摘要:
A: Thermoplastic moulding materials made from a vinyl chloride homopolymer or copolymer containing at least 50% by weight of vinyl choloride units,B: a graft polymer, prepared by graft polymerization ofB1: 50 to 85 parts by weight of a mixture of at least two of the monomers styrene, acrylonitrile, methyl methacrylate and .alpha.-methyl styrene onB2: 50 to 15 parts by weight of an at least partially crosslinked butadiene or acrylate rubber having average particle diameters of 0.08 to 1 .mu.m, andC: a hydrogenated nitrile rubber in which the nitrile group content is 50 to 28% by weight and the degree of hydrogenation is greater than 50%, andD: optionally, a non-crosslinked, rubber-like ethylene or alkyl acrylate polymer, optionally containing copolymerized up to 70% by weight of vinyl acetate, acrylonitrile, methyl methacrylate or carbon monoxide,E: optionally at least partially crosslinked, rubber-like ethylene or alkyl acrylate polymer, optionally containing copolymerized up to 50% by weight of vinyl acetate, acrylonitrile, methyl methacrylate or carbon monoxide.
摘要:
Thermoplastic moulding compositions consisting ofI. 75 to 99.5% by weight of a polymer ofA. 0 to 95% by weight, 95% or less by weight; of a graft copolymer prepared by grafting polymerization ofA.1 5 to 95% by weight of a mixture ofA.1.1 50 to 95% by weight of styrene, .alpha.-methylstyrene, nuclear-substituted styrene, methyl methacrylate or mixtures thereof andA.1.2 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof onA.2 95 to 5% by weight of a rubber with a glass transition temperature Tg or
摘要:
An advantageous process for the heterogeneous catalytic hydrogenation of nitrile group-containing unsaturated polymers retaining nitrile groups, is characterised in that palladium supported on alkaline earth metal carbonates is used as hydrogenation catalyst.
摘要:
The selective hydrogenation of unsaturated compounds which carry reducible groups containing nitrogen succeeds in a homogeneous phase with the preservation of the reducible groups containing nitrogen, characterized in that a compound of the formulaRuH.sub.2n L.sub.5-nis used as a catalyst, in whichL signifies a phosphane or arsane andn signifies 1 or 2.
摘要:
Carbon-carbon double bonds are hydrogenated selectively in a compound containing a reducible, nitrogen-containing group if the hydrogenation is carried out in the presence of a ruthenium complex catalyst. Also disclosed are new ruthenium complexes for use in such selective hydrogenation.
摘要:
The selective hydrogenation in a homogeneous phase of unsaturated compounds carrying reducible groups containing nitrogen so as to preserve the reducible groups containing nitrogen succeeds with excellent yields if a compound corresponding to the following general formula:RuH.sub.m (R.sub.1 CO.sub.2).sub.n (L).sub.pwhereinR.sub.1 represents an optionally substituted alkyl, aryl, cycloalkyl or aralkyl group;L represents a phosphane or arsane;m represents 0 or 1;n represents 1 or 2; andp represents 2 or 3;is used as catalyst.
摘要翻译:如果对应于以下通式的化合物RuHm(R1CO2)n(L)p,其中R1代表(R 1 CO 2)n(L)),在含有氮的可还原基团的不饱和化合物的均相中的选择性氢化可以保持含有氮的可还原基团, 任选取代的烷基,芳基,环烷基或芳烷基; L代表磷烷或异氰酸酯; m表示0或1; n表示1或2; p表示2或3; 用作催化剂。
摘要:
Co-vulcanizates which have good mechanical properties, a good resistance to oil, an effective flame resistance and a low smoke gas density are obtained from mixtures of (a) from 95 to 5% by weight of EVA rubber and (b) from 5 to 95% by weight of elastomers which contain nitrile groups and have from 25 to 140 nitrile groups and less than 35 double bonds per 1000 carbon atoms, by radical cross-linking.
摘要:
Statistical copolymers of from 85 to 52% by weight of a conjugated diene, from 15 to 48% by weight of at least one unsaturated nitrile and from 0 to 10% by weight of further monomers, copolymerizable with diene and nitrile, which have a molecular weight M.sub.n of from 0.5 to 30 kg/mol and a degree of hydrogenation of the double bonds of greater than 80%, give nitrile rubbers, which are mixed and colvulcanized with these copolymers, an increased ozone resistance.
摘要:
Co-vulcanizates having good mechanical properties are obtained from mixtures of: (a) from 35 to 5%, by weight, of hydrocarbon elastomers; (b) from 65 to 95%, by weight, of nitrile group-containing elastomers having from 25 to 140 nitrile nitrogen atoms and less 12 double bonds per 1000 carbon atoms; by radical cross-linking.
摘要:
This invention relates to vulcanizable diene rubber compounds with a high capacity for the addition of sulfur to be varied while processing safety is maintained, for the production of improved rubber moldings, particularly tire components.