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    Quinacridones having selectively adjusted triboelectric effects
    1.
    发明授权
    Quinacridones having selectively adjusted triboelectric effects 失效
    具有选择性调整的三电效应的喹喔啉

    公开(公告)号：US5137576A

    公开(公告)日：1992-08-11

    申请号：US414137

    申请日：1989-09-28

    申请人： Hans-Tobias Macholdt ,  Adolf Kroh ,  Alexander Sieber ,  Erwin Dietz

    发明人： Hans-Tobias Macholdt ,  Adolf Kroh ,  Alexander Sieber ,  Erwin Dietz

    IPC分类号： G03G9/097 ,  C09B48/00 ,  C09B67/20 ,  C09B67/22 ,  C09B67/52 ,  G03G9/09

    CPC分类号： G03G9/092 ,  C09B48/00 ,  C09B67/0036 ,  C09B67/006

    摘要： Quinacridones having selectively adjusted triboelectric effects, which quinacridones contain about 0.05% to 100 percent by weight of triboelectrically active compounds of the general formula IQ--A--Y].sub.n (I),in which Q is a quinacridone radical which is unsubstituted or substituted by halogen atoms, alkyl, alkoxy H.sub.2 N--CO--, alkyl--NH--CO-- or (alkyl).sub.2 N--CO groups, A is a direct bond or --O--, --S--, --NR.sup.1 --, --CO--, --SO.sub.2 --, --CR.sup.2 R.sup.3 -- or arylene and Y is an --NR.sup.4 R.sup.5 group or a five-, six- or seven-membered heterocycle which contains one to three heteroatoms from the series comprising nitrogen and/or oxygen and/or sulfur and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, --CN, --COOH, --CO-- NRR', --SO.sub.2 --NRR', hydroxyalkyl or alkylaminoalkyl, in which R and R' together with the nitrogen atom can be a heterocycle, R and R' are hydrogen atoms or alkyl and R.sup.1 to R.sup.5, independently of one another, are each hydrogen and/or alkyl or alkenyl of 1 to 22 carbon atoms and n is a number from 1 to 4, and their use for the preparation of toners or developers which are used for electrophotographic copying or reproduction of originals and for printing electronically, optionally or magnetically stored information or are used in color proofing.

    摘要翻译： 具有选择性调节摩擦电效应的喹吖啶酮，其中喹吖啶酮含有约0.05％至100％重量的通式I QAY] n（I）的摩擦电活性化合物，其中Q是未被取代或被卤素原子取代的喹吖啶酮基团， 烷基，烷氧基H2N-CO-，烷基-NH-CO-或（烷基）2N-CO基，A是直接键或-O - ， - S - ， - NR 1 - ， - CO - ， - SO 2 - CR 2 R 3 - 或亚芳基，Y是-NR 4 R 5基团或五元，六元或七元杂环，其含有一至三个包含氮和/或氧和/或硫的系列的杂原子，其可以被烷基， 烷氧基，羟基苯基，卤素，-CN，-COOH，-CO-NRR'，-SO2-NRR'，羟基烷基或烷基氨基烷基，其中R和R'与氮原子一起可以是杂环，R和R'是氢 原子或烷基和R 1至R 5彼此独立地为氢和/或1至22个碳原子的烷基或烯基，n为1至4的数，并且th 用于制备用于电子照相复制或再现原稿的电子调色剂或显影剂，以及用于电子，可选地或磁存储的信息的印刷，或用于彩色打样。

    Magenta colorant for electrophotographic recording processes
    2.
    发明授权
    Magenta colorant for electrophotographic recording processes 失效
    用于电子照相记录方法的品红色着色剂

    公开(公告)号：US4777105A

    公开(公告)日：1988-10-11

    申请号：US55347

    申请日：1987-05-28

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Adolf Kroh

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Adolf Kroh

    IPC分类号： G03G9/087 ,  G03G9/09 ,  G03G15/01 ,  G03G9/08 ,  G03G9/10

    CPC分类号： G03G9/092

    摘要： An improved magenta colorant for electrophotographic multicolor recording processes, comprising mix-crystals from 95 to 60 parts of a compound of the formula I below and 5 to 40 parts of a compound of the following formula II ##STR1## and use thereof for preparing toners or developers which are used for electrophotographic copying of subject copies and for printing electronically, optically and magnetically stored data.

