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公开(公告)号：US4774295A
公开(公告)日：1988-09-27
申请号：US940295
申请日：1986-12-11
IPC分类号： C08L33/00 , C08J3/24 , C08J3/28 , C08K5/14 , C08L1/00 , C08L7/00 , C08L9/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L23/00 , C08L23/26 , C08L23/34 , C08L27/00 , C08L29/04 , C08L33/02 , C08L33/18 , C08L33/20 , C08L101/00 , C08L23/08 , C08L27/06
CPC分类号： C08L15/005 , C08L23/34 , C08K3/36 , C08K5/0016 , C08L23/0861 , C08L23/286 , C08L27/06 , C08L29/02 , C08L33/08
摘要： Covulcanizates with good mechanical properties obtained from mixtures of (a) from 50 to 5% by weight of chlorinated or chlorosulphonated polyethylene, acrylate rubber or ethylene vinyl alcohol copolymers and (b) from 50 to 95% by weight of partially or completely hydrogenated nitrile group-containing elastomers containing from 25 to 140 nitrile nitrogen atoms and less than 35 double bonds for each 1,000 carbon atoms, by cross linking.
摘要翻译： 由（a）50至5重量％的氯化或氯磺化聚乙烯，丙烯酸酯橡胶或乙烯乙烯醇共聚物的混合物获得的具有良好机械性能的共硫化橡胶，和（b）50至95重量％的部分或完全氢化的腈基 含有25〜140个腈氮原子和每1000个碳原子少于35个双键的弹性体。
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公开(公告)号：US4675248A
公开(公告)日：1987-06-23
申请号：US661941
申请日：1984-10-17
IPC分类号： C08L7/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L23/00 , C08L23/08 , C08L31/04 , C08L33/00 , C08L33/02 , C08L101/00 , H01B3/44 , D02G3/00 , C08L33/04 , H01B7/00
CPC分类号： H01B3/441 , C08L15/005 , C08L23/0853 , C08L9/02 , C08L2312/06 , Y10T428/2975
摘要： Co-vulcanizates which have good mechanical properties, a good resistance to oil, an effective flame resistance and a low smoke gas density are obtained from mixtures of (a) from 95 to 5% by weight of EVA rubber and (b) from 5 to 95% by weight of elastomers which contain nitrile groups and have from 25 to 140 nitrile groups and less than 35 double bonds per 1000 carbon atoms, by radical cross-linking.
摘要翻译： 由（a）95〜5重量％的EVA橡胶和（b）5〜5重量份的混合物得到具有良好的机械性能，良好的耐油性，有效阻燃性和低烟气密度的共硫化橡胶 通过自由基交联，95重量％的含有腈基并具有25至140个腈基和小于35个双键的1000个碳原子的弹性体。
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公开(公告)号：US4647627A
公开(公告)日：1987-03-03
申请号：US770103
申请日：1985-08-28
IPC分类号： C08F236/00 , C08C19/02 , C08F8/04 , C08F236/04 , C08F236/12 , C08L7/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L33/00 , C08L33/02
CPC分类号： C08C19/02 , C08L9/02 , C08L15/005 , C08L2205/02
摘要： Statistical copolymers of from 85 to 52% by weight of a conjugated diene, from 15 to 48% by weight of at least one unsaturated nitrile and from 0 to 10% by weight of further monomers, copolymerizable with diene and nitrile, which have a molecular weight M.sub.n of from 0.5 to 30 kg/mol and a degree of hydrogenation of the double bonds of greater than 80%, give nitrile rubbers, which are mixed and colvulcanized with these copolymers, an increased ozone resistance.
摘要翻译： 85至52重量％的共轭二烯，15至48重量％的至少一种不饱和腈和0至10重量％可与二烯和腈共聚的其它单体的统计共聚物，其具有分子 重量Mn为0.5〜30kg / mol，双键氢化度大于80％，得到与这些共聚物混合和聚合硫化的丁腈橡胶，耐臭氧性提高。
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公开(公告)号：US4576992A
公开(公告)日：1986-03-18
申请号：US676486
申请日：1984-11-29
IPC分类号： C08L7/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L23/00 , C08L23/16 , C08L23/22 , C08L33/00 , C08L33/02 , C08L101/00 , C08L45/00
CPC分类号： C08L15/005 , C08L23/16 , C08L23/22
摘要： Co-vulcanizates having good mechanical properties are obtained from mixtures of: (a) from 35 to 5%, by weight, of hydrocarbon elastomers; (b) from 65 to 95%, by weight, of nitrile group-containing elastomers having from 25 to 140 nitrile nitrogen atoms and less 12 double bonds per 1000 carbon atoms; by radical cross-linking.
