubarik Chowdhry , Peter Preishuber-Pflugl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
IPC分类号： C08G18/63
CPC分类号： C08F10/00 , C08F110/06 , C08F2/18 , C08F4/7016
摘要： Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.
摘要翻译： 在至少一种分散剂和固体聚合催化剂的存在下，通过在水介质中聚合至少一种烯属不饱和化合物来制备聚合物水分散体的方法。
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公开(公告)号：US06667386B1
公开(公告)日：2003-12-23
申请号：US09719813
申请日：2000-12-18
申请人： Joachim Queisser , Michael Slany , Michael Geprägs , Ekkehard Lindner , Markus Schmid , Joachim Wald , Peter Wegner
发明人： Joachim Queisser , Michael Slany , Michael Geprägs , Ekkehard Lindner , Markus Schmid , Joachim Wald , Peter Wegner
IPC分类号： C08G6702
CPC分类号： C08G67/02 , B01J31/18 , B01J31/24 , B01J2531/10 , B01J2531/20 , B01J2531/80 , B01J2531/824 , C07F9/5004 , C07F9/5027 , C07F15/0066
摘要： Water-soluble transition metal complexes of the formula (I) where R1 to R4 are linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on nonmetallic elements of groups IVA to VIA of the Periodic Table of Elements.
摘要翻译： 式（I）的水溶性过渡金属络合物，其中R 1至R 4为直链或支链C 2至C 28 - 烷基，C 3至C 14 - 环烷基或烷芳基，其中烷基部分为1至28 碳原子和芳基部分为6至15个碳原子，其各自被至少一种基于元素周期表的IVA至VIA族的非金属元素的极性质子或离子官能团取代。
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7.发明授权
公开(公告)号：US5522905A
公开(公告)日：1996-06-04
申请号：US31912
申请日：1993-04-16
CPC分类号： C10L1/1828 , C10L1/1881 , C10L1/1886 , C10L1/189 , C10L10/02 , F01N3/023 , F02B51/00 , F01N2430/04 , F02B3/06
摘要： A diesel fuel containing an additive which improves the combustion of soot, for reducing the pollutant emission in the combustion exhaust gases from diesel engines by discontinuous burning-off of soot which has been precipitated in the exhaust gas filter, is described. For this purpose, a lithium, sodium or potassium salt of an aliphatic or aromatic alcohol, of a phenol, of an aliphatic acid or of a naphthoic acid, phenylacetic acid or cinnamic acid is added, singly or as a mixture, to the diesel fuel before the combustion of the latter in the internal combustion engine. As a result of the addition of the alkali metal salts, the ignition temperature of the soot precipitated in the particle filter is reduced, and the soot is oxidized at a temperature which is considerably lower than the normal ignition temperature. The regeneration range for the particle filter is therefore reached much more frequently in real running practice. This avoids a critical filter loading with soot, which can lead to filter damage during burning off. A further advantage of the process described is that, according to present knowledge, no additional substances with a health risk are emitted during running as a result of the addition of these alkali metal salts to the diesel fuel.
摘要翻译： 描述了含有改善烟灰燃烧的添加剂的柴油燃料，用于通过在废气过滤器中沉淀的烟灰的不连续燃烧来减少来自柴油发动机的燃烧废气中的污染物排放。 为此目的，将单独或作为混合物将脂族或芳族醇的脂族或芳族醇，脂肪酸或萘甲酸，苯乙酸或肉桂酸的锂，钠或钾盐加入到柴油中 在后者在内燃机中的燃烧之前。 作为添加碱金属盐的结果，在颗粒过滤器中沉淀的烟灰的点火温度降低，并且烟灰在比正常点火温度低得多的温度下被氧化。 因此，在实际运行实践中，更频繁地实现了颗粒过滤器的再生范围。 这样可以避免过滤装载烟尘的过滤器，这可能导致燃烧过程中的过滤器损坏。 所描述的方法的另一个优点是，根据现有的知识，由于向柴油燃料中加入这些碱金属盐，所以在运行期间不会发出具有健康风险的其它物质。
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公开(公告)号：US07462673B2
公开(公告)日：2008-12-09
申请号：US10556605
申请日：2004-05-06
申请人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
发明人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
IPC分类号： C08F4/26
CPC分类号： C08F10/00 , C08F110/06 , C08F2/18 , C08F4/7016
摘要： Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.
摘要翻译： 在至少一种分散剂和固体聚合催化剂的存在下，通过在水介质中聚合至少一种烯属不饱和化合物来制备聚合物水分散体的方法。
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9.发明授权Catalyst systems based on transition metal complexes for carbon monoxide copolymerization in an aqueous medium 失效基于在水性介质中一氧化碳共聚的过渡金属络合物的催化剂体系公开(公告)号：US06852662B2
公开(公告)日：2005-02-08
申请号：US10692334
申请日：2003-10-24
申请人： Joachim Queisser , Michael Slany , Michael Geprägs , Ekkehard Lindner , Markus Schmid , Joachim Wald , Peter Wegner
发明人： Joachim Queisser , Michael Slany , Michael Geprägs , Ekkehard Lindner , Markus Schmid , Joachim Wald , Peter Wegner
CPC分类号： B01J31/18 , B01J31/24 , B01J2531/10 , B01J2531/20 , B01J2531/80 , B01J2531/847 , C08G67/02
摘要： Catalyst systems for the copolymerization of carbon monoxide and α-olefinically unsaturated compounds contain, as essential components, a) a metal complex of the formula (I) where R1 to R4 are each linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on elements of groups IVA to VIA of the Periodic Table of Elements, and b) if required, one or more Lewis or protic acids or a mixture of Lewis and protic acids.
摘要翻译： 用于一氧化碳和α-烯属不饱和化合物共聚的催化剂体系含有a）式（I）的金属络合物，其中R 1至R 4各自为直链或支链C 2-8 - 烷基，C 3至C 14 - 环烷基或烷基芳基，其中烷基部分为1至28个碳原子，芳基部分为6至15个碳原子，各自被至少一个极性质子或离子官能团基团取代 元素周期表IVA至VIA族的元素，以及b）如果需要，可以使用一种或多种路易斯酸或质子酸或路易斯酸和质子酸的混合物。
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