    摘要翻译： 一种用于电子照相多色记录方法的改进的品红色着色剂，其包含95至60份下式I化合物和5至40份下式II化合物的混合晶体，并使用 用于制备用于电子照相复印对象副本并用于电子，光学和磁存储数据的打印的调色剂或显影剂。

    Specifically influencing the triboelectric effect of azo pigments
    4.
    发明授权
    Specifically influencing the triboelectric effect of azo pigments 失效
    具体影响偶氮颜料的摩擦电效应

    公开(公告)号：US4957841A

    公开(公告)日：1990-09-18

    申请号：US407225

    申请日：1989-09-14

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Franz Schui ,  Reinhold Deubel

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Franz Schui ,  Reinhold Deubel

    IPC分类号： C09B41/00 ,  C09B63/00 ,  C09B67/18 ,  C09B67/20 ,  C09D5/46 ,  G03G9/09 ,  G03G9/097

    CPC分类号： C09B41/001 ,  C09B63/005 ,  C09B67/002 ,  C09B67/006 ,  G03G9/091 ,  G03G9/09741 ,  Y10S524/904

    摘要： Process for specifically influencing the triboelectric effect of azo pigments in electrophotographic toners or developers or in powders for surface coating by adding to the azo pigments at the coupling reaction stage, at the laking stage or in the course of finishing at least one saltlike, cationic compound whose positively charged center is a nitrogen, phosphorus, arsenic or antimony atom or the group ##STR1## and use of such azo pigments for producing toners or developers used for the electrophotographic copying or manifolding of originals or for printing electronically, optically or magnetically stored data or in colorproofing or use of such azo pigments for producing powders or powder coatings used for the surface coating of articles made of metal, wood, plastics, glass, ceramics, concrete, textile material, paper or rubber.

    摘要翻译： 通过在偶联反应阶段，在褪色阶段或在整理至少一种盐状阳离子化合物的过程中加入到偶氮颜料中，特别影响电子照相色调剂或显影剂中的偶氮颜料的摩擦电效应或用于表面包衣的粉末的方法 其带正电荷的中心是氮，磷，砷或锑原子或组，并且使用这种偶氮颜料制造调色剂或显影剂，用于电子照相复印或歧管原稿或用电子，光学或磁存储数据印刷 或用于制造用于由金属，木材，塑料，玻璃，陶瓷，混凝土，纺织材料，纸或橡胶制成的制品的表面涂覆的粉末或粉末涂料的这种偶氮颜料的着色或使用。

    Process for enhancing the electrostatic chargeability of powder coatings of powders, and the use thereof for surface-coating solid objects
    6.
    发明授权
    Process for enhancing the electrostatic chargeability of powder coatings of powders, and the use thereof for surface-coating solid objects 失效
    增加粉末粉末涂料的静电电荷性能的方法及其用于表面涂布固体物体的用途

    公开(公告)号：US5073579A

    公开(公告)日：1991-12-17

    申请号：US266509

    申请日：1988-11-03

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    IPC分类号： C09D5/03 ,  C09D5/46

    CPC分类号： C09D5/034

    摘要： Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects.A process for enhancing the electrostatic chargeability of powder coatings or powders intended for surface-coating solid objects, by homogeneously incorporating at least one triarylmethane, azine, thazine and/or oxazine compound in an amount from about 0.01 to about 10 percent by weight into powder coatings or powders, the compounds mentioned being dissolved or dispersed in the powder coating system or powders.