摘要翻译： 具有良好机械性能的共硫化橡胶由下列混合物得到：（a）35至5重量％的烃弹性体; （b）65至95重量％的含有腈基的弹性体，每1000个碳原子具有25至140个腈氮原子和12个双键; 通过激进交联。
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5.发明授权Shaped articles for use in the exploration for and/or production of petroleum and natural gas 失效用于勘探和/或生产石油和天然气的成型制品
公开(公告)号：US4631309A
公开(公告)日：1986-12-23
申请号：US678720
申请日：1984-12-06
CPC分类号： C09K8/882 , C08L15/005
摘要： Equipment for the exploration and/or production of petroleum and natural gas having elastomeric components have high resistance to materials encountered if the elastomeric components are shaped from a hydrogenated butadiene-acrylonitrile copolymer with a residual double bond content less than 1% and unhydrogenated nitrile groups.
摘要翻译： 用于勘探和/或生产具有弹性体组分的石油和天然气的设备如果弹性体组分由残余双键含量小于1％的氢化丁二烯 - 丙烯腈共聚物和未氢化的腈基组成，则对所遇到的材料具有高抗性。
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公开(公告)号：US4565614A
公开(公告)日：1986-01-21
申请号：US657536
申请日：1984-10-04
IPC分类号： C08F2/46 , C08L1/00 , C08L7/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/12 , C08L57/00 , C08L101/00
CPC分类号： C08L15/005 , C08L27/12 , C08L15/00
摘要： Co-vulcanizates are produced from mixtures of (a) from 95 to 5% by weight of fluoroelastomers and (b) from 5 to 95% by weight of elastomers which contain nitrile groups and have from 25 to 140 nitrile-nitrogen atoms and less than 35 double bonds per 1000 carbon atoms, and (c) conventional mixture ingredients, the percentages relating to the sum total of (a) and (b). The co-vulcanizates are suitable for the production of seals and other rubber articles, in particular for areas of use which impose exacting requirements.
摘要翻译： 共硫化橡胶由（a）95至5重量％的含氟弹性体和（b）5至95重量％的含有腈基并具有25至140个腈氮原子并且小于 每1000个碳原子35个双键，（c）常规混合物成分，与（a）和（b）的总和相关的百分比。 共硫化橡胶适用于生产密封件和其他橡胶制品，特别适用于严格要求的区域。
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公开(公告)号：US4829128A
公开(公告)日：1989-05-09
申请号：US922947
申请日：1986-10-24
IPC分类号： C08F236/00 , C08C19/02 , C08F8/04 , C08F236/04 , C08F236/12 , C08L7/00 , C08L9/02 , C08L15/00 , C08L21/00 , C08L33/00 , C08L33/02
CPC分类号： C08C19/02 , C08L9/02 , C08L15/005 , C08L2205/02
摘要： Statistical copolymers of from 85 to 52% by weight of a conjugated diene, from 15 to 48% by weight of at least one unsaturated nitrile and from 0 to 10% by weight of further monomers, copolymerizable with diene and nitrile, which have a molecular weight M.sub.n of from 0.5 to 30 kg/mol and a degree of hydrogenation of the double bonds of greater than 80%, give nitrile rubbers, which are mixed and colvulcanized with these copolymers, an increased ozone resistance.
