摘要:
In an apparatus provided with a plate type heat exchanger as a heater and/or a cooler and operated to treat a gas containing an easily blocking substance, a method for preventing the plate type heat exchanger from being blocked is disclosed which is characterized by i) setting the width of a flow path on a plate of the plate type heat exchanger in the apparatus in a range of 6-25 mm and ii) setting the average flow rate of the gas passing the plate type heat exchanger in the apparatus per unit cross-sectional area of the flow path on the plate in the range of 3-15 m/s. In the exchange of heat of an easily blocking substance by the use of a plate type heat exchanger, a method for preventing the plate type heat exchanger from blockage is disclosed which has the plate type heat exchanger provided in the port for introducing a gas containing an easily blocking substance with a gas dispersion plate. This invention, in the heat exchange of an effluent gas emanating from a process for the production of (meth)acrylic acid or an ester thereof or the disposal of the gas, significantly allays blockage of the interior of the plate type heat exchanger.
摘要翻译:在设置有作为加热器和/或冷却器的板式热交换器并且被操作以处理含有易阻塞物质的气体的装置中,公开了一种防止板式热交换器被堵塞的方法,其特征在于i) 将设备中板式热交换器的板上的流路宽度设置在6-25mm的范围内,以及ii)将通过板式热交换器的气体的平均流量设置在每单位十字的装置中 板上流路的截面面积在3-15 m / s的范围内。 在通过使用板式热交换器交换容易堵塞物质的热的情况下,公开了一种防止板式热交换器堵塞的方法,其具有设置在用于引入含有 用气体分散板容易地堵塞物质。 本发明在从(甲基)丙烯酸或其酯的制备方法产生的流出气体的热交换或气体的处理中显着地阻止了板式热交换器的内部堵塞。
摘要:
For use in a process for the production of (meth)acrylic acid comprising at least a step for the reaction of (meth)acrylic acid by catalytic gas phase oxidation and a step for the absorption thereof, a method for preventing an effluent gas pipe from blocking is disclosed, which method is characterized by causing part or the whole of the gas discharged from the step for absorption, while being circulated via the effluent gas pipe to the step for the reaction or being discarded, to be subjected to temperature elevation and application of pressure and/or mist separation. Particularly by setting the temperature of the waste gas from the absorption column at a level in the range of 30-70° C., it is made possible to decrease the contents of water, low boiling substances, and subliming substances entrained by the waste gas and, coupled with the temperature elevation and the application of pressure implemented in the effluent gas pipe, attain effective prevention of the interior of the effluent gas pipe from blockage and corrosion.
摘要:
In the reaction of catalytic gas phase oxidation induced by the supply of at least a raw material to be oxidized and a molecular oxygen-containing gas to a reactor for catalytic gas phase oxidation, a method for starting up the reactor for catalytic gas phase oxidation is disclosed which is characterized by causing the raw material and the molecular oxygen-containing gas to pass a range in which the concentration of the raw material is less than the lower explosion limit of the raw material and the concentration of oxygen is not less than the limiting oxygen concentration, but excluding the concentration of the raw material of 0 vol. %. The method enables the reactor to be started up economically and safely by avoiding the explosion range induced by the composition of a raw material and a molecular oxygen-containing gas supplied to the reactor and decreasing the amount of a diluting gas to be supplied.
摘要:
A method for managing the operation of an apparatus for the reaction of gas phase partial oxidation of an unsaturated hydrocarbon with a molecular oxygen-containing gas for the purpose of omitting wasteful emergency stop of the operation and ensuring execution of necessary emergency measure and a method for producing (meth) acrylic acid by utilizing the method mentioned above are provided. The operation of the apparatus is brought to emergency stop exclusively when thee values of concentrations of various gases obtained by calculation from the flow rates of the gases being introduced at the inlet port of the reactor and the measured values obtained by analysis with gas analyzing instruments both deviate from the ranges of the present values.
摘要:
This invention concerns a method for absorbing acrylic acid, characterized by supplying an acrylic acid-containing reaction gas component obtained by the reaction of catalytic gas phase oxidation to an acrylic acid absorption column and advancing a high boiling inert hydrophobic organic liquid into counter-flow contact with said reaction gas in said acrylic acid absorption column with the mass flow rate of the organic liquid fixed in the range of 0.2-4.5 times the mass flow rate of the acrylic acid in the reaction gas thereby absorbing acrylic acid in said organic liquid and obtaining an acrylic acid-containing solution and a method for purifying acrylic acid, comprising a step for purifying the acrylic acid-containing organic liquid obtained by the step mentioned above. By this invention, a product of acrylic acid containing a low boiling substance at a low concentration can be produced.
摘要:
A method for the production of acrylic acid comprises (i) a step for introducing a polymerization inhibitor to a stage other than a stage for supplying a raw material and a stage for supplying a reflux of said distilling column or (ii) a step for supplying the acrylic acid recovered by thermally decomposing said oligomer to said stage for dehydration. Thus, the present invention enjoys effective utilization of acrylic acid and exalts the efficiency of production.
摘要:
A method is disclosed which produces acrylic acid in a high yield as maintaining the conditions for purifying acrylic acid in constant ranges and preventing the acrylic acid from polymerization. By using single a single reactor, propylene concentration adjusting in the range of 7–15 vol. % and water concentration adjusting in the range of 0–10 vol. % are introduced thereinto thereby obtaining an acrylic acid-containing gas. Then the gas is introduced to an acrylic acid absorption column to adjust water concentration in the range of 1–45 wt. %, thereby preventing from polymerization.
摘要:
This invention is providing a method for efficient treatment of the waste material from a process for production of acrylic acid and an acrylic ester. This is a method for the disposal of waste material, which at least one waste material selected from the group consisting of waste oil, waste water, and waste gas emitted from a process for production of acrylic acid is/are purified with at least one waste material selected from the group consisting of waste oil, waste water, and waste gas emitted from a process for production of an acrylic ester jointly. The efficiency of the treatment is enhanced by simultaneously treating the waste material.
摘要:
This invention concerns a method for absorbing acrylic acid, characterized by supplying an acrylic acid-containing reaction gas component obtained by the reaction of catalytic gas phase oxidation to an acrylic acid absorption column and advancing a high boiling inert hydrophobic organic liquid into counter-flow contact with said reaction gas in said acrylic acid absorption column with the mass flow rate of the organic liquid fixed in the range of 0.2-7.0 times the mass flow rate of the acrylic acid in the reaction gas thereby absorbing acrylic acid in said organic liquid and obtaining an acrylic acid-containing solution including a low boiling substance in the range of 0.7-7.5 wt % based on the weight of bottom liquid of absorption column.
摘要:
PROBLEMThere is provided a melting method of (meth)acrylic acid crystal which is capable of providing a higher quality of (meth)acrylic acid without carrying out an additional purification treatment to (meth)acrylic acid obtained by a crystallization operation accompanied by melting of (meth)acrylic acid. In addition, there is provided a simple method for adjusting a content of polymerization inhibitor in a product (meth)acrylic acid.SOLUTIONIn the crystallization method melting (meth)acrylic acid crystal while wetting with the crystalline molten liquid, a polymerization inhibitor is added to a molten liquid melted after initiation of melting, and all of crystal is melted while circulating and feeding the molten liquid containing said polymerization inhibitor to the crystal. In addition, a content of polymerization inhibitor in product (meth)acrylic acid is adjusted by adding a predetermined amount of polymerization inhibitor corresponding to a product specification to the molten liquid melted after initiation of melting.