    摘要翻译： 用于提高粉末涂料或粉末的静电充电性的方法及其用于表面涂覆固体物体的用途。 通过将约0.01至约10重量％的量的至少一种三芳基甲烷，吖嗪，嗪和/或恶嗪化合物均匀掺入粉末中来提高用于表面涂覆固体物体的粉末涂料或粉末的静电荷性的方法， 涂料或粉末，所述化合物溶解或分散在粉末涂料体系或粉末中。

    Use of colorless, intensely fluorinated ammonium and iminium compounds as charge control agents for electrophotographic recording processes
    7.
    发明授权
    Use of colorless, intensely fluorinated ammonium and iminium compounds as charge control agents for electrophotographic recording processes 失效
    作为电子记录记录过程的充电控制剂，使用无色，强力氟化氨和铱化合物

    公开(公告)号：US5069994A

    公开(公告)日：1991-12-03

    申请号：US430732

    申请日：1989-11-02

    申请人： Jorg Gitzel ,  Hans-Tobias Macholdt ,  Alexander Sieber ,  Frank Wehowsky ,  Gunther Prossel

    发明人： Jorg Gitzel ,  Hans-Tobias Macholdt ,  Alexander Sieber ,  Frank Wehowsky ,  Gunther Prossel

    IPC分类号： C09D5/03 ,  C09D5/46 ,  G03G9/09 ,  G03G9/097 ,  G03G9/113

    CPC分类号： G03G9/09741 ,  C09D5/034 ,  G03G9/09766

    摘要： The use of intensely fluorinated ammonium compounds of the general formula (I) ##STR1## in which R.sub.1 to R.sub.4 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.1 to R.sub.4 denoting a straight-chain or branched fluorine-containing alkyl radical or fluorine-containing alkenyl radical which contains 1 to 69 carbon atoms and 3 to 66 fluorine atoms and which may be substituted, and at most three of the radicals R.sub.1 to R.sub.4 are, independently of one another, hydrogen atoms, straight-chain or branched alkyl radicals or alkenyl radicals containing 1 to 30 carbon atoms, aryl radicals or aralkyl radicals, and X.sup.- denotes an organic or inorganic anion, and of intensely fluorinated iminium compounds of the general formula (II) ##STR2## in which R.sub.9 to R.sub.12 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.9 to R.sub.12 denoting a straight-chain or branched fluorine-containing alkyl radical or fluorine-containing alkenyl radical which contains 1 to 69 carbon atoms and 3 to 66 fluorine atoms and which may be substituted, and at most three of the radicals R.sub.9 to R.sub.12 denote, independently of one another, hydrogen, straight-chain or branched alkyl radicals or alkenyl radicals containing 1 to 30 carbon atoms, aryl or aralkyl radicals and Y.sup.- is an organic or inorganic anion, as colorless charge control agents having positive or negative control effect in toners and developers for electrophotographic recording processes.

    摘要翻译： 使用通式（I）的高度氟化的铵化合物，其中R 1至R 4表示氢原子或有机基团，基团R 1至R 4中的至少一个表示直链或支链的氟 - 含有1至69个碳原子和3至66个氟原子且可以被取代的烷基或含氟烯基，并且至少三个基团R 1至R 4彼此独立地为氢原子， 含有1至30个碳原子的链或支链烷基或烯基，芳基或芳烷基，X表示有机或无机阴离子，以及通式（II）的强氟化亚胺化合物。（II） 其中R9至R12表示氢原子或有机基团，表示含有1至69个碳原子的直链或支链含氟烷基或含氟烯基的基团R 9至R 12中的至少一个 和3至66个氟原子并且其可以被取代，并且至少三个基团R 9至R 12彼此独立地表示氢，直链或支链烷基或含有1至30个碳原子的烯基，芳基或 芳烷基和Y-是有机或无机阴离子，作为在调色剂和电子照相记录方法的显影剂中具有正或负控制效果的无色电荷控制剂。

    Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects
    8.
    发明授权
    Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects 失效
    用于提高粉末涂料或粉末的静电充电性的方法及其用于表面涂覆固体物体的用途

    公开(公告)号：US5021473A

    公开(公告)日：1991-06-04

    申请号：US266510

    申请日：1988-11-03

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    IPC分类号： B05D1/10 ,  B05B5/047 ,  B05D1/06 ,  B05D7/24 ,  C09D5/03 ,  C09D5/46 ,  C09D133/00 ,  C09D163/00 ,  C09D167/00

    CPC分类号： C09D5/034

    摘要： Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface coating solid objects.Process for enhancing the electrostatic chargeability of powder coatings or powders intended for the surface-coating of solid objects, by homogeneously incorporating at least one salt-like, cationic compound of the formula (1) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, denote hydrogen atoms, straight-chain or branched alkyl groups having 1 to 30 carbon atoms, mononuclear or polynuclear cycloaliphatic radicals having 5 to 12 carbon atoms, oxethyl groups of the general formula --(CH.sub.2 --CH.sub.2 --O).sub.n --R in which n denotes a number from 1 to 10 and R denotes a hydrogen atom, a (C.sub.1 -C.sub.4)alkyl or acyl group, furthermore denote mononuclear or polynuclear aromatic radicals or araliphatic radicals, where the aliphatic, aromatic and araliphatic radicals may be substituted, and where the alkyl, cycloalkyl, aralkyl and aryl radicals for R.sub.1 to R.sub.4 may be substituted by halogen atoms, X denotes a phosphorus, arsenic or antimony atom, where, in the case where X denotes an arsenic or antimony atom, at least one of the radicals R.sub.1 -R.sub.4 is not a hydrogen atom, and A.crclbar. denotes the equivalent of an inorganic or organic anion, in an amount from about 0.01 to about 10 percent by weight into powder coatings or powders, the salt-like, cationic compounds of the formula (1) being dissolved or dispersed in the powder of coating system.

    摘要翻译： 用于提高粉末涂料或粉末的静电充电性的方法及其用于表面涂覆固体物体的用途。 通过均匀掺入至少一种式（1）的盐状阳离子化合物，其中R 1，R 2，R 2，R 2， ，R 3和R 4彼此独立地表示氢原子，具有1至30个碳原子的直链或支链烷基，具有5至12个碳原子的单核或多核脂环族基团，通式为 - （CH 2 - CH2-O）nR，其中n表示1至10的数，R表示氢原子，（C1-C4）烷基或酰基，还表示单核或多核芳族基团或芳脂族基团，其中脂族，芳族和 芳脂族基可以被取代，并且当R 1至R 4的烷基，环烷基，芳烷基和芳基可以被卤素原子取代时，X表示磷，砷或锑原子，其中，在X表示砷或蚂蚁的情况下 亚胺原子，基团R 1 -R 4中的至少一个不是氢原子，并且A（ - ）表示无机或有机阴离子的当量，其量为粉末涂料或粉末中约0.01至约10重量％ ，式（1）的盐状阳离子化合物溶解或分散在涂料体系的粉末中。

    Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects
    9.
    发明授权
    Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects 失效
    用于提高粉末涂料或粉末的静电充电性的方法及其用于表面涂覆固体物体的用途

    公开(公告)号：US5015676A

    公开(公告)日：1991-05-14

    申请号：US266508

    申请日：1988-11-03

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber ,  Claus Godau ,  Albrecht Manz