摘要翻译： 85至52重量％的共轭二烯，15至48重量％的至少一种不饱和腈和0至10重量％可与二烯和腈共聚的其它单体的统计共聚物，其具有分子 重量Mn为0.5〜30kg / mol，双键氢化度大于80％，得到与这些共聚物混合和聚合硫化的丁腈橡胶，耐臭氧性提高。
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公开(公告)号：US4581417A
公开(公告)日：1986-04-08
申请号：US638954
申请日：1984-08-08
IPC分类号： C08F8/00 , C08C19/02 , C08F8/04 , C08F220/00 , C08F220/44 , C08F236/00 , C08F236/12
CPC分类号： C08C19/02
摘要： The hydrogenation of NBR in an aromatic solvent with tris-(triphenylphosphane)-rhodium-(I) halide as catalyst under hydrogen pressures of from 20 to 350 bars and at temperatures in the range from 100.degree. to 145.degree. C. leads to products having degrees of hydrogenation of at least 90% and outstanding properties when the catalyst concentration amounts to between 0.05 and 0.6% by weight, based on solid rubber, and when hydrogenation is carried out in the presence of at most 2% by weight of triphenylphosphane.
摘要翻译： 在20至350巴的氢气压力和100至145℃的温度下，用三 - （三苯基膦） - 铑 - （I）卤化物作为催化剂在芳族溶剂中氢化NBR，导致产物具有 当催化剂浓度为0.05-0.6重量％时，基于固体橡胶，并且当在至多2重量％的三苯基膦存在下进行氢化时，氢化程度至少为90％。
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公开(公告)号：US4746707A
公开(公告)日：1988-05-24
申请号：US891618
申请日：1986-08-01
申请人： Paul Fiedler , Hartmuth Buding , Rudolf Braden , Joachim Thormer
发明人： Paul Fiedler , Hartmuth Buding , Rudolf Braden , Joachim Thormer
IPC分类号： C07B35/02 , B01J31/00 , B01J31/24 , C07B31/00 , C07B61/00 , C07C67/00 , C07C239/00 , C07C249/12 , C07C251/42 , C07C251/44 , C07C253/00 , C07C253/30 , C07C255/02 , C07C255/46 , C08C19/02 , C08F8/00 , C08F8/04
摘要： The selective hydrogenation in a homogeneous phase of unsaturated compounds carrying reducible groups containing nitrogen so as to preserve the reducible groups containing nitrogen succeeds with excellent yields if a compound corresponding to the following general formula:RuH.sub.m (R.sub.1 CO.sub.2).sub.n (L).sub.pwhereinR.sub.1 represents an optionally substituted alkyl, aryl, cycloalkyl or aralkyl group;L represents a phosphane or arsane;m represents 0 or 1;n represents 1 or 2; andp represents 2 or 3;is used as catalyst.
摘要翻译： 如果对应于以下通式的化合物RuHm（R1CO2）n（L）p，其中R1代表（R 1 CO 2）n（L）），在含有氮的可还原基团的不饱和化合物的均相中的选择性氢化可以保持含有氮的可还原基团， 任选取代的烷基，芳基，环烷基或芳烷基; L代表磷烷或异氰酸酯; m表示0或1; n表示1或2; p表示2或3; 用作催化剂。
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公开(公告)号：US4631315A
公开(公告)日：1986-12-23
申请号：US771646
申请日：1985-09-03
IPC分类号： C08F8/00 , B01J31/00 , B01J31/16 , C08C19/02 , C08F8/04 , C08F236/00 , C08F236/12
CPC分类号： C08C19/02
摘要： Nitrile group-containing polymers are hydrogenated in a homogeneous phase with preservation of the nitrile groups in a low molecular weight ketone as a solvent and with a compound corresponding to formulaRuX[(L.sub.1)(L.sub.2).sub.n ]as a catalyst, whereinX represents hydrogen, halogenL.sub.1 represents hydrogen, halogen, optionally substituted cyclopentadienyl,L.sub.2 represents a phosphane, bisphosphane or arsane andn is 1, 2 or 3 and[(L.sub.1)(L.sub.2).sub.n ] represents a cyclopentadienyl bisphosphane.
摘要翻译： 含腈基的聚合物以均相形式被氢化，在作为溶剂的低分子量酮中保留腈基，并使用对应于式RuX [（L1）（L2）n]的化合物作为催化剂，其中X表示 氢，卤素L 1代表氢，卤素，任选取代的环戊二烯基，L 2代表一种膦，二膦或二异氰酸酯，n是1,2或3，[（L1）（L2）n]代表环戊二烯基双膦。
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