    IPC分类号： B05D1/10 ,  B05D7/24 ,  C09D5/03 ,  C09D5/46

    CPC分类号： C09D5/034

    摘要： A process for enhancing the electrostatic chargeability of powder coatings or powders intended for surface-coating solid objects, by homogeneously incorporating at least one salt-like, cationic compound of the formulae (1) and/or (2) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen atoms, straight-chain or branched alkyl groups having 1 to 30 carbon atoms, oxethyl groups of the formula --(CH.sub.2 --CH.sub.2 --O).sub.n --R in which R is a hydrogen atom or a (C.sub.1 -C.sub.4)alkyl or acyl group, and n is a number from 1 to 10, mononuclear or polynuclear cycloaliphatic radicals having 5 to 12 carbon atoms, mononuclear or polynuclear aromatic radicals or araliphatic radicals, R.sub.5 denotes a hydrogen, fluorine, chlorine or bromine atom or a (C.sub.1 -C.sub.6)alkoxy or primary amino group, and where R.sub.1 and R.sub.3 may be part of a ring system having 5 to 7 atoms and 0 to 3 double bonds, and A.sup.- denotes the equivalent of an anion, in an amount from about 0.01 to about 10 percent by weight into powder coatings or powders, where the salt-like cationic compounds of the general formulae (1) and (2) are dissolved or dispersed in the powder coating or powder.

    摘要翻译： 通过均匀掺入至少一种式（1）和/或（2）的“盐状阳离子化合物”，其中R 1（R 1） ，R 2，R 3和R 4彼此独立地为氢原子，具有1至30个碳原子的直链或支链烷基，式 - （CH 2 -CH 2 -O）n R的氧乙基，其中R为氢 原子或（C1-C4）烷基或酰基，n为1至10个数，具有5至12个碳原子的单核或多核脂环族基团，单核或多核芳族基团或芳脂族基，R5表示氢，氟 ，氯或溴原子或（C 1 -C 6）烷氧基或伯氨基，其中R 1和R 3可以是具有5至7个原子和0至3个双键的环系的一部分，A-表示相当于 阴离子，其量为粉末涂料中约0.01至约10重量％ 粉末，其中通式（1）和（2）的盐状阳离子化合物溶解或分散在粉末涂料或粉末中。

    Blue coloring agent for electro-photographic copying processes with positive control action
    10.
    发明授权
    Blue coloring agent for electro-photographic copying processes with positive control action 失效
    具有积极控制作用的电子照相复印工艺的蓝色染色剂

    公开(公告)号：US5061585A

    公开(公告)日：1991-10-29

    申请号：US664471

    申请日：1991-03-04

    申请人： Hans-Tobias Macholdt ,  Alexander Sieber

    发明人： Hans-Tobias Macholdt ,  Alexander Sieber

    IPC分类号： G03G9/097 ,  G03G9/00 ,  G03G9/09

    CPC分类号： G03G9/0912

    摘要： Blue coloring agent with positive control effect for electrophotographic copying processes, composed essentially of the compound of the formula ##STR1## the X-ray diffraction diagram of which contains a strong band at 2.degree. (CuK .alpha.)=18.47, three medium-strong bands at 2.degree. (CuK .alpha.)=5.97, 12.01 and 13.90 and weak broad bands at 2.degree. (CuK .alpha.)=20.0, 21.7, 22.5, 24.8, 28.2, 30.7 and 32.2, and the use of the coloring agent for the production of toners and developers which are used for the electrophotographic copying or duplication of originals, and also for the printing of electronically, optically or magnetically stored information or in color proofing.

    摘要翻译： PCT No.PCT / EP87 / 00003 Sec。 371日期：1989年6月1日 102（e）日期1989年6月1日PCT提交1987年1月7日PCT公布。 出版物WO88 / 04442 日期：1988年6月16日。对于电子照相复印工艺具有正面控制作用的蓝色着色剂，其基本上由下式的化合物组成：其中X射线衍射图包含2°的强条带（CuKα）= 18.47，在2℃（CuKα）= 5.97,12.01和13.90的三个中强带，在2℃（CuKα）= 20.0,21.7,22.5,24.8,28.2,30.7和32.2的弱宽带，以及 用于生产用于电子照相复印或复制原稿的调色剂和显影剂的着色剂，以及用于印刷电子，光学或磁存储信息或彩色打样的着色剂。